IDEAS home Printed from https://ideas.repec.org/a/nat/natcom/v13y2022i1d10.1038_s41467-022-29092-z.html
   My bibliography  Save this article

Resonant neutron reflectometry for hydrogen detection

Author

Listed:
  • L. Guasco

    (Max-Planck-Institut für Festkörperforschung
    Max Planck Society Outstation at the Heinz Maier-Leibnitz Zentrum (MLZ))

  • Yu. N. Khaydukov

    (Max-Planck-Institut für Festkörperforschung
    Max Planck Society Outstation at the Heinz Maier-Leibnitz Zentrum (MLZ))

  • S. Pütter

    (Forschungszentrum Jülich GmbH, Jülich Centre for Neutron Science (JCNS) at Heinz Maier-Leibnitz Zentrum (MLZ))

  • L. Silvi

    (Helmholtz Zentrum Berlin)

  • M. A. Paulin

    (Helmholtz Zentrum Berlin
    Laboratorio Argentino de Haces de Neutrones, CAB, CNEA)

  • T. Keller

    (Max-Planck-Institut für Festkörperforschung
    Max Planck Society Outstation at the Heinz Maier-Leibnitz Zentrum (MLZ))

  • B. Keimer

    (Max-Planck-Institut für Festkörperforschung)

Abstract

The detection and quantification of hydrogen is becoming increasingly important in research on electronic materials and devices, following the identification of the hydrogen content as a potent control parameter for the electronic properties. However, establishing quantitative correlations between the hydrogen content and the physical properties of solids remains a formidable challenge. Here we report neutron reflectometry experiments on 50 nm thick niobium films during hydrogen loading, and show that the momentum-space position of a prominent waveguide resonance allows tracking of the absolute hydrogen content with an accuracy of about one atomic percent on a timescale of less than a minute. Resonance-enhanced neutron reflectometry thus allows fast, direct, and non-destructive measurements of the hydrogen concentration in thin-film structures, with sensitivity high enough for real-time in-situ studies.

Suggested Citation

  • L. Guasco & Yu. N. Khaydukov & S. Pütter & L. Silvi & M. A. Paulin & T. Keller & B. Keimer, 2022. "Resonant neutron reflectometry for hydrogen detection," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-29092-z
    DOI: 10.1038/s41467-022-29092-z
    as

    Download full text from publisher

    File URL: https://www.nature.com/articles/s41467-022-29092-z
    File Function: Abstract
    Download Restriction: no
    File URL: https://libkey.io/10.1038/s41467-022-29092-z?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    References listed on IDEAS

    as
    1. K. Kitagawa & T. Takayama & Y. Matsumoto & A. Kato & R. Takano & Y. Kishimoto & S. Bette & R. Dinnebier & G. Jackeli & H. Takagi, 2018. "A spin–orbital-entangled quantum liquid on a honeycomb lattice," Nature, Nature, vol. 554(7692), pages 341-345, February.
    2. Jian Shi & You Zhou & Shriram Ramanathan, 2014. "Colossal resistance switching and band gap modulation in a perovskite nickelate by electron doping," Nature Communications, Nature, vol. 5(1), pages 1-9, December.
    3. C. Boelsma & L. J. Bannenberg & M. J. van Setten & N.-J. Steinke & A. A. van Well & B. Dam, 2017. "Hafnium—an optical hydrogen sensor spanning six orders in pressure," Nature Communications, Nature, vol. 8(1), pages 1-8, August.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. G. Cassella & P. d’Ornellas & T. Hodson & W. M. H. Natori & J. Knolle, 2023. "An exact chiral amorphous spin liquid," Nature Communications, Nature, vol. 14(1), pages 1-6, December.
    2. Haiming Deng & Lukas Zhao & Kyungwha Park & Jiaqiang Yan & Kamil Sobczak & Ayesha Lakra & Entela Buzi & Lia Krusin-Elbaum, 2022. "Topological surface currents accessed through reversible hydrogenation of the three-dimensional bulk," Nature Communications, Nature, vol. 13(1), pages 1-8, December.
    3. Yifan Yuan & Michele Kotiuga & Tae Joon Park & Ranjan Kumar Patel & Yuanyuan Ni & Arnob Saha & Hua Zhou & Jerzy T. Sadowski & Abdullah Al-Mahboob & Haoming Yu & Kai Du & Minning Zhu & Sunbin Deng & Ra, 2024. "Hydrogen-induced tunable remanent polarization in a perovskite nickelate," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    4. S. V. Syzranov & A. P. Ramirez, 2022. "Eminuscent phase in frustrated magnets: a challenge to quantum spin liquids," Nature Communications, Nature, vol. 13(1), pages 1-6, December.
    5. A. Torre & B. Zager & F. Bahrami & M. H. Upton & J. Kim & G. Fabbris & G.-H. Lee & W. Yang & D. Haskel & F. Tafti & K. W. Plumb, 2023. "Momentum-independent magnetic excitation continuum in the honeycomb iridate H3LiIr2O6," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    6. Neda Alsadat Aghamiri & Guangwei Hu & Alireza Fali & Zhen Zhang & Jiahan Li & Sivacarendran Balendhran & Sumeet Walia & Sharath Sriram & James H. Edgar & Shriram Ramanathan & Andrea Alù & Yohannes Aba, 2022. "Reconfigurable hyperbolic polaritonics with correlated oxide metasurfaces," Nature Communications, Nature, vol. 13(1), pages 1-9, December.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-022-29092-z. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Sonal Shukla or Springer Nature Abstracting and Indexing (email available below). General contact details of provider: http://www.nature.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.