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Reactor for biomass conversion and waste treatment in supercritical water: A review

Author

Listed:
  • Chen, Zhong
  • Chen, Hongzhen
  • Xu, Yuanjian
  • Hu, Mian
  • Hu, Zhongting
  • Wang, Junliang
  • Pan, Zhiyan

Abstract

Hydrothermal treatment of renewable biomass and organic waste using supercritical water (SCW) is a sustainable, green, and efficient route for achieving energy recovery, chemicals production, and harmless treatment. The reactor is undoubtedly the central arena where various SCW reactions perform. This review is the first to focus on the special topic, i.e., SCW reactors for biomass conversion and waste treatment. All reported reactors have been classified into three groups to discuss their individual merits and demerits, with a particular focus on their advanced aspects, to minimize or overcome their inherent technical problems (corrosion, plugging, safety issues, poor accessibility, and high energy cost). The first group—metallic reactors—includes tank and tube reactors. These are the most commonly used reactors for diverse SCW processes, and can be operated in three modes: batch, semi-batch, and continuous. The second group includes visual reactors, which are the most attractive experimental devices for SCW processes because they enable visual observation and in situ optical detection. These include X-ray/neutron-radiography-based reactors, the diamond anvil cell, sapphire window reactor, fused silica/quartz capillary reactors, and analogous transparent reactors. The last group includes specially designed reactors for different SCW processes geared toward industrial applications, such as reactors for SCW-based hydrolysis, upgrading, gasification, and oxidation. This review provides comprehensive information for the non-expert reader to select a suitable experimental device for fundamental research and discusses diverse advanced concepts for the development of industrial reactors.

Suggested Citation

  • Chen, Zhong & Chen, Hongzhen & Xu, Yuanjian & Hu, Mian & Hu, Zhongting & Wang, Junliang & Pan, Zhiyan, 2023. "Reactor for biomass conversion and waste treatment in supercritical water: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 171(C).
  • Handle: RePEc:eee:rensus:v:171:y:2023:i:c:s1364032122009121
    DOI: 10.1016/j.rser.2022.113031
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    References listed on IDEAS

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    1. Cabeza, Pablo & Silva Queiroz, Joao Paulo & Criado, Manuel & Jiménez, Cristina & Bermejo, Maria Dolores & Mato, Fidel & Cocero, Maria Jose, 2015. "Supercritical water oxidation for energy production by hydrothermal flame as internal heat source. Experimental results and energetic study," Energy, Elsevier, vol. 90(P2), pages 1584-1594.
    2. Wang, Yuanqing & Jin, Fangming & Zeng, Xu & Ma, Cuixiang & Wang, Fengwen & Yao, Guodong & Jing, Zhenzi, 2013. "Catalytic activity of Ni3S2 and effects of reactor wall in hydrogen production from water with hydrogen sulphide as a reducer under hydrothermal conditions," Applied Energy, Elsevier, vol. 104(C), pages 306-309.
    3. Gutiérrez Ortiz, F.J. & Campanario, F.J. & Aguilera, P.G. & Ollero, P., 2016. "Supercritical water reforming of glycerol: Performance of Ru and Ni catalysts on Al2O3 support," Energy, Elsevier, vol. 96(C), pages 561-568.
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    Cited by:

    1. Azwifunimunwe Tshikovhi & Tshwafo Ellias Motaung, 2023. "Technologies and Innovations for Biomass Energy Production," Sustainability, MDPI, vol. 15(16), pages 1-21, August.

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