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Li-B Alloy as an Anode Material for Stable and Long Life Lithium Metal Batteries

Author

Listed:
  • Qiang Liu

    (Wuhan Institute of Marine Electric Propulsion, China Shipbuilding Industry Corporation, Wuhan 430064, China)

  • Sisi Zhou

    (Wuhan Institute of Marine Electric Propulsion, China Shipbuilding Industry Corporation, Wuhan 430064, China)

  • Cong Tang

    (Faculty of Materials Science and Chemistry, China University of Geosciences, Wuhan 430074, China)

  • Qiaoling Zhai

    (Faculty of Materials Science and Chemistry, China University of Geosciences, Wuhan 430074, China)

  • Xianggong Zhang

    (Wuhan Institute of Marine Electric Propulsion, China Shipbuilding Industry Corporation, Wuhan 430064, China)

  • Rui Wang

    (Faculty of Materials Science and Chemistry, China University of Geosciences, Wuhan 430074, China)

Abstract

Rechargeable Li metal batteries have attracted lots of attention because they can achieve high energy densities. However, the commercialization of rechargeable Li metal batteries is delayed because Li dendrites may be generated during the batteries’ electrochemical cycles, which may cause severe safety issues. In this research, a Li-B alloy is investigated as an anode for rechargeable batteries instead of Li metal. Results show that the Li-B alloy has better effects in suppressing the formation of dendritic lithium, reducing the interface impedance and improving the cycle performance. These effects may result from the unique structure of Li-B alloy, in which free lithium is embedded in the Li 7 B 6 framework. These results suggest that Li-B alloy may be a promising anode material applicable in rechargeable lithium batteries.

Suggested Citation

  • Qiang Liu & Sisi Zhou & Cong Tang & Qiaoling Zhai & Xianggong Zhang & Rui Wang, 2018. "Li-B Alloy as an Anode Material for Stable and Long Life Lithium Metal Batteries," Energies, MDPI, vol. 11(10), pages 1-5, September.
    • Handle: RePEc:gam:jeners:v:11:y:2018:i:10:p:2512-:d:171230
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    References listed on IDEAS

    as
    1. Mukul D. Tikekar & Snehashis Choudhury & Zhengyuan Tu & Lynden A. Archer, 2016. "Design principles for electrolytes and interfaces for stable lithium-metal batteries," Nature Energy, Nature, vol. 1(9), pages 1-7, September.
    2. Holger C. Hesse & Michael Schimpe & Daniel Kucevic & Andreas Jossen, 2017. "Lithium-Ion Battery Storage for the Grid—A Review of Stationary Battery Storage System Design Tailored for Applications in Modern Power Grids," Energies, MDPI, vol. 10(12), pages 1-42, December.
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    Cited by:

    1. Bin Zhao & Qi Wang & Boheng Yuan & Yafei Lu & Xiaogang Han, 2021. "An All-Solid-State Lithium Metal Battery Based on Electrodes-Compatible Plastic Crystal Electrolyte," Energies, MDPI, vol. 14(21), pages 1-9, October.

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