IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v14y2021i23p7975-d690773.html
   My bibliography  Save this article

Tailor-Made Phosphorylated Polyvinyl Alcohol/Tungsten Polyoxometalate Proton Exchange Membrane for a Bio-Electrochemical Energy Storage System

Author

Listed:
  • Vassili Glibin

    (Department of Chemical and Biochemical Engineering, University of Western Ontario, 1151 Richmond St., London, ON N6A 5B9, Canada)

  • Vahid Vajihinejad

    (Department of Chemical and Materials Engineering, University of Alberta, 116k St. and 85 Ave., Edmonton, AB T6G 2R3, Canada)

  • Victor Pupkevich

    (Department of Chemical and Biochemical Engineering, University of Western Ontario, 1151 Richmond St., London, ON N6A 5B9, Canada)

  • Dimitre G. Karamanev

    (Department of Chemical and Biochemical Engineering, University of Western Ontario, 1151 Richmond St., London, ON N6A 5B9, Canada)

Abstract

In this work, the synthesis of a phosphorylated polyvinyl alcohol (p-PVA)/polyoxometalate (tungsto-phosphate) membrane for the BioGenerator, a bio-electrochemical energy storage technology, is reported. It was shown that bonding of lacunary tungsto-phosphate ions to the carbon skeleton of a polymer matrix results in an increase in proton conductivity of up to 2.7 times, compared to previously studied phosphorylated PVA membranes. Testing of the membrane in an actual Fe 3+ /H 2 electrochemical cell showed that it performs significantly better (0.28 W·cm −2 at 0.79 A·cm −2 ) than the previously used commercial Selemion HSF (Japan) membrane (0.18 W·cm −2 at 0.60 A·cm −2 ).

Suggested Citation

  • Vassili Glibin & Vahid Vajihinejad & Victor Pupkevich & Dimitre G. Karamanev, 2021. "Tailor-Made Phosphorylated Polyvinyl Alcohol/Tungsten Polyoxometalate Proton Exchange Membrane for a Bio-Electrochemical Energy Storage System," Energies, MDPI, vol. 14(23), pages 1-13, November.
    • Handle: RePEc:gam:jeners:v:14:y:2021:i:23:p:7975-:d:690773
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/14/23/7975/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/14/23/7975/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Karamanev, Dimitre & Pupkevich, Victor & Penev, Kalin & Glibin, Vassili & Gohil, Jay & Vajihinejad, Vahid, 2017. "Biological conversion of hydrogen to electricity for energy storage," Energy, Elsevier, vol. 129(C), pages 237-245.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Li, Ke & Wen, Jian & Xin, Biping & Zhou, Aimin & Wang, Simin, 2024. "Transient-state modeling and thermodynamic analysis of self-pressurization liquid hydrogen tank considering effect of vacuum multi-layer insulation coupled with vapor-cooled shield," Energy, Elsevier, vol. 286(C).
    2. Claudio Cubito & Federico Millo & Giulio Boccardo & Giuseppe Di Pierro & Biagio Ciuffo & Georgios Fontaras & Simone Serra & Marcos Otura Garcia & Germana Trentadue, 2017. "Impact of Different Driving Cycles and Operating Conditions on CO 2 Emissions and Energy Management Strategies of a Euro-6 Hybrid Electric Vehicle," Energies, MDPI, vol. 10(10), pages 1-18, October.
    3. Kandidayeni, M. & Macias, A. & Khalatbarisoltani, A. & Boulon, L. & Kelouwani, S., 2019. "Benchmark of proton exchange membrane fuel cell parameters extraction with metaheuristic optimization algorithms," Energy, Elsevier, vol. 183(C), pages 912-925.
    4. Yang, Tai & Wang, Peng & Li, Qiang & Xia, Chaoqun & Yin, Fuxing & Liang, Chunyong & Zhang, Yanghuan, 2018. "Hydrogen absorption and desorption behavior of Ni catalyzed Mg–Y–C–Ni nanocomposites," Energy, Elsevier, vol. 165(PA), pages 709-719.
    5. Shahparasti, Mahdi & Rajaei, Amirhossein & Tarrassó, Andres & Luna, Alvaro, 2022. "A multi-output AC/DC energy conversion system for grid integration of bioelectrochemical power-to-gas storage," Energy, Elsevier, vol. 249(C).
    6. Wang, Du & Ji, Changwei & Wang, Shuofeng & Yang, Jinxin & Tang, Chuanqi, 2019. "Experimental investigation on near wall ignited lean methane/hydrogen/air flame," Energy, Elsevier, vol. 168(C), pages 1094-1103.
    7. Chen, Bor-Yann & Liao, Jia-Hui & Hsueh, Chung-Chuan & Qu, Ziwei & Hsu, An-Wei & Chang, Chang-Tang & Zhang, Shuping, 2018. "Deciphering biostimulation strategy of using medicinal herbs and tea extracts for bioelectricity generation in microbial fuel cells," Energy, Elsevier, vol. 161(C), pages 1042-1054.
    8. Yang, Xiehe & Wang, Tiantian & Zhang, Yang & Zhang, Hai & Wu, Yuxin & Zhang, Jiansheng, 2022. "Hydrogen effect on flame extinction of hydrogen-enriched methane/air premixed flames: An assessment from the combustion safety point of view," Energy, Elsevier, vol. 239(PC).
    9. Mohsen Kandidayeni & Alvaro Macias & Loïc Boulon & João Pedro F. Trovão, 2020. "Online Modeling of a Fuel Cell System for an Energy Management Strategy Design," Energies, MDPI, vol. 13(14), pages 1-17, July.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:14:y:2021:i:23:p:7975-:d:690773. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.