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Membrane Permeability Rates of Vanadium Ions and Their Effects on Temperature Variation in Vanadium Redox Batteries

Author

Listed:
  • Liuyue Cao

    (School of Chemical Engineering, University of New South Wales, Sydney, NSW 2052, Australia)

  • Anders Kronander

    (School of Chemical Engineering, University of New South Wales, Sydney, NSW 2052, Australia)

  • Ao Tang

    (Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China)

  • Da-Wei Wang

    (School of Chemical Engineering, University of New South Wales, Sydney, NSW 2052, Australia)

  • Maria Skyllas-Kazacos

    (School of Chemical Engineering, University of New South Wales, Sydney, NSW 2052, Australia)

Abstract

The inevitable diffusion of vanadium ions across the membrane can cause considerable capacity loss and temperature increase in vanadium redox flow batteries (VRFBs) over long term operation. Reliable experimental data of the permeability rates of vanadium ions are needed for membrane selection and for use in mathematical models to predict long-term behavior. In this paper a number of ion exchange membranes were selected for detailed evaluation using a modified approach to obtain more accurate permeation rates of V 2+ , V 3+ , VO 2+ and VO 2 + ions. Three commercial ion exchange membranes—FAP450, VB2 and F930—are investigated. The obtained diffusion coefficients are then employed in dynamic models to predict the thermal behavior under specific operating conditions. The simulation results prove that smaller and more balanced permeability rates of V 2+ and VO 2 + ions are more important to avoid large temperature increases in the cell stack during stand-by periods at high states-of-charge with pumps off.

Suggested Citation

  • Liuyue Cao & Anders Kronander & Ao Tang & Da-Wei Wang & Maria Skyllas-Kazacos, 2016. "Membrane Permeability Rates of Vanadium Ions and Their Effects on Temperature Variation in Vanadium Redox Batteries," Energies, MDPI, vol. 9(12), pages 1-15, December.
    • Handle: RePEc:gam:jeners:v:9:y:2016:i:12:p:1058-:d:85184
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    Citations

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    Cited by:

    1. Bhattacharjee, Ankur & Saha, Hiranmay, 2018. "Development of an efficient thermal management system for Vanadium Redox Flow Battery under different charge-discharge conditions," Applied Energy, Elsevier, vol. 230(C), pages 1182-1192.
    2. Zhiquan Wei & Zhaodong Huang & Guojin Liang & Yiqiao Wang & Shixun Wang & Yihan Yang & Tao Hu & Chunyi Zhi, 2024. "Starch-mediated colloidal chemistry for highly reversible zinc-based polyiodide redox flow batteries," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    3. Zhang, Yunong & Liu, Le & Xi, Jingyu & Wu, Zenghua & Qiu, Xinping, 2017. "The benefits and limitations of electrolyte mixing in vanadium flow batteries," Applied Energy, Elsevier, vol. 204(C), pages 373-381.
    4. Ivan Kuzmin & Alexey Loskutov & Evgeny Osetrov & Andrey Kurkin, 2022. "Source for Autonomous Power Supply System Based on Flow Battery," Energies, MDPI, vol. 15(9), pages 1-15, April.
    5. Karrech, A., 2024. "Large-scale all-climate vanadium batteries," Applied Energy, Elsevier, vol. 355(C).

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