IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v16y2023i21p7316-d1269556.html
   My bibliography  Save this article

Combined Methane Pyrolysis and Solid Carbon Gasification for Electrified CO 2 -Free Hydrogen and Syngas Production

Author

Listed:
  • Patrice Perreault

    (Laboratory for the Electrification of Chemical Processes and Hydrogen (ElectrifHy), University of Antwerp, Olieweg 97, 2020 Antwerp, Belgium
    Blue App, Olieweg 97, 2020 Antwerp, Belgium
    Sustainable Energy, Air and Water Technology, Department of Bioscience Engineering, University of Antwerp, Groenenborgerlaan 171, 2020 Antwerp, Belgium)

  • Cristian-Renato Boruntea

    (Sustainable Energy, Air and Water Technology, Department of Bioscience Engineering, University of Antwerp, Groenenborgerlaan 171, 2020 Antwerp, Belgium)

  • Heena Dhawan Yadav

    (Sustainable Energy, Air and Water Technology, Department of Bioscience Engineering, University of Antwerp, Groenenborgerlaan 171, 2020 Antwerp, Belgium)

  • Iria Portela Soliño

    (Sustainable Energy, Air and Water Technology, Department of Bioscience Engineering, University of Antwerp, Groenenborgerlaan 171, 2020 Antwerp, Belgium)

  • Nithin B. Kummamuru

    (Laboratory for the Electrification of Chemical Processes and Hydrogen (ElectrifHy), University of Antwerp, Olieweg 97, 2020 Antwerp, Belgium
    Sustainable Energy, Air and Water Technology, Department of Bioscience Engineering, University of Antwerp, Groenenborgerlaan 171, 2020 Antwerp, Belgium)

Abstract

The coupling of methane pyrolysis with the gasification of a solid carbon byproduct provides CO 2 -free hydrogen and hydrogen-rich syngas, eliminating the conundrum of carbon utilization. Firstly, the various types of carbon that are known to result during the pyrolysis process and their dependencies on the reaction conditions for catalytic and noncatalytic systems are summarized. The synchronization of the reactions’ kinetics is considered to be of paramount importance for efficient performance. This translates to the necessity of finding suitable reaction conditions, carbon reactivities, and catalysts that might enable control over competing reactions through the manipulation of the reaction rates. As a consequence, the reaction kinetics of methane pyrolysis is then emphasized, followed by the particularities of carbon deposition and the kinetics of carbon gasification. Given the urgency in finding suitable solutions for decarbonizing the energy sector and the limited information on the gasification of pyrolytic carbon, more research is needed and encouraged in this area. In order to provide CO 2 -free hydrogen production, the reaction heat should also be provided without CO 2 . Electrification is one of the solutions, provided that low-carbon sources are used to generate the electricity. Power-to-heat, i.e., where electricity is used for heating, represents the first step for the chemical industry.

Suggested Citation

  • Patrice Perreault & Cristian-Renato Boruntea & Heena Dhawan Yadav & Iria Portela Soliño & Nithin B. Kummamuru, 2023. "Combined Methane Pyrolysis and Solid Carbon Gasification for Electrified CO 2 -Free Hydrogen and Syngas Production," Energies, MDPI, vol. 16(21), pages 1-20, October.
  • Handle: RePEc:gam:jeners:v:16:y:2023:i:21:p:7316-:d:1269556
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/16/21/7316/pdf
    Download Restriction: no

    File URL: https://www.mdpi.com/1996-1073/16/21/7316/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Bae, Dasol & Kim, Yikyeom & Ko, Eun Hee & Ju Han, Seung & Lee, Jae W. & Kim, Minkyu & Kang, Dohyung, 2023. "Methane pyrolysis and carbon formation mechanisms in molten manganese chloride mixtures," Applied Energy, Elsevier, vol. 336(C).
    2. Reuß, M. & Grube, T. & Robinius, M. & Preuster, P. & Wasserscheid, P. & Stolten, D., 2017. "Seasonal storage and alternative carriers: A flexible hydrogen supply chain model," Applied Energy, Elsevier, vol. 200(C), pages 290-302.
    3. Qi Dong & Yonggang Yao & Sichao Cheng & Konstantinos Alexopoulos & Jinlong Gao & Sanjana Srinivas & Yifan Wang & Yong Pei & Chaolun Zheng & Alexandra H. Brozena & Hao Zhao & Xizheng Wang & Hilal Ezgi , 2022. "Programmable heating and quenching for efficient thermochemical synthesis," Nature, Nature, vol. 605(7910), pages 470-476, May.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Li, Yanfei & Taghizadeh-Hesary, Farhad, 2022. "The economic feasibility of green hydrogen and fuel cell electric vehicles for road transport in China," Energy Policy, Elsevier, vol. 160(C).
    2. Kolb, Sebastian & Plankenbühler, Thomas & Frank, Jonas & Dettelbacher, Johannes & Ludwig, Ralf & Karl, Jürgen & Dillig, Marius, 2021. "Scenarios for the integration of renewable gases into the German natural gas market – A simulation-based optimisation approach," Renewable and Sustainable Energy Reviews, Elsevier, vol. 139(C).
    3. Jiwon Yu & Young Jae Han & Hyewon Yang & Sugil Lee & Gildong Kim & Chulung Lee, 2022. "Promising Technology Analysis and Patent Roadmap Development in the Hydrogen Supply Chain," Sustainability, MDPI, vol. 14(21), pages 1-20, October.
    4. Abdulrahman Joubi & Yutaro Akimoto & Keiichi Okajima, 2022. "A Production and Delivery Model of Hydrogen from Solar Thermal Energy in the United Arab Emirates," Energies, MDPI, vol. 15(11), pages 1-14, May.
    5. Liu, Hailiang & Brown, Tom & Andresen, Gorm Bruun & Schlachtberger, David P. & Greiner, Martin, 2019. "The role of hydro power, storage and transmission in the decarbonization of the Chinese power system," Applied Energy, Elsevier, vol. 239(C), pages 1308-1321.
    6. Andrzej Mianowski & Mateusz Szul & Tomasz Radko & Aleksander Sobolewski & Tomasz Iluk, 2024. "Literature Review on Thermodynamic and Kinetic Limitations of Thermal Decomposition of Methane," Energies, MDPI, vol. 17(19), pages 1-33, October.
    7. Wang, Jianxiao & An, Qi & Zhao, Yue & Pan, Guangsheng & Song, Jie & Hu, Qinran & Tan, Chin-Woo, 2023. "Role of electrolytic hydrogen in smart city decarbonization in China," Applied Energy, Elsevier, vol. 336(C).
    8. Lopez, Gabriel & Galimova, Tansu & Fasihi, Mahdi & Bogdanov, Dmitrii & Breyer, Christian, 2023. "Towards defossilised steel: Supply chain options for a green European steel industry," Energy, Elsevier, vol. 273(C).
    9. Michel Noussan & Pier Paolo Raimondi & Rossana Scita & Manfred Hafner, 2020. "The Role of Green and Blue Hydrogen in the Energy Transition—A Technological and Geopolitical Perspective," Sustainability, MDPI, vol. 13(1), pages 1-26, December.
    10. Stefan Arens & Sunke Schlüters & Benedikt Hanke & Karsten von Maydell & Carsten Agert, 2020. "Sustainable Residential Energy Supply: A Literature Review-Based Morphological Analysis," Energies, MDPI, vol. 13(2), pages 1-28, January.
    11. Lee, Sanghun & Kim, Taehong & Han, Gwangwoo & Kang, Sungmin & Yoo, Young-Sung & Jeon, Sang-Yun & Bae, Joongmyeon, 2021. "Comparative energetic studies on liquid organic hydrogen carrier: A net energy analysis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 150(C).
    12. Ehrenstein, Michael & Galán-Martín, Ángel & Tulus, Victor & Guillén-Gosálbez, Gonzalo, 2020. "Optimising fuel supply chains within planetary boundaries: A case study of hydrogen for road transport in the UK," Applied Energy, Elsevier, vol. 276(C).
    13. Jing Sun & Yonggang Peng & Di Lu & Xiaofeng Chen & Weifeng Xu & Liguo Weng & Jun Wu, 2022. "Optimized Configuration and Operating Plan for Hydrogen Refueling Station with On-Site Electrolytic Production," Energies, MDPI, vol. 15(7), pages 1-20, March.
    14. Frank, Matthias & Deja, Robert & Peters, Roland & Blum, Ludger & Stolten, Detlef, 2018. "Bypassing renewable variability with a reversible solid oxide cell plant," Applied Energy, Elsevier, vol. 217(C), pages 101-112.
    15. Fan Li & Dong Liu & Ke Sun & Songheng Yang & Fangzheng Peng & Kexin Zhang & Guodong Guo & Yuan Si, 2024. "Towards a Future Hydrogen Supply Chain: A Review of Technologies and Challenges," Sustainability, MDPI, vol. 16(5), pages 1-36, February.
    16. Yunesky Masip Macía & Pablo Rodríguez Machuca & Angel Alexander Rodríguez Soto & Roberto Carmona Campos, 2021. "Green Hydrogen Value Chain in the Sustainability for Port Operations: Case Study in the Region of Valparaiso, Chile," Sustainability, MDPI, vol. 13(24), pages 1-17, December.
    17. Niermann, M. & Timmerberg, S. & Drünert, S. & Kaltschmitt, M., 2021. "Liquid Organic Hydrogen Carriers and alternatives for international transport of renewable hydrogen," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).
    18. James T. Hinkley, 2021. "A New Zealand Perspective on Hydrogen as an Export Commodity: Timing of Market Development and an Energy Assessment of Hydrogen Carriers," Energies, MDPI, vol. 14(16), pages 1-15, August.
    19. Martin Robinius & Alexander Otto & Konstantinos Syranidis & David S. Ryberg & Philipp Heuser & Lara Welder & Thomas Grube & Peter Markewitz & Vanessa Tietze & Detlef Stolten, 2017. "Linking the Power and Transport Sectors—Part 2: Modelling a Sector Coupling Scenario for Germany," Energies, MDPI, vol. 10(7), pages 1-23, July.
    20. Cantú, Victor H. & Ponsich, Antonin & Azzaro-Pantel, Catherine & Carrera, Eduardo, 2023. "Capturing spatial, time-wise and technological detail in hydrogen supply chains: A bi-level multi-objective optimization approach," Applied Energy, Elsevier, vol. 344(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:16:y:2023:i:21:p:7316-:d:1269556. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.