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Molybdenum carbide nanoparticle: Understanding the surface properties and reaction mechanism for energy production towards a sustainable future

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  • Alaba, Peter Adeniyi
  • Abbas, Ali
  • Huang, Jun
  • Daud, Wan Mohd Ashri Wan

Abstract

Rational design and synthesis of cheap, noble metal-free, thermal/hydrothermal stable and active catalyst for efficient hydrogenation and hydrogen production reaction is crucial towards renewable and sustainable energy generation. This gives the use of molybdenum carbide nanoparticle considerable attention as an alternative to noble metals. However, the industrial application is not yet feasible due to insufficient stability and activity coupled with the lack of detailed understanding of the reaction mechanism. This work discusses the effect of the operating parameters on the properties and morphology of molybdenum carbide nanoparticle, as well as their impact on the catalytic activity. Critical issues such as structural diversity, surface properties, and multiscale reaction modeling are also discussed for better understanding of the reaction mechanism. This is a promising strategy towards synthesis of cost-effective and efficient catalysts for renewable and sustainable energy production.

Suggested Citation

  • Alaba, Peter Adeniyi & Abbas, Ali & Huang, Jun & Daud, Wan Mohd Ashri Wan, 2018. "Molybdenum carbide nanoparticle: Understanding the surface properties and reaction mechanism for energy production towards a sustainable future," Renewable and Sustainable Energy Reviews, Elsevier, vol. 91(C), pages 287-300.
    • Handle: RePEc:eee:rensus:v:91:y:2018:i:c:p:287-300
    DOI: 10.1016/j.rser.2018.03.106
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    References listed on IDEAS

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    1. Seung-Hoon Jhi & Jisoon Ihm & Steven G. Louie & Marvin L. Cohen, 1999. "Electronic mechanism of hardness enhancement in transition-metal carbonitrides," Nature, Nature, vol. 399(6732), pages 132-134, May.
    2. Iman Tahamtan & Askar Safipour Afshar & Khadijeh Ahamdzadeh, 2016. "Factors affecting number of citations: a comprehensive review of the literature," Scientometrics, Springer;Akadémiai Kiadó, vol. 107(3), pages 1195-1225, June.
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    Cited by:

    1. Escalante, Jamin & Chen, Wei-Hsin & Tabatabaei, Meisam & Hoang, Anh Tuan & Kwon, Eilhann E. & Andrew Lin, Kun-Yi & Saravanakumar, Ayyadurai, 2022. "Pyrolysis of lignocellulosic, algal, plastic, and other biomass wastes for biofuel production and circular bioeconomy: A review of thermogravimetric analysis (TGA) approach," Renewable and Sustainable Energy Reviews, Elsevier, vol. 169(C).

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