Evaluation of a Simplified Model for Three-Phase Equilibrium Calculations of Mixed Gas Hydrates

In this study, we perform an extensive evaluation of a simple model for hydrate equilibrium calculations of binary, ternary, and limited quaternary gas hydrate systems that are of practical interest for separation of gas mixtures. We adopt the model developed by Lipenkov and Istomin and analyze its performance at temperature conditions higher than the lower quadruple point. The model of interest calculates the dissociation pressure of mixed gas hydrate systems using a simple combination rule that involves the hydrate dissociation pressures of the pure gases and the gas mixture composition, which is at equilibrium with the aqueous and hydrate phases. Such an approach has been used extensively and successfully in polar science, as well as research related to space science where the temperatures are very low. However, the particular method has not been examined for cases of higher temperatures (i.e., above the melting point of the pure water). Such temperatures are of interest to practical industrial applications. Gases of interest for this study include eleven chemical components that are related to industrial gas-mixture separations. Calculations using the examined methodology, along with the commercial simulator CSMGem, are compared against experimental measurements, and the range of applicability of the method is delineated. Reasonable agreement (particularly at lower hydrate equilibrium pressures) between experiments and calculations is obtained considering the simplicity of the methodology. Depending on the hydrate-forming mixture considered, the percentage of absolute average deviation in predicting the hydrate equilibrium pressure is found to be in the range 3–91%, with the majority of systems having deviations that are less than 30%.