IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v15y2022i19p7301-d933391.html
   My bibliography  Save this article

Numerical Simulation of High-Performance CsPbI 3 /FAPbI 3 Heterojunction Perovskite Solar Cells

Author

Listed:
  • Yongjin Gan

    (Key Lab of Complex System Optimization and Big Data Processing, Guangxi Colleges and Universities, Yulin Normal University, Yulin 537000, China
    Optoelectronic Information Research Center, Yulin Normal University, Yulin 537000, China
    School of Physics and Telecommunication Engineering, Yulin Normal University, Yulin 537000, China)

  • Di Zhao

    (Key Lab of Complex System Optimization and Big Data Processing, Guangxi Colleges and Universities, Yulin Normal University, Yulin 537000, China
    School of Physics and Telecommunication Engineering, Yulin Normal University, Yulin 537000, China)

  • Binyi Qin

    (Key Lab of Complex System Optimization and Big Data Processing, Guangxi Colleges and Universities, Yulin Normal University, Yulin 537000, China
    School of Physics and Telecommunication Engineering, Yulin Normal University, Yulin 537000, China)

  • Xueguang Bi

    (School of Physics and Telecommunication Engineering, Yulin Normal University, Yulin 537000, China)

  • Yucheng Liu

    (Department of Mechanical Engineering, South Dakota State University, Brookings, SD 57006, USA)

  • Weilian Ning

    (School of Physics and Telecommunication Engineering, Yulin Normal University, Yulin 537000, China)

  • Ruizhao Yang

    (Optoelectronic Information Research Center, Yulin Normal University, Yulin 537000, China
    School of Physics and Telecommunication Engineering, Yulin Normal University, Yulin 537000, China)

  • Qubo Jiang

    (Optoelectronic Information Processing Key Laboratory of Guangxi, Guilin University of Electronic Technology, Guilin 541004, China)

Abstract

To broaden the absorption spectrum of cells, enhance the cell stability, and avoid high costs, a novel perovskite solar cell (PSC) with the structure of fluorine-doped tin oxide (FTO)/ZnO/CsPbI 3 /FAPbI 3 /CuSCN/Au is designed using the solar cell capacitance simulator (SCAPS) software. The simulation results indicate that the CsPbI 3 /FAPbI 3 heterojunction PSC has higher quantum efficiency ( QE ) characteristics than the single-junction CsPbI 3 -based PSC, and it outputs a higher short-circuit current density ( J sc ) and power conversion efficiency ( PCE ). In order to optimize the device performance, several critical device parameters, including the thickness and defect density of both the CsPbI 3 and FAPbI 3 layers, the work function of the contact electrodes, and the operating temperature are systematically investigated. Through the optimum analysis, the thicknesses of CsPbI 3 and FAPbI 3 are optimized to be 100 and 700 nm, respectively, so that the cell could absorb photons more sufficiently without an excessively high recombination rate, and the cell achieved the highest PCE . The defect densities of CsPbI 3 and FAPbI 3 are set to 10 12 cm −3 to effectively avoid the excessive carrier recombination centering on the cell to increase the carrier lifetime. Additionally, we found that when the work function of the metal back electrode is greater than 4.8 eV and FTO with a work function of 4.4 eV is selected as the front electrode, the excessively high Schottky barrier could be avoided and the collection of photogenerated carriers could be promoted. In addition, the operating temperature is proportional to the carrier recombination rate, and an excessively high temperature could inhibit V oc . After implementing the optimized parameters, the cell performance of the studied solar cell was improved. Its PCE reaches 28.75%, which is higher than most of existing solar cells. Moreover, the open circuit voltage ( V oc ), J sc , and PCE are increased by 17%, 9.5%, and 25.1%, respectively. The results of this paper provide a methodology and approach for the construction of high-efficiency heterojunction PSCs.

Suggested Citation

  • Yongjin Gan & Di Zhao & Binyi Qin & Xueguang Bi & Yucheng Liu & Weilian Ning & Ruizhao Yang & Qubo Jiang, 2022. "Numerical Simulation of High-Performance CsPbI 3 /FAPbI 3 Heterojunction Perovskite Solar Cells," Energies, MDPI, vol. 15(19), pages 1-18, October.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:19:p:7301-:d:933391
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/15/19/7301/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/15/19/7301/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Mingzhen Liu & Michael B. Johnston & Henry J. Snaith, 2013. "Efficient planar heterojunction perovskite solar cells by vapour deposition," Nature, Nature, vol. 501(7467), pages 395-398, September.
    2. Yongjin Gan & Xueguang Bi & Yucheng Liu & Binyi Qin & Qingliu Li & Qubo Jiang & Pei Mo, 2020. "Numerical Investigation Energy Conversion Performance of Tin-Based Perovskite Solar Cells Using Cell Capacitance Simulator," Energies, MDPI, vol. 13(22), pages 1-17, November.
    3. Hanul Min & Do Yoon Lee & Junu Kim & Gwisu Kim & Kyoung Su Lee & Jongbeom Kim & Min Jae Paik & Young Ki Kim & Kwang S. Kim & Min Gyu Kim & Tae Joo Shin & Sang Seok, 2021. "Perovskite solar cells with atomically coherent interlayers on SnO2 electrodes," Nature, Nature, vol. 598(7881), pages 444-450, October.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Omar M. Saif & Yasmine Elogail & Tarek M. Abdolkader & Ahmed Shaker & Abdelhalim Zekry & Mohamed Abouelatta & Marwa S. Salem & Mostafa Fedawy, 2023. "Comprehensive Review on Thin Film Homojunction Solar Cells: Technologies, Progress and Challenges," Energies, MDPI, vol. 16(11), pages 1-23, May.
    2. Ran Ji & Zongbao Zhang & Yvonne J. Hofstetter & Robin Buschbeck & Christian Hänisch & Fabian Paulus & Yana Vaynzof, 2022. "Perovskite phase heterojunction solar cells," Nature Energy, Nature, vol. 7(12), pages 1170-1179, December.
    3. Yingxiao Fan & Yu Wu & Yang Xu & Wenhui Li & Huawei Zhou & Xianxi Zhang, 2022. "Situation and Perspectives on Tin-Based Perovskite Solar Cells," Sustainability, MDPI, vol. 14(24), pages 1-11, December.
    4. Sreeram Valsalakumar & Anurag Roy & Tapas K. Mallick & Justin Hinshelwood & Senthilarasu Sundaram, 2022. "An Overview of Current Printing Technologies for Large-Scale Perovskite Solar Cell Development," Energies, MDPI, vol. 16(1), pages 1-29, December.
    5. Ahmed A. Said & Erkan Aydin & Esma Ugur & Zhaojian Xu & Caner Deger & Badri Vishal & Aleš Vlk & Pia Dally & Bumin K. Yildirim & Randi Azmi & Jiang Liu & Edward A. Jackson & Holly M. Johnson & Manting , 2024. "Sublimed C60 for efficient and repeatable perovskite-based solar cells," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    6. Lutao Li & Junjie Yao & Juntong Zhu & Yuan Chen & Chen Wang & Zhicheng Zhou & Guoxiang Zhao & Sihan Zhang & Ruonan Wang & Jiating Li & Xiangyi Wang & Zheng Lu & Lingbo Xiao & Qiang Zhang & Guifu Zou, 2023. "Colloid driven low supersaturation crystallization for atomically thin Bismuth halide perovskite," Nature Communications, Nature, vol. 14(1), pages 1-8, December.
    7. Ming-Hsien Li & Jun-Ho Yum & Soo-Jin Moon & Peter Chen, 2016. "Inorganic p-Type Semiconductors: Their Applications and Progress in Dye-Sensitized Solar Cells and Perovskite Solar Cells," Energies, MDPI, vol. 9(5), pages 1-28, April.
    8. Salhi, B. & Wudil, Y.S. & Hossain, M.K. & Al-Ahmed, A. & Al-Sulaiman, F.A., 2018. "Review of recent developments and persistent challenges in stability of perovskite solar cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 90(C), pages 210-222.
    9. Ubani, C.A. & Ibrahim, M.A. & Teridi, M.A.M., 2017. "Moving into the domain of perovskite sensitized solar cell," Renewable and Sustainable Energy Reviews, Elsevier, vol. 72(C), pages 907-915.
    10. La Notte, Luca & Giordano, Lorena & Calabrò, Emanuele & Bedini, Roberto & Colla, Giuseppe & Puglisi, Giovanni & Reale, Andrea, 2020. "Hybrid and organic photovoltaics for greenhouse applications," Applied Energy, Elsevier, vol. 278(C).
    11. Simone M. P. Meroni & Carys Worsley & Dimitrios Raptis & Trystan M. Watson, 2021. "Triple-Mesoscopic Carbon Perovskite Solar Cells: Materials, Processing and Applications," Energies, MDPI, vol. 14(2), pages 1-37, January.
    12. Zhonghui Zhu & Matyas Daboczi & Minzhi Chen & Yimin Xuan & Xianglei Liu & Salvador Eslava, 2024. "Ultrastable halide perovskite CsPbBr3 photoanodes achieved with electrocatalytic glassy-carbon and boron-doped diamond sheets," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    13. Mehmood, Umer & Al-Ahmed, Amir & Afzaal, Mohammad & Al-Sulaiman, Fahad A. & Daud, Muhammad, 2017. "Recent progress and remaining challenges in organometallic halides based perovskite solar cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 78(C), pages 1-14.
    14. Ke Wang & Benjamin Ecker & Yongli Gao, 2021. "Photoemission Studies on the Environmental Stability of Thermal Evaporated MAPbI 3 Thin Films and MAPbBr 3 Single Crystals," Energies, MDPI, vol. 14(7), pages 1-18, April.
    15. Alaa A. Zaky & Ahmed Fathy & Hegazy Rezk & Konstantina Gkini & Polycarpos Falaras & Amlak Abaza, 2021. "A Modified Triple-Diode Model Parameters Identification for Perovskite Solar Cells via Nature-Inspired Search Optimization Algorithms," Sustainability, MDPI, vol. 13(23), pages 1-22, November.
    16. Issa M. Aziz, 2023. "Synthesizing and characterization of Lead Halide Perovskite Nanocrystals solar cells from reused car batteries," Technium, Technium Science, vol. 10(1), pages 14-26.
    17. Meng-Hsueh Kuo & Neda Neykova & Ivo Stachiv, 2024. "Overview of the Recent Findings in the Perovskite-Type Structures Used for Solar Cells and Hydrogen Storage," Energies, MDPI, vol. 17(18), pages 1-23, September.
    18. Min Xu & Jinjun Qu & Mai Li, 2022. "National Policies, Recent Research Hotspots, and Application of Sustainable Energy: Case of China, USA, and European Countries," Sustainability, MDPI, vol. 14(16), pages 1-30, August.
    19. Satya Kamal Chirauri & Asish K. Dehury & Yatendra S. Chaudhary, 2020. "Photosupercapacitors: A perspective of planar and flexible dual functioning devices," Wiley Interdisciplinary Reviews: Energy and Environment, Wiley Blackwell, vol. 9(6), November.
    20. Zengqi Huang & Lin Li & Tingqing Wu & Tangyue Xue & Wei Sun & Qi Pan & Huadong Wang & Hongfei Xie & Jimei Chi & Teng Han & Xiaotian Hu & Meng Su & Yiwang Chen & Yanlin Song, 2023. "Wearable perovskite solar cells by aligned liquid crystal elastomers," Nature Communications, Nature, vol. 14(1), pages 1-11, December.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:15:y:2022:i:19:p:7301-:d:933391. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.