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A Numerical Study of Vapor–Liquid Equilibrium in Binary Refrigerant Mixtures Based on 2,3,3,3-Tetrafluoroprop-1-ene

Author

Listed:
  • Li Sun

    (College of Mechanical and Electrical Engineering, Hohai University, Changzhou 213022, China)

  • Jierong Liang

    (MagnoTherm Solutions GmbH, Pfungstädter Str. 102, 64297 Darmstadt, Germany)

  • Tingting Zhu

    (Department of Thermal and Fluid Engineering, Faculty of Engineering Technology (ET), University of Twente, 7522 NB Enschede, The Netherlands)

Abstract

The binary refrigerant mixtures containing 2,3,3,3-Tetrafluoroprop-1-ene are considered as excellent substitutes for traditional refrigerants. Weak hydrogen bonds exist in hydrofluorocarbons and hydrofluoroolefins. However, for several recently published binary refrigerant mixtures, there is no Vapor–Liquid Equilibrium calculation study considering hydrogen-bonding associations. This work presents a calculation work of the saturated properties of nine pure refrigerants using the Cubic-Plus-Association Equation of State, considering the hydrogen-bonding association in refrigerant fluids. The average relative deviations of the saturated vapor pressure, liquid, and vapor density are less than 1.0%, 1.5%, and 3.5%, respectively. The Vapor–Liquid Equilibrium of ten binary refrigerant mixtures containing 2,3,3,3-Tetrafluoroprop-1-ene is also calculated using the Cubic-Plus-Association Equation of State with the van der Waals mixing rule. The average relative deviations of the liquid-phase and vapor-phase mole fractions are less than 1.0% and 2.0%, respectively. Moreover, the Vapor–Liquid Equilibrium data and the model’s adaptability are analyzed and discussed.

Suggested Citation

  • Li Sun & Jierong Liang & Tingting Zhu, 2023. "A Numerical Study of Vapor–Liquid Equilibrium in Binary Refrigerant Mixtures Based on 2,3,3,3-Tetrafluoroprop-1-ene," Sustainability, MDPI, vol. 15(19), pages 1-22, October.
    • Handle: RePEc:gam:jsusta:v:15:y:2023:i:19:p:14482-:d:1253626
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    References listed on IDEAS

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    1. Khem Raj Gautam & Gorm Brunn Andresen & Marta Victoria, 2022. "Review and Techno-Economic Analysis of Emerging Thermo-Mechanical Energy Storage Technologies," Energies, MDPI, vol. 15(17), pages 1-28, August.
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