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Photocontrolled multiple-state photochromic benzo[b]phosphole thieno[3,2-b]phosphole-containing alkynylgold(I) complex via selective light irradiation

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  • Nathan Man-Wai Wu

    (The University of Hong Kong)

  • Maggie Ng

    (The University of Hong Kong)

  • Vivian Wing-Wah Yam

    (The University of Hong Kong)

Abstract

Photochromic materials have drawn growing attention because using light as a stimulus has been regarded as a convenient and environmental-friendly way to control properties of smart materials. While photoresponsive systems that are capable of showing multiple-state photochromism are attractive, the development of materials with such capabilities has remained a challenging task. Here we show that a benzo[b]phosphole thieno[3,2‑b]phosphole-containing alkynylgold(I) complex features multiple photoinduced color changes, in which the gold(I) metal center plays an important role in separating two photoactive units that leads to the suppression of intramolecular quenching processes of the excited states. More importantly, the exclusive photochemical reactivity of the thieno[3,2‑b]phosphole moiety of the gold(I) complex can be initiated upon photoirradiation of visible light. Stepwise photochromism of the gold(I) complex has been made possible, offering an effective strategy for the construction of multiple-state photochromic materials with multiple photocontrolled states to enhance the storage capacity of potential optical memory devices.

Suggested Citation

  • Nathan Man-Wai Wu & Maggie Ng & Vivian Wing-Wah Yam, 2022. "Photocontrolled multiple-state photochromic benzo[b]phosphole thieno[3,2-b]phosphole-containing alkynylgold(I) complex via selective light irradiation," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
  • Handle: RePEc:nat:natcom:v:13:y:2022:i:1:d:10.1038_s41467-021-27711-9
    DOI: 10.1038/s41467-021-27711-9
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    Cited by:

    1. Adil Majeed Rather & Sravanthi Vallabhuneni & Austin J. Pyrch & Mohammed Barrubeeah & Sreekiran Pillai & Arsalan Taassob & Felix N. Castellano & Arun Kumar Kota, 2024. "Color morphing surfaces with effective chemical shielding," Nature Communications, Nature, vol. 15(1), pages 1-7, December.

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