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Graphene-Based Phase Change Composite Nano-Materials for Thermal Storage Applications

Author

Listed:
  • Marina Tselepi

    (Department of Physics, University of Ioannina, 45110 Ioannina, Greece)

  • Costas Prouskas

    (Department of Materials Science and Engineering, University of Ioannina, 45110 Ioannina, Greece)

  • Dimitrios G. Papageorgiou

    (Department of Materials Science and Engineering, University of Ioannina, 45110 Ioannina, Greece)

  • Isaac. E. Lagaris

    (Department of Computer Science and Engineering, University of Ioannina, 45110 Ioannina, Greece)

  • Georgios A. Evangelakis

    (Department of Physics, University of Ioannina, 45110 Ioannina, Greece
    Institute of Materials Science and Computing, 45110 Ioannina, Greece)

Abstract

We report results concerning the functionalization of graphene-based nanoplatelets for improving the thermal energy storage capacity of commonly used phase change materials (PCMs). The goal of this study was to enhance the low thermal conductivity of the PCMs, while preserving their specific and latent heats. We focused on wax-based PCMs, and we tested several types of graphene nanoparticles (GNPs) at a set of different concentrations. Both the size and shape of the GNPs were found to be important factors affecting the PCM’s thermal properties. These were evaluated using differential scanning calorimetry measurements and a modified enthalpy-based water bath method. We found that a small addition of GNPs (1% weight) with high aspect ratio is sufficient to double the thermal conductivity of several widely used PCMs. Our results suggest a simple and efficient procedure for improving the thermal properties of PCMs used in thermal energy storage applications.

Suggested Citation

  • Marina Tselepi & Costas Prouskas & Dimitrios G. Papageorgiou & Isaac. E. Lagaris & Georgios A. Evangelakis, 2022. "Graphene-Based Phase Change Composite Nano-Materials for Thermal Storage Applications," Energies, MDPI, vol. 15(3), pages 1-12, February.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:3:p:1192-:d:743312
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    References listed on IDEAS

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    1. Gupta, Munish & Singh, Vinay & Kumar, Rajesh & Said, Z., 2017. "A review on thermophysical properties of nanofluids and heat transfer applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 74(C), pages 638-670.
    2. Zamzamian, Amirhossein & KeyanpourRad, Mansoor & KianiNeyestani, Maryam & Jamal-Abad, Milad Tajik, 2014. "An experimental study on the effect of Cu-synthesized/EG nanofluid on the efficiency of flat-plate solar collectors," Renewable Energy, Elsevier, vol. 71(C), pages 658-664.
    3. Colangelo, Gianpiero & Favale, Ernani & de Risi, Arturo & Laforgia, Domenico, 2013. "A new solution for reduced sedimentation flat panel solar thermal collector using nanofluids," Applied Energy, Elsevier, vol. 111(C), pages 80-93.
    4. Arthur, Owen & Karim, M.A., 2016. "An investigation into the thermophysical and rheological properties of nanofluids for solar thermal applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 55(C), pages 739-755.
    5. Jouybari, H. Javaniyan & Saedodin, S. & Zamzamian, A. & Nimvari, M. Eshagh & Wongwises, S., 2017. "Effects of porous material and nanoparticles on the thermal performance of a flat plate solar collector: An experimental study," Renewable Energy, Elsevier, vol. 114(PB), pages 1407-1418.
    6. Li, Min, 2013. "A nano-graphite/paraffin phase change material with high thermal conductivity," Applied Energy, Elsevier, vol. 106(C), pages 25-30.
    7. Khodadadi, J.M. & Fan, Liwu & Babaei, Hasan, 2013. "Thermal conductivity enhancement of nanostructure-based colloidal suspensions utilized as phase change materials for thermal energy storage: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 24(C), pages 418-444.
    8. Suganthi, K.S. & Rajan, K.S., 2017. "Metal oxide nanofluids: Review of formulation, thermo-physical properties, mechanisms, and heat transfer performance," Renewable and Sustainable Energy Reviews, Elsevier, vol. 76(C), pages 226-255.
    9. Elsheikh, A.H. & Sharshir, S.W. & Mostafa, Mohamed E. & Essa, F.A. & Ahmed Ali, Mohamed Kamal, 2018. "Applications of nanofluids in solar energy: A review of recent advances," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 3483-3502.
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