IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v15y2022i19p6982-d923226.html
   My bibliography  Save this article

Measurement of the Kinetics and Thermodynamics of the Thermal Degradation for a Flame Retardant Polyurethane-Based Aerogel

Author

Listed:
  • Xinyang Wang

    (Faculty of Engineering, China University of Geosciences, Wuhan 430074, China)

  • Yan Ding

    (Faculty of Engineering, China University of Geosciences, Wuhan 430074, China
    Key Laboratory of Functional Geomaterials in China Nonmetallic Minerals Industry, China University of Geosciences, Wuhan 430074, China)

  • Zhanwen Chen

    (Faculty of Engineering, China University of Geosciences, Wuhan 430074, China)

  • Chuyan Tang

    (Faculty of Engineering, China University of Geosciences, Wuhan 430074, China)

  • Xingyu Ren

    (Department of Fire Protection Engineering, University of Maryland, College Park, MD 20742, USA)

  • Hongyun Hu

    (State Key Laboratory of Coal Combustion, Huazhong University of Science and Technology, Wuhan 430074, China)

  • Qingyan Fang

    (State Key Laboratory of Coal Combustion, Huazhong University of Science and Technology, Wuhan 430074, China)

Abstract

The current work aims to study the thermal degradation of the flame retardant polyurethane aerogel (FR_PU_aerogel) through multiple milligram-scale experimental methods. A systemic methodology for measuring the reaction kinetics and thermodynamics of the thermal degradation of FR_PU_aerogel is detailed. Specifically, the thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC) were performed simultaneously in inert atmosphere to measure the mass loss and heat flow data, and a numerical framework called ThermaKin2Ds was used to inversely model these experimental data. First, a reaction mechanism with six first-order consecutive reactions was developed based on the inverse analysis of the TGA data. The corresponding reaction kinetics were optimized using the hill climbing optimization algorithm. Subsequently, the heat capacities of each condensed phase component and the heat of the reactions were obtained through inversely modeling the heat flow data. Furthermore, the heat of the complete combustion of each gaseous component were derived based on the heat release rates measured in the milligram-scale combustion calorimeter (MCC) experiments. It is noted that the developed reaction mechanism was further validated against the mass loss data obtained at different heating rates. The parameters determined in this work serve as a core subset of inputs for the pyrolysis model development, which is essential for the quantitative understanding of the ignition and the combustion behavior of solid materials.

Suggested Citation

  • Xinyang Wang & Yan Ding & Zhanwen Chen & Chuyan Tang & Xingyu Ren & Hongyun Hu & Qingyan Fang, 2022. "Measurement of the Kinetics and Thermodynamics of the Thermal Degradation for a Flame Retardant Polyurethane-Based Aerogel," Energies, MDPI, vol. 15(19), pages 1-16, September.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:19:p:6982-:d:923226
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/15/19/6982/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/15/19/6982/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Yu, Jinghua & Yang, Changzhi & Tian, Liwei & Liao, Dan, 2009. "A study on optimum insulation thicknesses of external walls in hot summer and cold winter zone of China," Applied Energy, Elsevier, vol. 86(11), pages 2520-2529, November.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Natalia Pawlik & Barbara Szpikowska-Sroka & Artur Miros & Bronisław Psiuk & Agnieszka Ślosarczyk, 2023. "Effect of Drying Control Agent on Physicochemical and Thermal Properties of Silica Aerogel Derived via Ambient Pressure Drying Process," Energies, MDPI, vol. 16(17), pages 1-16, August.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Axaopoulos, Ioannis & Axaopoulos, Petros & Gelegenis, John, 2014. "Optimum insulation thickness for external walls on different orientations considering the speed and direction of the wind," Applied Energy, Elsevier, vol. 117(C), pages 167-175.
    2. Omer Kaynakli, 2011. "Parametric Investigation of Optimum Thermal Insulation Thickness for External Walls," Energies, MDPI, vol. 4(6), pages 1-15, June.
    3. Hu, Shan & Yan, Da & Cui, Ying & Guo, Siyue, 2016. "Urban residential heating in hot summer and cold winter zones of China—Status, modeling, and scenarios to 2030," Energy Policy, Elsevier, vol. 92(C), pages 158-170.
    4. Jie, Pengfei & Yan, Fuchun & Li, Jing & Zhang, Yumei & Wen, Zhimei, 2019. "Optimizing the insulation thickness of walls of existing buildings with CHP-based district heating systems," Energy, Elsevier, vol. 189(C).
    5. Al-Sanea, Sami A. & Zedan, M.F., 2011. "Improving thermal performance of building walls by optimizing insulation layer distribution and thickness for same thermal mass," Applied Energy, Elsevier, vol. 88(9), pages 3113-3124.
    6. De Boeck, L. & Verbeke, S. & Audenaert, A. & De Mesmaeker, L., 2015. "Improving the energy performance of residential buildings: A literature review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 52(C), pages 960-975.
    7. Aditya, L. & Mahlia, T.M.I. & Rismanchi, B. & Ng, H.M. & Hasan, M.H. & Metselaar, H.S.C. & Muraza, Oki & Aditiya, H.B., 2017. "A review on insulation materials for energy conservation in buildings," Renewable and Sustainable Energy Reviews, Elsevier, vol. 73(C), pages 1352-1365.
    8. Baglivo, Cristina & Congedo, Paolo Maria, 2016. "High performance precast external walls for cold climate by a multi-criteria methodology," Energy, Elsevier, vol. 115(P1), pages 561-576.
    9. Wang, Xiaotong & Lu, Meijun & Mao, Wei & Ouyang, Jinlong & Zhou, Bo & Yang, Yunkai, 2015. "Improving benefit-cost analysis to overcome financing difficulties in promoting energy-efficient renovation of existing residential buildings in China," Applied Energy, Elsevier, vol. 141(C), pages 119-130.
    10. Audenaert, A. & De Boeck, L. & Geudens, K. & Buyle, M., 2012. "Cost and E-level analysis of different dwelling types and different heating systems with or without heat exchanger," Energy, Elsevier, vol. 44(1), pages 604-610.
    11. Pan, Dongmei & Chan, Mingyin & Deng, Shiming & Lin, Zhongping, 2012. "The effects of external wall insulation thickness on annual cooling and heating energy uses under different climates," Applied Energy, Elsevier, vol. 97(C), pages 313-318.
    12. Mourshed, Monjur, 2016. "Climatic parameters for building energy applications: A temporal-geospatial assessment of temperature indicators," Renewable Energy, Elsevier, vol. 94(C), pages 55-71.
    13. Daouas, Naouel, 2016. "Impact of external longwave radiation on optimum insulation thickness in Tunisian building roofs based on a dynamic analytical model," Applied Energy, Elsevier, vol. 177(C), pages 136-148.
    14. Küçüktopcu, Erdem & Cemek, Bilal, 2018. "A study on environmental impact of insulation thickness of poultry building walls," Energy, Elsevier, vol. 150(C), pages 583-590.
    15. Daouas, Naouel, 2011. "A study on optimum insulation thickness in walls and energy savings in Tunisian buildings based on analytical calculation of cooling and heating transmission loads," Applied Energy, Elsevier, vol. 88(1), pages 156-164, January.
    16. Kaiser Ahmed & Jarek Kurnitski, 2021. "New Equation for Optimal Insulation Dependency on the Climate for Office Buildings," Energies, MDPI, vol. 14(2), pages 1-20, January.
    17. Kaynakli, Omer, 2014. "Economic thermal insulation thickness for pipes and ducts: A review study," Renewable and Sustainable Energy Reviews, Elsevier, vol. 30(C), pages 184-194.
    18. Abden, Md Jaynul & Tao, Zhong & Pan, Zhu & George, Laurel & Wuhrer, Richard, 2020. "Inclusion of methyl stearate/diatomite composite in gypsum board ceiling for building energy conservation," Applied Energy, Elsevier, vol. 259(C).
    19. Freire, Roberto Zanetti & Mazuroski, Walter & Abadie, Marc Olivier & Mendes, Nathan, 2011. "Capacitive effect on the heat transfer through building glazing systems," Applied Energy, Elsevier, vol. 88(12), pages 4310-4319.
    20. Jihui Yuan & Craig Farnham & Kazuo Emura, 2017. "Optimum Insulation Thickness for Building Exterior Walls in 32 Regions of China to Save Energy and Reduce CO 2 Emissions," Sustainability, MDPI, vol. 9(10), pages 1-13, September.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:15:y:2022:i:19:p:6982-:d:923226. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.