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Efficient electrochemical production of glucaric acid and H2 via glucose electrolysis

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  • Wu-Jun Liu

    (University of Science & Technology of China
    University of Wisconsin-Madison)

  • Zhuoran Xu

    (University of Wisconsin-Madison)

  • Dongting Zhao

    (University of Wisconsin-Madison)

  • Xiao-Qiang Pan

    (University of Science & Technology of China)

  • Hong-Chao Li

    (University of Science & Technology of China)

  • Xiao Hu

    (University of Science & Technology of China)

  • Zhi-Yong Fan

    (Tongji University)

  • Wei-Kang Wang

    (Tongji University)

  • Guo-Hua Zhao

    (Tongji University)

  • Song Jin

    (University of Wisconsin-Madison)

  • George W. Huber

    (University of Wisconsin-Madison)

  • Han-Qing Yu

    (University of Science & Technology of China)

Abstract

Glucose electrolysis offers a prospect of value-added glucaric acid synthesis and energy-saving hydrogen production from the biomass-based platform molecules. Here we report that nanostructured NiFe oxide (NiFeOx) and nitride (NiFeNx) catalysts, synthesized from NiFe layered double hydroxide nanosheet arrays on three-dimensional Ni foams, demonstrate a high activity and selectivity towards anodic glucose oxidation. The electrolytic cell assembled with these two catalysts can deliver 100 mA cm−2 at 1.39 V. A faradaic efficiency of 87% and glucaric acid yield of 83% are obtained from the glucose electrolysis, which takes place via a guluronic acid pathway evidenced by in-situ infrared spectroscopy. A rigorous process model combined with a techno-economic analysis shows that the electrochemical reduction of glucose produces glucaric acid at a 54% lower cost than the current chemical approach. This work suggests that glucose electrolysis is an energy-saving and cost-effective approach for H2 production and biomass valorization.

Suggested Citation

  • Wu-Jun Liu & Zhuoran Xu & Dongting Zhao & Xiao-Qiang Pan & Hong-Chao Li & Xiao Hu & Zhi-Yong Fan & Wei-Kang Wang & Guo-Hua Zhao & Song Jin & George W. Huber & Han-Qing Yu, 2020. "Efficient electrochemical production of glucaric acid and H2 via glucose electrolysis," Nature Communications, Nature, vol. 11(1), pages 1-11, December.
    • Handle: RePEc:nat:natcom:v:11:y:2020:i:1:d:10.1038_s41467-019-14157-3
    DOI: 10.1038/s41467-019-14157-3
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    Cited by:

    1. Yuan, Chen & Liu, Zailun & Gu, Wenhao & Teng, Fei & Hao, Weiyi & Hussain, Shah Abid & Jiang, Wenjun, 2021. "Hydrogen production performance of novel glycerin-based electrolytic cell," Renewable Energy, Elsevier, vol. 167(C), pages 862-868.
    2. Ke Xie & Adnan Ozden & Rui Kai Miao & Yuhang Li & David Sinton & Edward H. Sargent, 2022. "Eliminating the need for anodic gas separation in CO2 electroreduction systems via liquid-to-liquid anodic upgrading," Nature Communications, Nature, vol. 13(1), pages 1-9, December.
    3. Ying, Zhi & Geng, Zhen & Zheng, Xiaoyuan & Dou, Binlin & Cui, Guomin, 2022. "Improving water electrolysis assisted by anodic biochar oxidation for clean hydrogen production," Energy, Elsevier, vol. 238(PB).
    4. Jun Qi & Yadong Du & Qi Yang & Na Jiang & Jiachun Li & Yi Ma & Yangjun Ma & Xin Zhao & Jieshan Qiu, 2023. "Energy-saving and product-oriented hydrogen peroxide electrosynthesis enabled by electrochemistry pairing and product engineering," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    5. Nie, Yifan & Hou, Qidong & Qian, Hengli & Bai, Xinyu & Xia, Tianliang & Lai, Ruite & Yu, Guanjie & Rehman, Mian Laiq Ur & Ju, Meiting, 2022. "Synthesis of mesoporous sulfonated carbon from chicken bones to boost rapid conversion of 5-hydroxymethylfurfural and carbohydrates to 5-ethoxymethylfurfural," Renewable Energy, Elsevier, vol. 192(C), pages 279-288.
    6. Kumar, Manish & Bolan, Shiv & Padhye, Lokesh P. & Konarova, Muxina & Foong, Shin Ying & Lam, Su Shiung & Wagland, Stuart & Cao, Runzi & Li, Yang & Batalha, Nuno & Ahmed, Mohamed & Pandey, Ashok & Sidd, 2023. "Retrieving back plastic wastes for conversion to value added petrochemicals: opportunities, challenges and outlooks," Applied Energy, Elsevier, vol. 345(C).
    7. Zuyun He & Jinwoo Hwang & Zhiheng Gong & Mengzhen Zhou & Nian Zhang & Xiongwu Kang & Jeong Woo Han & Yan Chen, 2022. "Promoting biomass electrooxidation via modulating proton and oxygen anion deintercalation in hydroxide," Nature Communications, Nature, vol. 13(1), pages 1-10, December.
    8. Zhangliu Tian & Yumin Da & Meng Wang & Xinyu Dou & Xinhang Cui & Jie Chen & Rui Jiang & Shibo Xi & Baihua Cui & Yani Luo & Haotian Yang & Yu Long & Yukun Xiao & Wei Chen, 2023. "Selective photoelectrochemical oxidation of glucose to glucaric acid by single atom Pt decorated defective TiO2," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    9. Zhou, Wei & Chen, Shuai & Meng, Xiaoxiao & Li, Jiayi & Huang, Yuming & Gao, Jihui & Zhao, Guangbo & He, Yong & Qin, Yukun, 2022. "Two-step coal-assisted water electrolysis for energy-saving hydrogen production at cell voltage of 1.2 V with current densities larger than 150 mA/cm2," Energy, Elsevier, vol. 260(C).
    10. Ying, Zhi & Du, Yueyue & Gu, Xufei & Yu, Xiaosha & Zheng, Xiaoyuan & Dou, Binlin & Cui, Guomin, 2024. "Biochar-assisted water electrolysis for energy-saving hydrogen production: Evolution of corn straw-based biochar structure and its enhanced effect on Cr(VI) removal," Energy, Elsevier, vol. 305(C).

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