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Prussian Blue Analogues Based on 3d-Metals as Cathode Materials for Magnesium Ion Batteries

Author

Listed:
  • Andrey Arbenin

    (Saint Petersburg State University, Universitetsky pr.26, Saint Petersburg 198504, Russia)

  • Semyon Egorov

    (Saint Petersburg State University, Universitetsky pr.26, Saint Petersburg 198504, Russia)

  • Igor Prikhodko

    (Saint Petersburg State University, Universitetsky pr.26, Saint Petersburg 198504, Russia)

  • Anna Fedorova

    (Saint Petersburg State University, Universitetsky pr.26, Saint Petersburg 198504, Russia)

  • Anastasia Penkova

    (Saint Petersburg State University, Universitetsky pr.26, Saint Petersburg 198504, Russia)

  • Artem Selyutin

    (Saint Petersburg State University, Universitetsky pr.26, Saint Petersburg 198504, Russia)

Abstract

Prussian blue PB analogues (K;Mg) x M[Fe(CN) 6 ] were obtained via the co-precipitation method. Manganese, iron, cobalt, nickel, copper and zinc were selected to obtain the metal hexacyanoferrates (MHCFs) of these metals and to systematically study their structural and electrochemical properties as cathode materials. The obtained substances were characterized via X-ray powder analysis, scanning electron microscopy, thermogravimetric analysis and elemental analysis. An electrochemical study of the obtained cathode materials relative to a platinum anode in an aqueous medium and a magnesium anode in a nonaqueous medium was carried out, and the cycling parameters were determined. The influence of 3d-metal nature on the composition–structure–properties of hexacyanoferrates was demonstrated. MHCFs are promising cathode materials for Mg 2+ intercalation/deintercalation in aqueous electrolytes.

Suggested Citation

  • Andrey Arbenin & Semyon Egorov & Igor Prikhodko & Anna Fedorova & Anastasia Penkova & Artem Selyutin, 2025. "Prussian Blue Analogues Based on 3d-Metals as Cathode Materials for Magnesium Ion Batteries," Energies, MDPI, vol. 18(3), pages 1-17, February.
    • Handle: RePEc:gam:jeners:v:18:y:2025:i:3:p:711-:d:1583343
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    References listed on IDEAS

    as
    1. Colin D. Wessells & Robert A. Huggins & Yi Cui, 2011. "Copper hexacyanoferrate battery electrodes with long cycle life and high power," Nature Communications, Nature, vol. 2(1), pages 1-5, September.
    2. Ke, Xi & Zhao, Zhuozhuo & Liu, Jun & Shi, Zhicong & Li, Yunyong & Zhang, Lingyu & Zhang, Haiyan & Chen, Ying & Guo, Zaiping & Wu, Qihui & Liu, Liying, 2017. "Improvement in capacity retention of cathode material for high power density lithium ion batteries: The route of surface coating," Applied Energy, Elsevier, vol. 194(C), pages 540-548.
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