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Pressure-controlled magnetism in 2D molecular layers

Author

Listed:
  • Yulong Huang

    (University at Buffalo, The State University of New York)

  • Arjun K. Pathak

    (SUNY Buffalo State, Buffalo)

  • Jeng-Yuan Tsai

    (Northeastern University)

  • Clayton Rumsey

    (University at Buffalo, The State University of New York)

  • Mathew Ivill

    (DEVCOM Army Research Laboratory)

  • Noah Kramer

    (SUNY Buffalo State, Buffalo)

  • Yong Hu

    (University at Buffalo, The State University of New York)

  • Martin Trebbin

    (University at Buffalo, The State University of New York
    University at Buffalo, The State University of New York)

  • Qimin Yan

    (Northeastern University)

  • Shenqiang Ren

    (University at Buffalo, The State University of New York
    Northeastern University
    University at Buffalo, The State University of New York
    University at Buffalo, The State University of New York)

Abstract

Long-range magnetic ordering of two-dimensional crystals can be sensitive to interlayer coupling, enabling the effective control of interlayer magnetism towards voltage switching, spin filtering and transistor applications. With the discovery of two-dimensional atomically thin magnets, a good platform provides us to manipulate interlayer magnetism for the control of magnetic orders. However, a less-known family of two-dimensional magnets possesses a bottom-up assembled molecular lattice and metal-to-ligand intermolecular contacts, which lead to a combination of large magnetic anisotropy and spin-delocalization. Here, we report the pressure-controlled interlayer magnetic coupling of molecular layered compounds via chromium-pyrazine coordination. Room-temperature long-range magnetic ordering exhibits pressure tuning with a coercivity coefficient up to 4 kOe/GPa, while pressure-controlled interlayer magnetism also presents a strong dependence on alkali metal stoichiometry and composition. Two-dimensional molecular interlayers provide a pathway towards pressure-controlled peculiar magnetism through charge redistribution and structural transformation.

Suggested Citation

  • Yulong Huang & Arjun K. Pathak & Jeng-Yuan Tsai & Clayton Rumsey & Mathew Ivill & Noah Kramer & Yong Hu & Martin Trebbin & Qimin Yan & Shenqiang Ren, 2023. "Pressure-controlled magnetism in 2D molecular layers," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:14:y:2023:i:1:d:10.1038_s41467-023-38991-8
    DOI: 10.1038/s41467-023-38991-8
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    References listed on IDEAS

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    1. Bevin Huang & Genevieve Clark & Efrén Navarro-Moratalla & Dahlia R. Klein & Ran Cheng & Kyle L. Seyler & Ding Zhong & Emma Schmidgall & Michael A. McGuire & David H. Cobden & Wang Yao & Di Xiao & Pabl, 2017. "Layer-dependent ferromagnetism in a van der Waals crystal down to the monolayer limit," Nature, Nature, vol. 546(7657), pages 270-273, June.
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    1. Chenglin Han & Shida Fan & Hong-Tao Zhou & Kuan He & Yurou Jia & Changyou Li & Hongzhu Li & Xiao-Dong Yang & Li-Qun Chen & Tianzhi Yang & Cheng-Wei Qiu, 2025. "All-angle unidirectional flat-band acoustic metasurfaces," Nature Communications, Nature, vol. 16(1), pages 1-7, December.

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