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Comparison of Pyrolysis and Combustion Processes of Vinyl Floor Panels Using Thermogravimetric Analysis (TG-FTIR) in Terms of the Circular Economy

Author

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  • Małgorzata Kajda-Szcześniak

    (Department of Technologies and Installations for Waste Management, Silesian University of Technology, 44-100 Gliwice, Poland)

  • Monika Czop

    (Department of Technologies and Installations for Waste Management, Silesian University of Technology, 44-100 Gliwice, Poland)

Abstract

The article analyzes the thermal degradation in the inert and oxidative atmosphere of waste vinyl panels, the main component of which is PVC. Both pyrolysis and incineration of plastic waste are difficult, complex and multifaceted processes due to several physical and chemical phenomena occurring during their performance. The coupled TG-MS (thermogravimetry-mass spectrometry) analysis combined with the Fourier transform infrared spectrometry (TG-FTIR) analysis was used to identify the decomposition mechanisms of waste vinyl panels. Thermogravimetric tests were carried out for two heating rates of 5 and 20 K/min in the temperature range of 40–1000 °C, mass losses were determined, and products resulting from thermal degradation were identified. It was found that the individual components decompose at different temperatures depending on the heating rate and the choice of an inert or oxidative atmosphere. Vinyl floor panels were treated in terms of secondary raw material, which, in the light of the circular economy, may constitute a potential energy or chemical resource.

Suggested Citation

  • Małgorzata Kajda-Szcześniak & Monika Czop, 2022. "Comparison of Pyrolysis and Combustion Processes of Vinyl Floor Panels Using Thermogravimetric Analysis (TG-FTIR) in Terms of the Circular Economy," Energies, MDPI, vol. 15(4), pages 1-15, February.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:4:p:1516-:d:752465
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    References listed on IDEAS

    as
    1. Alicja Kicińska & Grzegorz Caba, 2021. "Leaching of Chlorides, Sulphates, and Phosphates from Ashes Formed as a Result of Burning Conventional Fuels, Alternative Fuels, and Municipal Waste in Household Furnaces," Energies, MDPI, vol. 14(13), pages 1-18, June.
    2. Tomasz J. Jaworski & Małgorzata Kajda-Szcześniak, 2020. "Study on the Similarity of the Parameters of Biomass and Solid Waste Fuel Combustion for the Needs of Thermal Power Engineering," Sustainability, MDPI, vol. 12(19), pages 1-14, September.
    3. Józef Ciuła & Violetta Kozik & Agnieszka Generowicz & Krzysztof Gaska & Andrzej Bak & Marlena Paździor & Krzysztof Barbusiński, 2020. "Emission and Neutralization of Methane from a Municipal Landfill-Parametric Analysis," Energies, MDPI, vol. 13(23), pages 1-18, November.
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