IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v13y2020i8p1927-d345459.html
   My bibliography  Save this article

Influence of Chloride/Iodide Ratio in MAPbI 3-x Cl x Perovskite Solar Devices: Case of Low Temperature Processable AZO Sub-Layer

Author

Listed:
  • Manon Spalla

    (Department LEPMI/GUIDE, Université Grenoble Alpes, Université Savoie Mont Blanc, CNRS, Grenoble INP, LEPMI, 38000 Grenoble, France
    Department CEA/LITEN/INES, Université Grenoble Alpes, CEA, 73375 Le Bourget du Lac, France)

  • Lara Perrin

    (Department LEPMI/GUIDE, Université Grenoble Alpes, Université Savoie Mont Blanc, CNRS, Grenoble INP, LEPMI, 38000 Grenoble, France)

  • Emilie Planès

    (Department LEPMI/GUIDE, Université Grenoble Alpes, Université Savoie Mont Blanc, CNRS, Grenoble INP, LEPMI, 38000 Grenoble, France)

  • Muriel Matheron

    (Department CEA/LITEN/INES, Université Grenoble Alpes, CEA, 73375 Le Bourget du Lac, France)

  • Solenn Berson

    (Department CEA/LITEN/INES, Université Grenoble Alpes, CEA, 73375 Le Bourget du Lac, France)

  • Lionel Flandin

    (Department LEPMI/GUIDE, Université Grenoble Alpes, Université Savoie Mont Blanc, CNRS, Grenoble INP, LEPMI, 38000 Grenoble, France)

Abstract

A significant current challenge for perovskite solar technology is succeeding in designing devices all by low temperature processes. This could help for both rigid devices industrialisation and flexible devices development. The depositions of nanoparticles from colloidal suspensions consequently emerge as attractive approaches, especially due to their potential for low temperature curing not only for the photoactive perovskite layer but also for charge transporting layers. Here, NIP solar cells based on aluminium doped zinc oxide (AZO) electron transport layer were fabricated using a low temperature compatible process for AZO deposition. For the extensively studied perovskites based on methylammonium lead halides (MAPbI 3-x Cl x ), the chloride/iodide equation is widely proposed to follow an optimal value corresponding to an introduced MAI:PbCl 2 ratio of 3:1. However, the perovskite formulation should be considered as a key parameter for the optimization of power conversion efficiency when exploring new perovskite sub-layers. We here propose a systematic method for the structural determination of the optimal ratio. It may depend on the sublayer and results from structural changes around the optimal value. The functional properties gradually increase with the addition of chlorine as long as it remains intercalated in a single phase. Above the optimal ratio, the appearance of two phases degrades the system.

Suggested Citation

  • Manon Spalla & Lara Perrin & Emilie Planès & Muriel Matheron & Solenn Berson & Lionel Flandin, 2020. "Influence of Chloride/Iodide Ratio in MAPbI 3-x Cl x Perovskite Solar Devices: Case of Low Temperature Processable AZO Sub-Layer," Energies, MDPI, vol. 13(8), pages 1-20, April.
  • Handle: RePEc:gam:jeners:v:13:y:2020:i:8:p:1927-:d:345459
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/13/8/1927/pdf
    Download Restriction: no

    File URL: https://www.mdpi.com/1996-1073/13/8/1927/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Takeo Oku, 2015. "Crystal Structures of CH3NH3PbI3 and Related Perovskite Compounds Used for Solar Cells," Chapters, in: Leonid A. Kosyachenko (ed.), Solar Cells - New Approaches and Reviews, IntechOpen.
    2. Kevin H. Stone & Aryeh Gold-Parker & Vanessa L. Pool & Eva L. Unger & Andrea R. Bowring & Michael D. McGehee & Michael F. Toney & Christopher J. Tassone, 2018. "Transformation from crystalline precursor to perovskite in PbCl2-derived MAPbI3," Nature Communications, Nature, vol. 9(1), pages 1-7, December.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Thibault Lemercier & Lara Perrin & Emilie Planès & Solenn Berson & Lionel Flandin, 2020. "A Comparison of the Structure and Properties of Opaque and Semi-Transparent NIP/PIN-Type Scalable Perovskite Solar Cells," Energies, MDPI, vol. 13(15), pages 1-18, July.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Marina M. Tepliakova & Alexandra N. Mikheeva & Pavel A. Somov & Eugene S. Statnik & Alexander M. Korsunsky & Keith J. Stevenson, 2021. "Combination of Metal Oxide and Polytriarylamine: A Design Principle to Improve the Stability of Perovskite Solar Cells," Energies, MDPI, vol. 14(16), pages 1-13, August.
    2. Tonui, Patrick & Oseni, Saheed O. & Sharma, Gaurav & Yan, Qingfenq & Tessema Mola, Genene, 2018. "Perovskites photovoltaic solar cells: An overview of current status," Renewable and Sustainable Energy Reviews, Elsevier, vol. 91(C), pages 1025-1044.
    3. Thibault Lemercier & Lara Perrin & Emilie Planès & Solenn Berson & Lionel Flandin, 2020. "A Comparison of the Structure and Properties of Opaque and Semi-Transparent NIP/PIN-Type Scalable Perovskite Solar Cells," Energies, MDPI, vol. 13(15), pages 1-18, July.
    4. Daming Zheng & Florian Raffin & Polina Volovitch & Thierry Pauporté, 2022. "Control of perovskite film crystallization and growth direction to target homogeneous monolithic structures," Nature Communications, Nature, vol. 13(1), pages 1-12, December.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:13:y:2020:i:8:p:1927-:d:345459. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.