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Structural Characterization of Geopolymers with the Addition of Eggshell Ash

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  • Marija Ivanović

    (Department of Materials, Vinča Institute of Nuclear Sciences, National Institute of the Republic of Serbia, University of Belgrade, Mike Petrović Alasa 12-14, Vinča, 11000 Belgrade, Serbia)

  • Sanja Knežević

    (Department of Materials, Vinča Institute of Nuclear Sciences, National Institute of the Republic of Serbia, University of Belgrade, Mike Petrović Alasa 12-14, Vinča, 11000 Belgrade, Serbia)

  • Miljana M. Mirković

    (Department of Materials, Vinča Institute of Nuclear Sciences, National Institute of the Republic of Serbia, University of Belgrade, Mike Petrović Alasa 12-14, Vinča, 11000 Belgrade, Serbia)

  • Ljiljana Kljajević

    (Department of Materials, Vinča Institute of Nuclear Sciences, National Institute of the Republic of Serbia, University of Belgrade, Mike Petrović Alasa 12-14, Vinča, 11000 Belgrade, Serbia)

  • Dušan Bučevac

    (Department of Materials, Vinča Institute of Nuclear Sciences, National Institute of the Republic of Serbia, University of Belgrade, Mike Petrović Alasa 12-14, Vinča, 11000 Belgrade, Serbia)

  • Vladimir B. Pavlović

    (Institute of Technical Sciences of the Serbian Academy of Sciences and Arts, University of Belgrade, 11000 Belgrade, Serbia)

  • Miloš Nenadović

    (Department of Atomics Physics, Vinča Institute of Nuclear Sciences, National Institute of the Republic of Serbia, Mike Petrović Alasa 12-14, Vinča, 11000 Belgrade, Serbia)

Abstract

It is well known that geopolymers are a new group of binder materials of alumosilicate origin. Geopolymers are made by the reaction of precursor aluminosilicate materials with alkaline activator solutions. The current research relates to a low-cost and eco-friendly procedure, suitable of being implemented in two easy steps. The first step is the production of a solid phase based on fly ash (Obrenovac, Serbia) and eggshell ash as waste materials rich in calcium. The second step is alkali activating the solid phase using an alkaline activator (a mixture of NaOH and Na 2 SiO 3 ) and procedures in proper laboratory conditions. Four samples with different eggshell ash content were synthesized. The concentration of used NaOH was 12 mol dm −3 . The structural properties of all investigated samples were analyzed by XRD ( X-ray diffraction ), DRIFT ( diffuse reflectance infrared Fourier transform ), SEM ( scanning electron microscopy ) and UV/Vis spectroscopy analysis. XRD determined the amorphous halo with the presence of quartz as the crystal phase in all of the investigated samples. These results were confirmed by DRIFT analysis. The morphology of the samples was determined by SEM analysis. UV/Vis showed that the material could be a potential adsorbent.

Suggested Citation

  • Marija Ivanović & Sanja Knežević & Miljana M. Mirković & Ljiljana Kljajević & Dušan Bučevac & Vladimir B. Pavlović & Miloš Nenadović, 2023. "Structural Characterization of Geopolymers with the Addition of Eggshell Ash," Sustainability, MDPI, vol. 15(6), pages 1-13, March.
  • Handle: RePEc:gam:jsusta:v:15:y:2023:i:6:p:5419-:d:1101222
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    References listed on IDEAS

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    1. Memduh Karalar & Yasin Onuralp Özkılıç & Ahmed Farouk Deifalla & Ceyhun Aksoylu & Musa Hakan Arslan & Mahmood Ahmad & Mohanad Muayad Sabri Sabri, 2022. "Improvement in Bending Performance of Reinforced Concrete Beams Produced with Waste Lathe Scraps," Sustainability, MDPI, vol. 14(19), pages 1-17, October.
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