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Characterization of bio-oil and its sub-fractions from pyrolysis of Scenedesmus dimorphus

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  • Bordoloi, Neonjyoti
  • Narzari, Rumi
  • Sut, Debashis
  • Saikia, Ruprekha
  • Chutia, Rahul Singh
  • Kataki, Rupam

Abstract

In the present study, microalgae Scenedesmus dimorphus was reported for pyrolysis in a fixed-bed reactor to determine the effects of temperature on products yield and the chemical compositions of the liquid and solid products. Experiments were carried out at a temperature range of 300–600 °C with heating rate of 40 °C/min and nitrogen flow rate of 100 ml/min. The yield of bio-oil was found to be maximum (39.6%) at the temperature of 500 °C and was further fractionated into n-hexane, toluene, ethyl acetate and methanol sub-fractions by using liquid column chromatography. Various characteristics of bio-oil and its sub-fractions were determined by 1H NMR, FTIR and GC–MS. The biochar produced as a co-product can be a potential soil amendment with multiple benefits including soil fertility and C-sequestration. The present investigation suggests the suitability of Scenedesmus dimorphus as a potential feedstock for exploitation of energy and biomaterials through pyrolytic conversion.

Suggested Citation

  • Bordoloi, Neonjyoti & Narzari, Rumi & Sut, Debashis & Saikia, Ruprekha & Chutia, Rahul Singh & Kataki, Rupam, 2016. "Characterization of bio-oil and its sub-fractions from pyrolysis of Scenedesmus dimorphus," Renewable Energy, Elsevier, vol. 98(C), pages 245-253.
    • Handle: RePEc:eee:renene:v:98:y:2016:i:c:p:245-253
    DOI: 10.1016/j.renene.2016.03.081
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    1. Phukan, Mayur M. & Chutia, Rahul S. & Konwar, B.K. & Kataki, R., 2011. "Microalgae Chlorella as a potential bio-energy feedstock," Applied Energy, Elsevier, vol. 88(10), pages 3307-3312.
    2. Brennan, Liam & Owende, Philip, 2010. "Biofuels from microalgae--A review of technologies for production, processing, and extractions of biofuels and co-products," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(2), pages 557-577, February.
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