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Struvite Precipitation from Centrate—Identifying the Best Balance Between Effectiveness and Resource Efficiency

Author

Listed:
  • Andreas Kolb

    (Institute of Sanitary and Environmental Engineering, Technische Universität Braunschweig, Pockelsstraße 2a, 38106 Braunschweig, Germany)

  • Tim Gebhardt

    (Institute of Sanitary and Environmental Engineering, Technische Universität Braunschweig, Pockelsstraße 2a, 38106 Braunschweig, Germany)

  • Thomas Dockhorn

    (Institute of Sanitary and Environmental Engineering, Technische Universität Braunschweig, Pockelsstraße 2a, 38106 Braunschweig, Germany)

Abstract

In the context of struvite precipitation, the most significant gap pertains to the transfer of knowledge from scientific research to practical applications. The primary objective of this study is twofold: firstly, to identify the most critical process parameters influencing struvite precipitation and, secondly, to translate these parameters into a pragmatic tool for real-world applications. This study investigates the precipitation of struvite from digestion centrate to obtain information on the appropriate precipitation conditions for different initial chemical compositions. We carried out 24 lab-scale experiments to investigate the effect of varying pH value (7.0–8.5), temperature (5 °C and 33 °C) and initial phosphate concentrations (353; 165; 68 mg/L) on struvite precipitation. Varying the pH had the strongest influence on precipitation efficiencies. Adjusting pH from 7 to 8.5 increased PO 4 -P removal from 1.4% to 98.8%, whereas temperature had little impact on PO 4 -P removal. Furthermore, we found that a saturation index of at least 1.7 is imperative to precipitate at least 90% of the available PO 4 -P. Based on the results, we developed a nomogram showing the resulting saturation index and the associated PO 4 -P removal efficiency for variable initial PO 4 -P and pH levels. The tool developed in this study enables users to directly identify the so-called ‘sweet spot’, which is the optimal balance between process effectiveness and resource efficiency, for each centrate.

Suggested Citation

  • Andreas Kolb & Tim Gebhardt & Thomas Dockhorn, 2025. "Struvite Precipitation from Centrate—Identifying the Best Balance Between Effectiveness and Resource Efficiency," Resources, MDPI, vol. 14(4), pages 1-18, March.
  • Handle: RePEc:gam:jresou:v:14:y:2025:i:4:p:56-:d:1622810
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    References listed on IDEAS

    as
    1. Işık Kabdaşlı & Alessio Siciliano & Carlo Limonti & Olcay Tünay, 2022. "Is K-Struvite Precipitation a Plausible Nutrient Recovery Method from Potassium-Containing Wastes?—A Review," Sustainability, MDPI, vol. 14(18), pages 1-35, September.
    2. Carolina González-Morales & Belén Fernández & Francisco J. Molina & Darío Naranjo-Fernández & Adriana Matamoros-Veloza & Miller Alonso Camargo-Valero, 2021. "Influence of pH and Temperature on Struvite Purity and Recovery from Anaerobic Digestate," Sustainability, MDPI, vol. 13(19), pages 1-14, September.
    3. Saba Daneshgar & Armando Buttafava & Arianna Callegari & Andrea G. Capodaglio, 2018. "Simulations and Laboratory Tests for Assessing Phosphorus Recovery Efficiency from Sewage Sludge," Resources, MDPI, vol. 7(3), pages 1-14, August.
    Full references (including those not matched with items on IDEAS)

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