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A general approach to high-efficiency perovskite solar cells by any antisolvent

Author

Listed:
  • Alexander D. Taylor

    (Ruprecht-Karls-Universität Heidelberg
    Technische Universität Dresden
    Technische Universität Dresden)

  • Qing Sun

    (Ruprecht-Karls-Universität Heidelberg)

  • Katelyn P. Goetz

    (Ruprecht-Karls-Universität Heidelberg
    Technische Universität Dresden
    Technische Universität Dresden)

  • Qingzhi An

    (Ruprecht-Karls-Universität Heidelberg
    Technische Universität Dresden
    Technische Universität Dresden)

  • Tim Schramm

    (Technische Universität Dresden)

  • Yvonne Hofstetter

    (Ruprecht-Karls-Universität Heidelberg
    Technische Universität Dresden
    Technische Universität Dresden)

  • Maximillian Litterst

    (Ruprecht-Karls-Universität Heidelberg)

  • Fabian Paulus

    (Ruprecht-Karls-Universität Heidelberg
    Technische Universität Dresden)

  • Yana Vaynzof

    (Ruprecht-Karls-Universität Heidelberg
    Technische Universität Dresden
    Technische Universität Dresden)

Abstract

Deposition of perovskite films by antisolvent engineering is a highly common method employed in perovskite photovoltaics research. Herein, we report on a general method that allows for the fabrication of highly efficient perovskite solar cells by any antisolvent via manipulation of the antisolvent application rate. Through detailed structural, compositional, and microstructural characterization of perovskite layers fabricated by 14 different antisolvents, we identify two key factors that influence the quality of the perovskite layer: the solubility of the organic precursors in the antisolvent and its miscibility with the host solvent(s) of the perovskite precursor solution, which combine to produce rate-dependent behavior during the antisolvent application step. Leveraging this, we produce devices with power conversion efficiencies (PCEs) that exceed 21% using a wide range of antisolvents. Moreover, we demonstrate that employing the optimal antisolvent application procedure allows for highly efficient solar cells to be fabricated from a broad range of precursor stoichiometries.

Suggested Citation

  • Alexander D. Taylor & Qing Sun & Katelyn P. Goetz & Qingzhi An & Tim Schramm & Yvonne Hofstetter & Maximillian Litterst & Fabian Paulus & Yana Vaynzof, 2021. "A general approach to high-efficiency perovskite solar cells by any antisolvent," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
    • Handle: RePEc:nat:natcom:v:12:y:2021:i:1:d:10.1038_s41467-021-22049-8
    DOI: 10.1038/s41467-021-22049-8
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    Cited by:

    1. Ouedraogo, Nabonswende Aida Nadege & Odunmbaku, George Omololu & Ouyang, Yunfei & Xiong, Xiqiu & Guo, Bing & Chen, Shanshan & Lu, Shirong & Sun, Kuan, 2024. "Eco-friendly processing of perovskite solar cells in ambient air," Renewable and Sustainable Energy Reviews, Elsevier, vol. 192(C).
    2. Tian Chen & Jiangsheng Xie & Bin Wen & Qixin Yin & Ruohao Lin & Shengcai Zhu & Pingqi Gao, 2023. "Inhibition of defect-induced α-to-δ phase transition for efficient and stable formamidinium perovskite solar cells," Nature Communications, Nature, vol. 14(1), pages 1-9, December.

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