Mathematical Modeling of Collisional Heat Generation and Convective Heat Transfer Problem for Single Spherical Body in Oscillating Boundaries

The application of high-energy ball milling in the field of advanced materials processing, such as mechanochemical alloying and ammonia synthesis, has been gaining increasing attention beyond its traditional use in material crushing. It is important to recognize the role of thermodynamics in high-energy processes, including heat generation from collisions, as well as ongoing investigations into grinding ball behavior. This study aims to develop a mathematical model for the numerical analysis of a spherical ball in a shaker mill, taking into account its dynamics, contact mechanics, thermodynamics, and heat transfer. The complexity of the problem for mathematical modeling is reduced by limiting the motion to one-dimensional translation and representing the vibration of the vial wall in a shaker mill as rigid boundaries that move in a linear fashion. A nonlinear viscoelastic contact model is employed to construct a heat generation model. An equation of internal energy evolution is derived that incorporates a velocity-dependent heat convection model. In coupled field modeling, equations of motion for high-energy impact phenomena are derived from energy-based Hamiltonian mechanics rather than vector-based Newtonian mechanics. The numerical integration of the governing equations is performed at the system level to analyze the general heating characteristics during collisions and the effect of various operational parameters, such as the oscillation frequency and amplitude of the vial. The results of the numerical analysis provide essential performance metrics, including steady-state temperature and time constant for the characteristics of temperature evolution for a high-energy shaker milling process with a computation accuracy of 0.1%. The novelty of this modeling study is that it is the first to obtain such a high accuracy numerical solution for the temperature evolution associated with a shaker mill process.