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Material degradation of components in polymer electrolyte membrane (PEM) electrolytic cell and mitigation mechanisms: A review

Author

Listed:
  • Khatib, F.N.
  • Wilberforce, Tabbi
  • Ijaodola, Oluwatosin
  • Ogungbemi, Emmanuel
  • El-Hassan, Zaki
  • Durrant, A.
  • Thompson, J.
  • Olabi, A.G.

Abstract

Hydrogen is increasingly becoming an important element in the quest for clean energy and pollution free transport and this investigation concentrates on one aspect of the hydrogen supply chain which is its production. This work reviews current methods for production of hydrogen and discusses the negative impacts of methods that depend on fossil material to produce hydrogen. The work then reviews the technologies for production of hydrogen using water electrolysis as a clean source of hydrogen production utilising energy from renewables with strong emphasis on the use of polymer electrolyte membrane (PEM) electrolytic cells. The components of PEM electrolyser cell are analysed and their impact on the cell operations are examined. The work discusses the performance of PEM electrolysers and examines the different challenges that face the development of these cells components and the effect of operational conditions on cell construction materials and their longevity. The work analyse published research that discusses the impact cells material deterioration has on cell performance and deviation from optimum operational conditions. Degradation effects at varying operational conditions are discussed along with some mitigation strategies that can be used to improve cells durability and efficiency. This includes the material composition of components in the electrolyser that contribute significantly to the overall efficiency of the cell.

Suggested Citation

  • Khatib, F.N. & Wilberforce, Tabbi & Ijaodola, Oluwatosin & Ogungbemi, Emmanuel & El-Hassan, Zaki & Durrant, A. & Thompson, J. & Olabi, A.G., 2019. "Material degradation of components in polymer electrolyte membrane (PEM) electrolytic cell and mitigation mechanisms: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 111(C), pages 1-14.
    • Handle: RePEc:eee:rensus:v:111:y:2019:i:c:p:1-14
    DOI: 10.1016/j.rser.2019.05.007
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    1. Dihrab, Salwan S. & Sopian, K. & Alghoul, M.A. & Sulaiman, M.Y., 2009. "Review of the membrane and bipolar plates materials for conventional and unitized regenerative fuel cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 13(6-7), pages 1663-1668, August.
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    6. Tabbi Wilberforce & Abdul Ghani Olabi, 2020. "Performance Prediction of Proton Exchange Membrane Fuel Cells (PEMFC) Using Adaptive Neuro Inference System (ANFIS)," Sustainability, MDPI, vol. 12(12), pages 1-16, June.
    7. Hernández-Gómez, Ángel & Ramirez, Victor & Guilbert, Damien & Saldivar, Belem, 2021. "Cell voltage static-dynamic modeling of a PEM electrolyzer based on adaptive parameters: Development and experimental validation," Renewable Energy, Elsevier, vol. 163(C), pages 1508-1522.
    8. Abed Alaswad & Abdelnasir Omran & Jose Ricardo Sodre & Tabbi Wilberforce & Gianmichelle Pignatelli & Michele Dassisti & Ahmad Baroutaji & Abdul Ghani Olabi, 2020. "Technical and Commercial Challenges of Proton-Exchange Membrane (PEM) Fuel Cells," Energies, MDPI, vol. 14(1), pages 1-21, December.
    9. Lee, Boreum & Lim, Dongjun & Lee, Hyunjun & Lim, Hankwon, 2021. "Which water electrolysis technology is appropriate?: Critical insights of potential water electrolysis for green ammonia production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 143(C).
    10. Pan, Mingzhang & Pan, Chengjie & Li, Chao & Zhao, Jian, 2021. "A review of membranes in proton exchange membrane fuel cells: Transport phenomena, performance and durability," Renewable and Sustainable Energy Reviews, Elsevier, vol. 141(C).
    11. Abdul Ghani Olabi & Tabbi Wilberforce & Abdulrahman Alanazi & Parag Vichare & Enas Taha Sayed & Hussein M. Maghrabie & Khaled Elsaid & Mohammad Ali Abdelkareem, 2022. "Novel Trends in Proton Exchange Membrane Fuel Cells," Energies, MDPI, vol. 15(14), pages 1-35, July.
    12. Wang, Xuefei & Luo, Hong & Cheng, Hongxu & Yue, Luo & Deng, Zhanfeng & Yao, Jizheng & Li, Xiaogang, 2024. "Investigation on the performance of Pt surface modified Ti bipolar plates in proton exchange membrane water electrolyzer," Applied Energy, Elsevier, vol. 357(C).
    13. Sayed, Enas Taha & Abdelkareem, Mohammad Ali & Bahaa, Ahmed & Eisa, Tasnim & Alawadhi, Hussain & Al-Asheh, Sameer & Chae, Kyu-Jung & Olabi, A.G., 2021. "Synthesis and performance evaluation of various metal chalcogenides as active anodes for direct urea fuel cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 150(C).
    14. Hui Xing & Charles Stuart & Stephen Spence & Hua Chen, 2021. "Fuel Cell Power Systems for Maritime Applications: Progress and Perspectives," Sustainability, MDPI, vol. 13(3), pages 1-34, January.
    15. Mayyas, Ahmad & Chadly, Assia & Amer, Saed Talib & Azar, Elie, 2022. "Economics of the Li-ion batteries and reversible fuel cells as energy storage systems when coupled with dynamic electricity pricing schemes," Energy, Elsevier, vol. 239(PA).
    16. Olabi, A.G. & Wilberforce, Tabbi & Abdelkareem, Mohammad Ali, 2021. "Fuel cell application in the automotive industry and future perspective," Energy, Elsevier, vol. 214(C).
    17. Ana P. R. A. Ferreira & Raisa C. P. Oliveira & Maria Margarida Mateus & Diogo M. F. Santos, 2023. "A Review of the Use of Electrolytic Cells for Energy and Environmental Applications," Energies, MDPI, vol. 16(4), pages 1-33, February.
    18. Olabi, A.G. & Abdelkareem, Mohammad Ali, 2022. "Renewable energy and climate change," Renewable and Sustainable Energy Reviews, Elsevier, vol. 158(C).

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