IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v13y2022i1d10.1038_s41467-022-32024-6.html
   My bibliography  Save this article

Sustainable oxygen evolution electrocatalysis in aqueous 1 M H2SO4 with earth abundant nanostructured Co3O4

Author

Listed:
  • Jiahao Yu

    (Institute of Chemical Research of Catalonia (ICIQ), The Barcelona Institute of Science and Technology (BIST)
    Universitat Rovira i Virgili)

  • Felipe A. Garcés-Pineda

    (Institute of Chemical Research of Catalonia (ICIQ), The Barcelona Institute of Science and Technology (BIST))

  • Jesús González-Cobos

    (Institute of Chemical Research of Catalonia (ICIQ), The Barcelona Institute of Science and Technology (BIST)
    Institut de Recherches sur la Catalyse et l’Environnement de Lyon, UMR 5256, CNRS, Université Claude Bernard Lyon 1)

  • Marina Peña-Díaz

    (CFM/MPC, (UPV/EHU-CSIC))

  • Celia Rogero

    (CFM/MPC, (UPV/EHU-CSIC)
    Donostia International Physics Center)

  • Sixto Giménez

    (Institute of Advanced Materials (INAM), Universitat Jaume I)

  • Maria Chiara Spadaro

    (Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC and BIST)

  • Jordi Arbiol

    (Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC and BIST
    ICREA, Passeig Lluis Companys, 23)

  • Sara Barja

    (University of the Basque Country UPV/EHU
    Donostia International Physics Center)

  • José Ramón Galán-Mascarós

    (Institute of Chemical Research of Catalonia (ICIQ), The Barcelona Institute of Science and Technology (BIST)
    ICREA, Passeig Lluis Companys, 23)

Abstract

Earth-abundant electrocatalysts for the oxygen evolution reaction (OER) able to work in acidic working conditions are elusive. While many first-row transition metal oxides are competitive in alkaline media, most of them just dissolve or become inactive at high proton concentrations where hydrogen evolution is preferred. Only noble-metal catalysts, such as IrO2, are fast and stable enough in acidic media. Herein, we report the excellent activity and long-term stability of Co3O4-based anodes in 1 M H2SO4 (pH 0.1) when processed in a partially hydrophobic carbon-based protecting matrix. These Co3O4@C composites reliably drive O2 evolution a 10 mA cm–2 current density for >40 h without appearance of performance fatigue, successfully passing benchmarking protocols without incorporating noble metals. Our strategy opens an alternative venue towards fast, energy efficient acid-media water oxidation electrodes.

Suggested Citation

  • Jiahao Yu & Felipe A. Garcés-Pineda & Jesús González-Cobos & Marina Peña-Díaz & Celia Rogero & Sixto Giménez & Maria Chiara Spadaro & Jordi Arbiol & Sara Barja & José Ramón Galán-Mascarós, 2022. "Sustainable oxygen evolution electrocatalysis in aqueous 1 M H2SO4 with earth abundant nanostructured Co3O4," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-32024-6
    DOI: 10.1038/s41467-022-32024-6
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-022-32024-6
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-022-32024-6?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. Sharma, Sunita & Ghoshal, Sib Krishna, 2015. "Hydrogen the future transportation fuel: From production to applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 43(C), pages 1151-1158.
    2. Yong-Tae Kim & Pietro Papa Lopes & Shin-Ae Park & A-Yeong Lee & Jinkyu Lim & Hyunjoo Lee & Seoin Back & Yousung Jung & Nemanja Danilovic & Vojislav Stamenkovic & Jonah Erlebacher & Joshua Snyder & Nen, 2017. "Balancing activity, stability and conductivity of nanoporous core-shell iridium/iridium oxide oxygen evolution catalysts," Nature Communications, Nature, vol. 8(1), pages 1-8, December.
    3. Singh, Sonal & Jain, Shikha & PS, Venkateswaran & Tiwari, Avanish K. & Nouni, Mansa R. & Pandey, Jitendra K. & Goel, Sanket, 2015. "Hydrogen: A sustainable fuel for future of the transport sector," Renewable and Sustainable Energy Reviews, Elsevier, vol. 51(C), pages 623-633.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Sehatpour, Mohammad-Hadi & Kazemi, Aliyeh & Sehatpour, Hesam-eddin, 2017. "Evaluation of alternative fuels for light-duty vehicles in Iran using a multi-criteria approach," Renewable and Sustainable Energy Reviews, Elsevier, vol. 72(C), pages 295-310.
    2. Alviani, Vani Novita & Hirano, Nobuo & Watanabe, Noriaki & Oba, Masahiro & Uno, Masaoki & Tsuchiya, Noriyoshi, 2021. "Local initiative hydrogen production by utilization of aluminum waste materials and natural acidic hot-spring water," Applied Energy, Elsevier, vol. 293(C).
    3. Qi, Meng & Park, Jinwoo & Lee, Inkyu & Moon, Il, 2022. "Liquid air as an emerging energy vector towards carbon neutrality: A multi-scale systems perspective," Renewable and Sustainable Energy Reviews, Elsevier, vol. 159(C).
    4. Burton, N.A. & Padilla, R.V. & Rose, A. & Habibullah, H., 2021. "Increasing the efficiency of hydrogen production from solar powered water electrolysis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).
    5. Navas-Anguita, Zaira & García-Gusano, Diego & Iribarren, Diego, 2019. "A review of techno-economic data for road transportation fuels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 112(C), pages 11-26.
    6. Alina E. Kozhukhova & Stephanus P. du Preez & Dmitri G. Bessarabov, 2021. "Catalytic Hydrogen Combustion for Domestic and Safety Applications: A Critical Review of Catalyst Materials and Technologies," Energies, MDPI, vol. 14(16), pages 1-32, August.
    7. Zhang, Peiye & Liu, Ming & Mu, Ruiqi & Yan, Junjie, 2024. "Exergy-based control strategy design and dynamic performance enhancement for parabolic trough solar receiver-reactor of methanol decomposition reaction," Renewable Energy, Elsevier, vol. 224(C).
    8. Rahman, Syed & Khan, Irfan Ahmed & Khan, Ashraf Ali & Mallik, Ayan & Nadeem, Muhammad Faisal, 2022. "Comprehensive review & impact analysis of integrating projected electric vehicle charging load to the existing low voltage distribution system," Renewable and Sustainable Energy Reviews, Elsevier, vol. 153(C).
    9. Kleperis Jānis & Sloka Biruta & Dimants Justs & Dimanta Ilze & Kleperis Jānis, 2016. "Solution to Urban Air Pollution – Carbon Free Transport," Baltic Journal of Real Estate Economics and Construction Management, Sciendo, vol. 4(1), pages 32-47, November.
    10. Mostafa Rezaei & Ali Mostafaeipour & Mojtaba Qolipour & Hamid-Reza Arabnia, 2018. "Hydrogen production using wind energy from sea water: A case study on Southern and Northern coasts of Iran," Energy & Environment, , vol. 29(3), pages 333-357, May.
    11. Zhaohua Wang & Chunyang Dong & Xuan Tang & Xuetao Qin & Xingwu Liu & Mi Peng & Yao Xu & Chuqiao Song & Jie Zhang & Xuan Liang & Sheng Dai & Ding Ma, 2022. "CO-tolerant RuNi/TiO2 catalyst for the storage and purification of crude hydrogen," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    12. Bailera, Manuel & Lisbona, Pilar & Romeo, Luis M. & Espatolero, Sergio, 2016. "Power to Gas–biomass oxycombustion hybrid system: Energy integration and potential applications," Applied Energy, Elsevier, vol. 167(C), pages 221-229.
    13. Mohammadi, Mohammad & Noorollahi, Younes & Mohammadi-ivatloo, Behnam & Yousefi, Hossein, 2017. "Energy hub: From a model to a concept – A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 80(C), pages 1512-1527.
    14. Hao, Han & Liu, Zongwei & Zhao, Fuquan & Li, Weiqi, 2016. "Natural gas as vehicle fuel in China: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 62(C), pages 521-533.
    15. Arash Khalilnejad & Aditya Sundararajan & Alireza Abbaspour & Arif Sarwat, 2016. "Optimal Operation of Combined Photovoltaic Electrolyzer Systems," Energies, MDPI, vol. 9(5), pages 1-12, April.
    16. Chen, Scarlett & Kumar, Anikesh & Wong, Wee Chin & Chiu, Min-Sen & Wang, Xiaonan, 2019. "Hydrogen value chain and fuel cells within hybrid renewable energy systems: Advanced operation and control strategies," Applied Energy, Elsevier, vol. 233, pages 321-337.
    17. Ahmad Nazrul Hakimi Ibrahim & Muhamad Nazri Borhan & Riza Atiq O.K. Rahmat, 2020. "Understanding Users’ Intention to Use Park-and-Ride Facilities in Malaysia: The Role of Trust as a Novel Construct in the Theory of Planned Behaviour," Sustainability, MDPI, vol. 12(6), pages 1-14, March.
    18. Ajanovic, Amela & Sayer, Marlene & Haas, Reinhard, 2024. "On the future relevance of green hydrogen in Europe," Applied Energy, Elsevier, vol. 358(C).
    19. Sagir, Emrah & Alipour, Siamak, 2021. "Photofermentative hydrogen production by immobilized photosynthetic bacteria: Current perspectives and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 141(C).
    20. Zheng, Jianpeng & Chen, Liubiao & Liu, Xuming & Zhu, Honglai & Zhou, Yuan & Wang, Junjie, 2020. "Thermodynamic optimization of composite insulation system with cold shield for liquid hydrogen zero-boil-off storage," Renewable Energy, Elsevier, vol. 147(P1), pages 824-832.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-32024-6. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.