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Metal-free atom transfer radical polymerization with ppm catalyst loading under sunlight

Author

Listed:
  • Qiang Ma

    (Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), College of Chemistry, Fuzhou University)

  • Jinshuai Song

    (Zhengzhou University)

  • Xun Zhang

    (Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), College of Chemistry, Fuzhou University)

  • Yu Jiang

    (Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), College of Chemistry, Fuzhou University)

  • Li Ji

    (Grubbs Institute, Southern University of Science and Technology)

  • Saihu Liao

    (Key Laboratory of Molecule Synthesis and Function Discovery (Fujian Province University), College of Chemistry, Fuzhou University
    Fuzhou University
    Beijing National Laboratory of Molecular Science (BNLMS))

Abstract

Organocatalytic atom transfer radical polymerization (O-ATRP) is recently emerging as an appealing method for the synthesis of metal-free polymer materials with well-defined microstructures and architectures. However, the development of highly effective catalysts that can be employed at a practical low loading are still a challenging task. Herein, we introduce a catalyst design logic based on heteroatom-doping of polycyclic arenes, which leads to the discovery of oxygen-doped anthanthrene (ODA) as highly effective organic photoredox catalysts for O-ATRP. In comparison with known organocatalysts, ODAs feature strong visible-light absorption together with high molar extinction coefficient (ε455nm up to 23,950 M–1 cm–1), which allow for the establishment of a controlled polymerization under sunlight at low ppm levels of catalyst loading.

Suggested Citation

  • Qiang Ma & Jinshuai Song & Xun Zhang & Yu Jiang & Li Ji & Saihu Liao, 2021. "Metal-free atom transfer radical polymerization with ppm catalyst loading under sunlight," Nature Communications, Nature, vol. 12(1), pages 1-8, December.
    • Handle: RePEc:nat:natcom:v:12:y:2021:i:1:d:10.1038_s41467-020-20645-8
    DOI: 10.1038/s41467-020-20645-8
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    Cited by:

    1. Lei Wang & Yupo Xu & Quan Zuo & Haojie Dai & Lei Huang & Meng Zhang & Yongli Zheng & Chunyang Yu & Shaodong Zhang & Yongfeng Zhou, 2022. "Visible light-controlled living cationic polymerization of methoxystyrene," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    2. Wei-Wei Fang & Gui-Yu Yang & Zi-Hui Fan & Zi-Chao Chen & Xun-Liang Hu & Zhen Zhan & Irshad Hussain & Yang Lu & Tao He & Bi-En Tan, 2023. "Conjugated cross-linked phosphine as broadband light or sunlight-driven photocatalyst for large-scale atom transfer radical polymerization," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    3. Woojin Jeon & Yonghwan Kwon & Min Sang Kwon, 2024. "Highly efficient dual photoredox/copper catalyzed atom transfer radical polymerization achieved through mechanism-driven photocatalyst design," Nature Communications, Nature, vol. 15(1), pages 1-13, December.

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