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Adhesion-Increased Carbon Nanowalls for the Electrodes of Energy Storage Systems

Author

Listed:
  • Hyeokjoo Choi

    (Department of Electrical Engineering, Hanbat National University, Daejeon 34158, Korea)

  • Seokhun Kwon

    (Department of Electrical Engineering, Hanbat National University, Daejeon 34158, Korea)

  • Hyunil Kang

    (Department of Electrical Engineering, Hanbat National University, Daejeon 34158, Korea)

  • Jung Hyun Kim

    (Department of Advanced Materials Engineering, Hanbat National University, Daejeon 34158, Korea)

  • Wonseok Choi

    (Department of Electrical Engineering, Hanbat National University, Daejeon 34158, Korea)

Abstract

Carbon nanowalls (CNWs), which are used as electrodes for secondary batteries in energy storage systems (ESSs), have the widest reaction surface area among the carbon-based nanomaterials, but their application is rare due to their low adhesion with substrates. Indium tin oxide (ITO), a representative transparent conducting oxide (TCO) material, is widely used as the electrode for displays, solar cells, etc. Titanium nitride (TiN) is a well-used material as an interlayer for improving the adhesion between two materials. In this study, ITO or TiN thin films were used as an interlayer to improve the adhesion between a CNW and a substrate. The interlayer was deposited on the substrate using a radio frequency (RF) magnetron sputtering system with a four-inch TiN or ITO target. CNWs were grown on the interlayer-coated substrate using a microwave-plasma-enhanced chemical vapor deposition (MPECVD) system with a mixture of methane (CH 4 ) and hydrogen (H 2 ) gases. The adhesion of the CNW/interlayer/substrate structure was observed through ultrasonic cleaning.

Suggested Citation

  • Hyeokjoo Choi & Seokhun Kwon & Hyunil Kang & Jung Hyun Kim & Wonseok Choi, 2019. "Adhesion-Increased Carbon Nanowalls for the Electrodes of Energy Storage Systems," Energies, MDPI, vol. 12(24), pages 1-11, December.
  • Handle: RePEc:gam:jeners:v:12:y:2019:i:24:p:4759-:d:297627
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    Cited by:

    1. May Tran Thi & Chulsoo Kim & Seokhun Kwon & Hyunil Kang & Jang Myoun Ko & Junghyun Kim & Wonseok Choi, 2023. "Investigation of the Properties of Anode Electrodes for Lithium–Ion Batteries Manufactured Using Cu, and Si-Coated Carbon Nanowall Materials," Energies, MDPI, vol. 16(4), pages 1-14, February.

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