IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v15y2024i1d10.1038_s41467-024-48835-8.html
   My bibliography  Save this article

Syntheses and reactivities of strained fused-ring metallaaromatics containing planar eleven-carbon chains

Author

Listed:
  • Binbin Xu

    (Southern University of Science and Technology)

  • Wei Mao

    (Southern University of Science and Technology)

  • Zhengyu Lu

    (Southern University of Science and Technology)

  • Yuanting Cai

    (Southern University of Science and Technology)

  • Dafa Chen

    (Southern University of Science and Technology)

  • Haiping Xia

    (Southern University of Science and Technology
    Southern University of Science and Technology Guangming Advanced Research Institute)

Abstract

Carbolong complexes are one of the primary types of metallaaromatics, and they include metallapentalynes and metallapentalenes. A series of 7C-10C and 12C-carbolong complexes with planar ligand skeletons respectively containing 7-10 and 12 carbon atoms in their backbones, have been previously reported. Herein, two classes of strained substances, metallabenzyne-fused metallapentalenes and metallabenzene-fused metallapentalynes, were prepared, both representing 11C-carbolong complexes with a planar carbon-chain ligand. Furthermore, the former type is also the carbolong derivatives containing a metallabenzyne skeleton, another primary metallaaromatic framework. Metallabenzyne-fused metallapentalenes show versatile reactivities, and the most interesting one is the metal carbyne bond shift from a 6-membered to a more strained 5-membered ring, affording the above-mentioned metallabenzene-fused metallapentalyne. This work makes carbolong chemistry more complete, and provides a method to achieve metallabenzynes, which is anticipated to concurrently advance the development of these two types of metallaaromatics.

Suggested Citation

  • Binbin Xu & Wei Mao & Zhengyu Lu & Yuanting Cai & Dafa Chen & Haiping Xia, 2024. "Syntheses and reactivities of strained fused-ring metallaaromatics containing planar eleven-carbon chains," Nature Communications, Nature, vol. 15(1), pages 1-8, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-48835-8
    DOI: 10.1038/s41467-024-48835-8
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-024-48835-8
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-024-48835-8?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Zhe Huang & Yongliang Zhang & Wen-Xiong Zhang & Junnian Wei & Shengfa Ye & Zhenfeng Xi, 2021. "A tris-spiro metalla-aromatic system featuring Craig-Möbius aromaticity," Nature Communications, Nature, vol. 12(1), pages 1-7, December.
    2. Shiyan Chen & Longzhu Liu & Xiang Gao & Yuhui Hua & Lixia Peng & Ying Zhang & Liulin Yang & Yuanzhi Tan & Feng He & Haiping Xia, 2020. "Addition of alkynes and osmium carbynes towards functionalized dπ–pπ conjugated systems," Nature Communications, Nature, vol. 11(1), pages 1-11, December.
    3. Congqing Zhu & Ming Luo & Qin Zhu & Jun Zhu & Paul v. R. Schleyer & Judy I-Chia Wu & Xin Lu & Haiping Xia, 2014. "Planar Möbius aromatic pentalenes incorporating 16 and 18 valence electron osmiums," Nature Communications, Nature, vol. 5(1), pages 1-7, December.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Xue Lai, & Shiyan Chen, & Xiaoyu Gu, & Hanjian Lai, & Yunpeng Wang, & Yulin Zhu, & Hui Wang, & Jianfei Qu, & Aung Ko Ko Kyaw & Haiping Xia & Feng He, 2023. "Phenanthroline-carbolong interface suppress chemical interactions with active layer enabling long-time stable organic solar cells," Nature Communications, Nature, vol. 14(1), pages 1-11, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-024-48835-8. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.