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Efficient and Stable Perovskite Large Area Cells by Low-Cost Fluorene-Xantene-Based Hole Transporting Layer

Author

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  • Luigi Vesce

    (CHOSE–Centre for Hybrid and Organic Solar Energy, Department of Electronic Engineering, University of Rome “Tor Vergata”, Via del Politecnico 1, 00133 Rome, Italy)

  • Maurizio Stefanelli

    (CHOSE–Centre for Hybrid and Organic Solar Energy, Department of Electronic Engineering, University of Rome “Tor Vergata”, Via del Politecnico 1, 00133 Rome, Italy)

  • Aldo Di Carlo

    (CHOSE–Centre for Hybrid and Organic Solar Energy, Department of Electronic Engineering, University of Rome “Tor Vergata”, Via del Politecnico 1, 00133 Rome, Italy
    ISM-CNR, Istituto di Struttura Della Materia, Consiglio Nazionale delle Ricerche, Via del Fosso del Cavaliere 100, 00133 Rome, Italy)

Abstract

Among the new generation photovoltaics, perovskite solar cell (PSC) technology reached top efficiencies in a few years. Currently, the main objective to further develop PSCs is related to the fabrication of stable devices with cost-effective materials and reliable fabrication processes to achieve a possible industrialization pathway. In the n-i-p device configuration, the hole transporting material (HTM) used most is the highly doped organic spiro-fluorene-based material (Spiro-OMeTAD). In addition to the high cost related to its complex synthesis, this material has different issues such as poor photo, thermal and moisture stability. Here, we test on small and large area PSCs a commercially available HTM (X55, Dyenamo) with a new core made by low-cost fluorene–xantene units. The one-pot synthesis of this compound reduces 30 times its cost with respect to Spiro-OMeTAD. The optoelectronic performances and properties are characterized through JV measurement, IPCE (incident photon to current efficiency), steady-state photoluminescence and ISOS stability test. SEM (scanning electron microscope) images reveal a uniform and pinhole free coverage of the X55 HTM surface, which reduces the charge recombination losses and improves the device performance relative to Spiro-OMeTAD from 16% to 17%. The ISOS-D-1 stability test on large area cells without any encapsulation reports an efficiency drop of about 15% after 1000 h compared to 30% for the reference case.

Suggested Citation

  • Luigi Vesce & Maurizio Stefanelli & Aldo Di Carlo, 2021. "Efficient and Stable Perovskite Large Area Cells by Low-Cost Fluorene-Xantene-Based Hole Transporting Layer," Energies, MDPI, vol. 14(19), pages 1-8, September.
    • Handle: RePEc:gam:jeners:v:14:y:2021:i:19:p:6081-:d:642103
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    References listed on IDEAS

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    1. Konrad Domanski & Essa A. Alharbi & Anders Hagfeldt & Michael Grätzel & Wolfgang Tress, 2018. "Systematic investigation of the impact of operation conditions on the degradation behaviour of perovskite solar cells," Nature Energy, Nature, vol. 3(1), pages 61-67, January.
    2. Parisi, M.L. & Maranghi, S. & Vesce, L. & Sinicropi, A. & Di Carlo, A. & Basosi, R., 2020. "Prospective life cycle assessment of third-generation photovoltaics at the pre-industrial scale: A long-term scenario approach," Renewable and Sustainable Energy Reviews, Elsevier, vol. 121(C).
    3. Mohamed M. H. Desoky & Matteo Bonomo & Roberto Buscaino & Andrea Fin & Guido Viscardi & Claudia Barolo & Pierluigi Quagliotto, 2021. "Dopant-Free All-Organic Small-Molecule HTMs for Perovskite Solar Cells: Concepts and Structure–Property Relationships," Energies, MDPI, vol. 14(8), pages 1-49, April.
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    Cited by:

    1. Luigi Vesce, 2022. "Novel Materials and Processes for Photovoltaic Technology," Energies, MDPI, vol. 16(1), pages 1-4, December.
    2. Carmen Coppola & Maria Laura Parisi & Adalgisa Sinicropi, 2023. "The Role of Organic Compounds in Dye-Sensitized and Perovskite Solar Cells," Energies, MDPI, vol. 16(2), pages 1-4, January.

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