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Isolation and Purification of Actinides Using N,O-Hybrid Donor Ligands for Closing the Nuclear Fuel Cycle

Author

Listed:
  • Mikhail Alyapyshev

    (Polymetal Engineering, 2 pr. Narodnogo Opolcheniya, 198216 St. Petersburg, Russia)

  • Vasiliy Babain

    (Independent Researcher, Grazhdansky pr. 88/4-83, 195220 St. Petersburg, Russia)

  • Dmitry Kirsanov

    (Institute of Chemistry, St. Petersburg University, Universitetskaya nab 7/9, 199034 St. Petersburg, Russia)

Abstract

Despite the fact that in the mass consciousness nuclear power is associated with increased environmental risks, this type of energy today remains one of the cleanest, most efficient and carbon neutral. Further development of nuclear energy is hampered by the problem of appropriate handling of spent nuclear fuel (SNF). A very attractive concept of the closed nuclear cycle has been developed to solve it. A real-life implementation of this concept requires the development of technological processes for the efficient separation of minor actinides from the rest of the SNF components. Recent progress in this area has been closely associated with N,O-hybrid donor ligands for liquid–liquid extraction. This work systematically reviews the available literature on the topic and provides detailed explanations on the behavior of the most perspective ligands. Notably, another important aspect of the application of N,O-hybrid donor ligands in nuclear cycle analytics through their incorporation in chemical sensors is also discussed.

Suggested Citation

  • Mikhail Alyapyshev & Vasiliy Babain & Dmitry Kirsanov, 2022. "Isolation and Purification of Actinides Using N,O-Hybrid Donor Ligands for Closing the Nuclear Fuel Cycle," Energies, MDPI, vol. 15(19), pages 1-31, October.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:19:p:7380-:d:936039
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    References listed on IDEAS

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    1. Viacheslav Pershukov & Vladimir Artisyuk & Andrey Kashirsky, 2022. "Paving the Way to Green Status for Nuclear Power," Sustainability, MDPI, vol. 14(15), pages 1-10, July.
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    Cited by:

    1. Nataliya E. Borisova & Tsagana B. Sumyanova & Alexey V. Ivanov & Anastasia V. Kharcheva & Petr I. Matveev & Svetlana V. Patsaeva & Vladimir G. Petrov, 2022. "Sterical Driving Minor Actinide Selectivity of Bi-pyridyl Diamides: Ortho- vs. Para-Substitution," Energies, MDPI, vol. 15(24), pages 1-12, December.

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