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Integrated energy storage and CO2 conversion using an aqueous battery with tamed asymmetric reactions

Author

Listed:
  • Yumei Liu

    (Peking University)

  • Yun An

    (Peking University)

  • Jiexin Zhu

    (Peking University
    University College London)

  • Lujun Zhu

    (Peking University)

  • Xiaomei Li

    (Peking University)

  • Peng Gao

    (Peking University)

  • Guanjie He

    (University College London)

  • Quanquan Pang

    (Peking University)

Abstract

Developing a CO2-utilization and energy-storage integrated system possesses great advantages for carbon- and energy-intensive industries. Efforts have been made to developing the Zn-CO2 batteries, but access to long cycling life and low charging voltage remains a grand challenge. Here we unambiguously show such inefficiencies originate from the high-barrier oxygen evolution reaction on charge, and by recharging the battery via oxidation of reducing molecules, Faradaic efficiency-enhanced CO2 reduction and low-overpotential battery regeneration can be simultaneously achieved. Showcased by using hydrazine oxidation, our battery demonstrates a long life over 1000 hours with a charging voltage as low as 1.2 V. The low charging voltage and formation of gaseous product upon hydrazine oxidation are the key to stabilize the catalyst over cycling. Our findings suggest that by fundamentally taming the asymmetric reactions, aqueous batteries are viable tools to achieve integrated energy storage and CO2 conversion that is economical, highly energy efficient, and scalable.

Suggested Citation

  • Yumei Liu & Yun An & Jiexin Zhu & Lujun Zhu & Xiaomei Li & Peng Gao & Guanjie He & Quanquan Pang, 2024. "Integrated energy storage and CO2 conversion using an aqueous battery with tamed asymmetric reactions," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    • Handle: RePEc:nat:natcom:v:15:y:2024:i:1:d:10.1038_s41467-023-44283-y
    DOI: 10.1038/s41467-023-44283-y
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    References listed on IDEAS

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    1. Steven Chu & Arun Majumdar, 2012. "Opportunities and challenges for a sustainable energy future," Nature, Nature, vol. 488(7411), pages 294-303, August.
    2. Shengwen Liu & Chenzhao Li & Michael J. Zachman & Yachao Zeng & Haoran Yu & Boyang Li & Maoyu Wang & Jonathan Braaten & Jiawei Liu & Harry M. Meyer & Marcos Lucero & A. Jeremy Kropf & E. Ercan Alp & Q, 2022. "Atomically dispersed iron sites with a nitrogen–carbon coating as highly active and durable oxygen reduction catalysts for fuel cells," Nature Energy, Nature, vol. 7(7), pages 652-663, July.
    3. Haeun Shin & Kentaro U. Hansen & Feng Jiao, 2021. "Techno-economic assessment of low-temperature carbon dioxide electrolysis," Nature Sustainability, Nature, vol. 4(10), pages 911-919, October.
    4. Nestor A. Sepulveda & Jesse D. Jenkins & Aurora Edington & Dharik S. Mallapragada & Richard K. Lester, 2021. "The design space for long-duration energy storage in decarbonized power systems," Nature Energy, Nature, vol. 6(5), pages 506-516, May.
    5. Zhiping Zeng & Li Yong Gan & Hong Yang & Xiaozhi Su & Jiajian Gao & Wei Liu & Hiroaki Matsumoto & Jun Gong & Junming Zhang & Weizhen Cai & Zheye Zhang & Yibo Yan & Bin Liu & Peng Chen, 2021. "Orbital coupling of hetero-diatomic nickel-iron site for bifunctional electrocatalysis of CO2 reduction and oxygen evolution," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
    6. Adnan Ozden & F. Pelayo García de Arquer & Jianan Erick Huang & Joshua Wicks & Jared Sisler & Rui Kai Miao & Colin P. O’Brien & Geonhui Lee & Xue Wang & Alexander H. Ip & Edward H. Sargent & David Sin, 2022. "Carbon-efficient carbon dioxide electrolysers," Nature Sustainability, Nature, vol. 5(7), pages 563-573, July.
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