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Generating circularly polarized luminescence from clusterization‐triggered emission using solid phase molecular self-assembly

Author

Listed:
  • Peilong Liao

    (Peking University)

  • Shihao Zang

    (Peking University)

  • Tongyue Wu

    (Peking University)

  • Hongjun Jin

    (Peking University)

  • Wenkai Wang

    (Peking University)

  • Jianbin Huang

    (Peking University)

  • Ben Zhong Tang

    (The Chinese University of Hong Kong)

  • Yun Yan

    (Peking University)

Abstract

Purely-organic clusterization‐triggered emission (CTE) has displayed promising abilities in bioimaging, chemical sensing, and multicolor luminescence. However, it remains absent in the field of circularly polarized luminescence (CPL) due to the difficulties in well-aligning the nonconventional luminogens. We report a case of CPL generated with CTE using the solid phase molecular self-assembly (SPMSA) of poly-L-lysine (PLL) and oleate ion (OL), that is, the macroscopic CPL supramolecular film self-assembled by the electrostatic complex of PLL/OL under mechanical pressure. Well-defined interface charge distribution, given by lamellar mesophases of OL ions, forces the PLL chains to fold regularly as a requirement of optimal electrostatic interactions. Further facilitated by hydrogen bonding, the through-space conjugation (TSC) of orderly aligned electron-rich O and N atoms leads to CTE-based CPL, which is capable of transferring energy to an acceptor via a Förster resonance energy transfer (FRET) process, making it possible to develop environmentally friendly and economic CPL from sustainable and renewable materials.

Suggested Citation

  • Peilong Liao & Shihao Zang & Tongyue Wu & Hongjun Jin & Wenkai Wang & Jianbin Huang & Ben Zhong Tang & Yun Yan, 2021. "Generating circularly polarized luminescence from clusterization‐triggered emission using solid phase molecular self-assembly," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    • Handle: RePEc:nat:natcom:v:12:y:2021:i:1:d:10.1038_s41467-021-25789-9
    DOI: 10.1038/s41467-021-25789-9
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    Cited by:

    1. Yipu Wang & Jianyu Zhang & Qingyang Xu & Weihao Tu & Lei Wang & Yuan Xie & Jing Zhi Sun & Feihe Huang & Haoke Zhang & Ben Zhong Tang, 2024. "Narrowband clusteroluminescence with 100% quantum yield enabled by through-space conjugation of asymmetric conformation," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    2. Tianwen Zhu & Tianjia Yang & Qiang Zhang & Wang Zhang Yuan, 2022. "Clustering and halogen effects enabled red/near-infrared room temperature phosphorescence from aliphatic cyclic imides," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    3. Qiuju Li & Xingyi Wang & Qisu Huang & Zhuo Li & Ben Zhong Tang & Shun Mao, 2023. "Molecular-level enhanced clusterization-triggered emission of nonconventional luminophores in dilute aqueous solution," Nature Communications, Nature, vol. 14(1), pages 1-11, December.

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