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A Study on the Preparation of Regular Multiple Micro-Electrolysis Filler and the Application in Pretreatment of Oil Refinery Wastewater

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  • Ruihong Yang

    (Key Laboratory for Integrated Regulation and Resource Development on Shallow Lake of Ministry of Education, College of Environment, Hohai University, Nanjing 210098, China
    Department of Chemical Engineering, Yangzhou Polytechnic Institute, Yangzhou 225127, China)

  • Jianzhong ZHU

    (Key Laboratory for Integrated Regulation and Resource Development on Shallow Lake of Ministry of Education, College of Environment, Hohai University, Nanjing 210098, China)

  • Yingliu Li

    (Key Laboratory for Integrated Regulation and Resource Development on Shallow Lake of Ministry of Education, College of Environment, Hohai University, Nanjing 210098, China)

  • Hui Zhang

    (Key Laboratory for Integrated Regulation and Resource Development on Shallow Lake of Ministry of Education, College of Environment, Hohai University, Nanjing 210098, China)

Abstract

Through a variety of material screening experiments, Al was selected as the added metal and constituted a multiple micro-electrolysis system of Fe/C/Al. The metal proportion of alloy-structured filler was also analyzed with the best Fe/C/Al ratio of 3:1:1. The regular Fe/C/Al multiple micro-electrolysis fillers were prepared using a high-temperature anaerobic roasting method. The optimum conditions for oil refinery wastewater treated by Fe/C/Al multiple micro-electrolysis were determined to be an initial pH value of 3, reaction time of 80 min, and 0.05 mol/L Na 2 SO 4 additive concentration. The reaction mechanism of the treatment of oil refinery wastewater by Fe/C/Al micro-electrolysis was investigated. The process of the treatment of oil refinery wastewater with multiple micro-electrolysis conforms to the third-order reaction kinetics. The gas chromatography–mass spectrometry (GC–MS) used to analyze the organic compounds of the oil refinery wastewater before and after treatment and the Ultraviolet–visible spectroscopy (UV–VIS) absorption spectrum analyzed the degradation process of organic compounds in oil refinery wastewater. The treatment effect of Fe/C/Al multiple micro-electrolysis was examined in the continuous experiment under the optimum conditions, which showed high organic compound removal and stable treatment efficiency.

Suggested Citation

  • Ruihong Yang & Jianzhong ZHU & Yingliu Li & Hui Zhang, 2016. "A Study on the Preparation of Regular Multiple Micro-Electrolysis Filler and the Application in Pretreatment of Oil Refinery Wastewater," IJERPH, MDPI, vol. 13(5), pages 1-15, April.
    • Handle: RePEc:gam:jijerp:v:13:y:2016:i:5:p:457-:d:69174
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    Cited by:

    1. Meiqing Zhu & Lijun Wang & Yu Wang & Jie Zhou & Jie Ding & Wei Li & Yue Xin & Shisuo Fan & Zhen Wang & Yi Wang, 2018. "Biointeractions of Herbicide Atrazine with Human Serum Albumin: UV-Vis, Fluorescence and Circular Dichroism Approaches," IJERPH, MDPI, vol. 15(1), pages 1-16, January.

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