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Enhancing CO 2 Hydrogenation to Methane by Ni-Based Catalyst with V Species Using 3D-mesoporous KIT-6 as Support

Author

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  • Hongxia Cao

    (Key Laboratory of Spin Electron and Nanomaterials of Anhui Higher Education Institutes, Suzhou University, Suzhou 234000, China
    Jiangsu Province Engineering Laboratory of High Efficient Energy Storage Technology and Equipments, China University of Mining and Technology, Xuzhou 221116, China
    School of Chemistry and Chemical Engineering, Suzhou University, Suzhou 234000, China
    Low Carbon Energy Institute, China University of Mining and Technology, Xuzhou 221008, China)

  • Wenyuan Wang

    (School of Chemistry and Chemical Engineering, Suzhou University, Suzhou 234000, China)

  • Tianlei Cui

    (School of Chemistry and Chemical Engineering, Suzhou University, Suzhou 234000, China)

  • Hongyan Wang

    (Key Laboratory of Spin Electron and Nanomaterials of Anhui Higher Education Institutes, Suzhou University, Suzhou 234000, China
    School of Chemistry and Chemical Engineering, Suzhou University, Suzhou 234000, China)

  • Guang Zhu

    (Key Laboratory of Spin Electron and Nanomaterials of Anhui Higher Education Institutes, Suzhou University, Suzhou 234000, China)

  • Xiangkun Ren

    (Low Carbon Energy Institute, China University of Mining and Technology, Xuzhou 221008, China)

Abstract

Using renewable H 2 for CO 2 hydrogenation to methane not only achieves CO 2 utilization, but also mitigates the greenhouse effect. In this work, several Ni-based catalysts with V species using 3D-mesoporous KIT-6 (Korea Advanced Institute of Science and Technology, KIT) as support were prepared at different contents of NiO and V 2 O 5 . Small Ni nanoparticles with high dispersibility on 20Ni-0.5V/KIT-6 were identified by X-ray diffraction (XRD), TEM and hydrogen temperature-programmed desorption (H 2 -TPD) analysis, which promoted the production of more Ni active sites for enhancing catalytic activity for CO 2 methanation. Moreover, TEM and hydrogen temperature-programmed reduction (H 2 -TPR) characterizations confirmed that a proper amount of Ni and V species was favorable to preserve the 3D-mesoporous structure and strengthen the interaction between active Ni and KIT-6. The synergistic effect between Ni and V could strengthen surface basicity to elevate the ability of CO 2 activity on the 20Ni-0.5V/KIT-6. In addition, a strong interaction with the 3D-mesoporous structure allowed active Ni to be firmly anchored onto the catalyst surface, which was accountable for improving catalytic activity and stability. These results revealed that 20Ni-0.5V/KIT-6 was a catalyst with superior catalytic activity and stability, which was considered as a promising candidate for CO 2 hydrogenation to methane.

Suggested Citation

  • Hongxia Cao & Wenyuan Wang & Tianlei Cui & Hongyan Wang & Guang Zhu & Xiangkun Ren, 2020. "Enhancing CO 2 Hydrogenation to Methane by Ni-Based Catalyst with V Species Using 3D-mesoporous KIT-6 as Support," Energies, MDPI, vol. 13(9), pages 1-14, May.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:9:p:2235-:d:353625
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    References listed on IDEAS

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    1. Bailera, Manuel & Lisbona, Pilar & Peña, Begoña & Alarcón, Andreina & Guilera, Jordi & Perpiñán, Jorge & Romeo, Luis M., 2022. "Synthetic natural gas production in a 1 kW reactor using Ni–Ce/Al2O3 and Ru–Ce/Al2O3: Kinetics, catalyst degradation and process design," Energy, Elsevier, vol. 256(C).
    2. Zhang, Qiaofei & Xie, Wenlei & Li, Jiangbo & Guo, Lihong, 2023. "Bimetallic Zrx-Aly-KIT-6 modified with sulfate as acidic catalyst for biodiesel production from low-grade acidic oils," Renewable Energy, Elsevier, vol. 217(C).

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