IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v15y2024i1d10.1038_s41467-024-49750-8.html
   My bibliography  Save this article

Stimuli-responsive mechanically interlocked polymer wrinkles

Author

Listed:
  • Mengling Yang

    (Shanghai Jiao Tong University)

  • Shuai Chen

    (Shanghai Jiao Tong University)

  • Zhaoming Zhang

    (Shanghai Jiao Tong University)

  • Lin Cheng

    (Shanghai Jiao Tong University)

  • Jun Zhao

    (Shanghai Jiao Tong University)

  • Ruixue Bai

    (Shanghai Jiao Tong University)

  • Wenbin Wang

    (Shanghai Jiao Tong University)

  • Wenzhe Gao

    (Shanghai Jiao Tong University)

  • Wei Yu

    (Shanghai Jiao Tong University)

  • Xuesong Jiang

    (Shanghai Jiao Tong University)

  • Xuzhou Yan

    (Shanghai Jiao Tong University)

Abstract

Artificial wrinkles, especially those with responsive erasure/regeneration behaviors have gained extensive interest due to their potential in smart applications. However, current wrinkle modulation methods primarily rely on network rearrangement, causing bottlenecks in in situ wrinkle regeneration. Herein, we report a dually cross-linked network wherein [2]rotaxane cross-link can dissipate stress within the wrinkles through its sliding motion without disrupting the network, and quadruple H-bonding cross-link comparatively highlight the advantages of [2]rotaxane modulation. Acid stimulation dissociates quadruple H-bonding and destructs network, swiftly eliminating the wrinkles. However, the regeneration process necessitates network rearrangement, making in situ recovery unfeasible. By contrast, alkaline stimulation disrupts host–guest recognition, and subsequent intramolecular motion of [2]rotaxane dissipate energy to eliminate wrinkles gradually. The always intact network allows for the in situ recovery of surface microstructures. The responsive behaviors of quadruple H-bonding and mechanical bond are orthogonal, and their combination leads to wrinkles with multiple but accurate responsiveness.

Suggested Citation

  • Mengling Yang & Shuai Chen & Zhaoming Zhang & Lin Cheng & Jun Zhao & Ruixue Bai & Wenbin Wang & Wenzhe Gao & Wei Yu & Xuesong Jiang & Xuzhou Yan, 2024. "Stimuli-responsive mechanically interlocked polymer wrinkles," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-49750-8
    DOI: 10.1038/s41467-024-49750-8
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-024-49750-8
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-024-49750-8?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Jie Yin & Mary C. Boyce, 2015. "Unique wrinkles as identity tags," Nature, Nature, vol. 520(7546), pages 164-165, April.
    2. Sougata Datta & Yasuki Kato & Seiya Higashiharaguchi & Keisuke Aratsu & Atsushi Isobe & Takuho Saito & Deepak D. Prabhu & Yuichi Kitamoto & Martin J. Hollamby & Andrew J. Smith & Robert Dalgliesh & Na, 2020. "Self-assembled poly-catenanes from supramolecular toroidal building blocks," Nature, Nature, vol. 583(7816), pages 400-405, July.
    3. Xu Wang & Wei Zeng & Liang Hong & Wenwen Xu & Haokai Yang & Fan Wang & Huigao Duan & Ming Tang & Hanqing Jiang, 2018. "Stress-driven lithium dendrite growth mechanism and dendrite mitigation by electroplating on soft substrates," Nature Energy, Nature, vol. 3(3), pages 227-235, March.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Chao Wang & Ming Liu & Michel Thijs & Frans G. B. Ooms & Swapna Ganapathy & Marnix Wagemaker, 2021. "High dielectric barium titanate porous scaffold for efficient Li metal cycling in anode-free cells," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
    2. Ningfei Sun & Ziyu Chen & Yanke Wang & Shu Wang & Yong Xie & Qian Liu, 2023. "Random fractal-enabled physical unclonable functions with dynamic AI authentication," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    3. Shilong Zhong & Zhaoxiang Zhu & Qizheng Huo & Yubo Long & Li Gong & Zetong Ma & Dingshan Yu & Yi Zhang & Weien Liang & Wei Liu & Cheng Wang & Zhongke Yuan & Yuzhao Yang & Shaolin Lu & Yujie Chen & Zhi, 2024. "Designed wrinkles for optical encryption and flexible integrated circuit carrier board," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    4. Joseph F. Woods & Lucía Gallego & Amira Maisch & Dominik Renggli & Corrado Cuocci & Olivier Blacque & Gunther Steinfeld & Andres Kaech & Bernhard Spingler & Andreas Vargas Jentzsch & Michel Rickhaus, 2023. "Saddles as rotational locks within shape-assisted self-assembled nanosheets," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    5. Srinu Kotha & Rahul Sahu & Aditya Chandrakant Yadav & Preeti Sharma & B. V. V. S. Pavan Kumar & Sandeep K. Reddy & Kotagiri Venkata Rao, 2024. "Noncovalent synthesis of homo and hetero-architectures of supramolecular polymers via secondary nucleation," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    6. Nils Bäumer & Eduardo Castellanos & Bartolome Soberats & Gustavo Fernández, 2023. "Bioinspired crowding directs supramolecular polymerisation," Nature Communications, Nature, vol. 14(1), pages 1-9, December.
    7. Sai Rachana Pramatha & Dasari Srideep & Udaijit Pattnaik & Rahul Sahu & Devamrutha Ilayidathu Suresh & Aditya Chandrakant Yadav & Chinmayee Muduli & Sandeep K. Reddy & Satyaprasad P. Senanayak & Kotag, 2024. "Secondary nucleation guided noncovalent synthesis of dendritic homochiral superstructures via growth on and from surface," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    8. Tiejun Li & Dian Niu & Lukang Ji & Qian Li & Bo Guan & Hanxiao Wang & Guanghui Ouyang & Minghua Liu, 2025. "Supramolecular rosette intermediated homochiral double helix," Nature Communications, Nature, vol. 16(1), pages 1-10, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-49750-8. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.