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Development of a Unique Technology for the Pyrolysis of Rice Husk Biochar for Promising Heavy Metal Remediation

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  • Ilia Lobzenko

    (Academy of Biology and Biotechnology named after D.I. Ivanovsky, Southern Federal University, 344006 Rostov-on-Don, Russia)

  • Marina Burachevskaya

    (Academy of Biology and Biotechnology named after D.I. Ivanovsky, Southern Federal University, 344006 Rostov-on-Don, Russia)

  • Inna Zamulina

    (Academy of Biology and Biotechnology named after D.I. Ivanovsky, Southern Federal University, 344006 Rostov-on-Don, Russia)

  • Anatoly Barakhov

    (Academy of Biology and Biotechnology named after D.I. Ivanovsky, Southern Federal University, 344006 Rostov-on-Don, Russia)

  • Tatiana Bauer

    (Academy of Biology and Biotechnology named after D.I. Ivanovsky, Southern Federal University, 344006 Rostov-on-Don, Russia)

  • Saglara Mandzhieva

    (Academy of Biology and Biotechnology named after D.I. Ivanovsky, Southern Federal University, 344006 Rostov-on-Don, Russia)

  • Svetlana Sushkova

    (Academy of Biology and Biotechnology named after D.I. Ivanovsky, Southern Federal University, 344006 Rostov-on-Don, Russia)

  • Tatiana Minkina

    (Academy of Biology and Biotechnology named after D.I. Ivanovsky, Southern Federal University, 344006 Rostov-on-Don, Russia)

  • Andrey Tereschenko

    (Academy of Biology and Biotechnology named after D.I. Ivanovsky, Southern Federal University, 344006 Rostov-on-Don, Russia)

  • Valery Kalinichenko

    (Institute of Fertility of Soils of South Russia, 346493 Persianovka, Russia)

  • Oleg Khroniuk

    (Academy of Biology and Biotechnology named after D.I. Ivanovsky, Southern Federal University, 344006 Rostov-on-Don, Russia)

  • Vishnu D. Rajput

    (Academy of Biology and Biotechnology named after D.I. Ivanovsky, Southern Federal University, 344006 Rostov-on-Don, Russia)

Abstract

Due to anthropogenic activities, potentially toxic elements cause severe soil pollution worldwide. Therefore, remediation of contaminated soils is exigent and imperative. One cost-effective and environmentally friendly remediation approach is the application of biochar, which is a solid carbonaceous material. Biochar degrades slowly in soil and can persist there for thousands of years, according to various estimations. In addition, coal obtained from crop wastes has a developed porous structure, a high specific surface area, and does not contain toxic compounds such as heavy metals and polycyclic aromatic hydrocarbons. Biochar with optimal values for specific surface area and porosity was obtained from rice husk by stepwise pyrolysis. The pyrolysis parameters such as the heating rate (11 °C∙min −1 ), temperature (700 °C), and holding time (45 min) were established. At the same time, the surface area of the biochar increased by almost three times with a change in the pyrolysis conditions. As a part of this research, the efficacy of adsorption of Cu(II) from Haplic Chernozem using biochar made from rice husk was examined. The Langmuir and Freundlich models were employed to describe the adsorption data. The isotherm data of heavy metals was better fitted to the Langmuir adsorption model. The addition of rice husk biochar to the soil presented greater removal efficiencies of Cu(II) than soil in pure form. The analysis of the structural characteristics of the sorbent suggest that this material may work efficiently for the restoration of contaminated soil.

Suggested Citation

  • Ilia Lobzenko & Marina Burachevskaya & Inna Zamulina & Anatoly Barakhov & Tatiana Bauer & Saglara Mandzhieva & Svetlana Sushkova & Tatiana Minkina & Andrey Tereschenko & Valery Kalinichenko & Oleg Khr, 2022. "Development of a Unique Technology for the Pyrolysis of Rice Husk Biochar for Promising Heavy Metal Remediation," Agriculture, MDPI, vol. 12(10), pages 1-11, October.
    • Handle: RePEc:gam:jagris:v:12:y:2022:i:10:p:1689-:d:941813
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    References listed on IDEAS

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    1. Yonglong Lu & Nebojsa Nakicenovic & Martin Visbeck & Anne-Sophie Stevance, 2015. "Policy: Five priorities for the UN Sustainable Development Goals," Nature, Nature, vol. 520(7548), pages 432-433, April.
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    Cited by:

    1. Seyede Roghie Ghadirnezhad Shiade & Amin Fathi & Tatiana Minkina & Ming Hung Wong & Vishnu D. Rajput, 2024. "Biochar application in agroecosystems: a review of potential benefits and limitations," Environment, Development and Sustainability: A Multidisciplinary Approach to the Theory and Practice of Sustainable Development, Springer, vol. 26(8), pages 19231-19255, August.
    2. Mohammad Faizan & Pravej Alam & Vishnu D. Rajput & Ahmad Faraz & Shadma Afzal & S. Maqbool Ahmed & Fang-Yuan Yu & Tatiana Minkina & Shamsul Hayat, 2023. "Nanoparticle Mediated Plant Tolerance to Heavy Metal Stress: What We Know?," Sustainability, MDPI, vol. 15(2), pages 1-14, January.

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