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Kinetic of myristic acid esterification with methanol in the presence of triglycerides over sulfated zirconia

Author

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  • Rattanaphra, Dussadee
  • Harvey, Adam P.
  • Thanapimmetha, Anusith
  • Srinophakun, Penjit

Abstract

The esterification of myristic acid with methanol in presence of triglycerides using sulfated zirconia prepared by solvent-free method as the heterogeneous catalyst was studied. The effects of reaction temperature (393–443 K), catalyst loading (1–3 %wt) and molar ratio of oil to methanol (1:4–1:20) on the conversion of myristic acid were investigated. The experimental data was interpreted with a second order pseudo-homogeneous kinetic model. The kinetic parameters were obtained. A good agreement between the experimental data and the model was observed. Sulfated zirconia prepared by solvent-free method exhibited high catalytic activity for this reaction. Low activation energy of 22.51 kJ mol−1 was obtained in the range of temperature of 393–443 K.

Suggested Citation

  • Rattanaphra, Dussadee & Harvey, Adam P. & Thanapimmetha, Anusith & Srinophakun, Penjit, 2011. "Kinetic of myristic acid esterification with methanol in the presence of triglycerides over sulfated zirconia," Renewable Energy, Elsevier, vol. 36(10), pages 2679-2686.
    • Handle: RePEc:eee:renene:v:36:y:2011:i:10:p:2679-2686
    DOI: 10.1016/j.renene.2011.02.018
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    Cited by:

    1. Kaur, Navjot & Ali, Amjad, 2015. "Preparation and application of Ce/ZrO2−TiO2/SO42− as solid catalyst for the esterification of fatty acids," Renewable Energy, Elsevier, vol. 81(C), pages 421-431.
    2. Hernández-Montelongo, Rosaura & García-Sandoval, Juan Paulo & González-Álvarez, Alejandro & Dochain, Denis & Aguilar-Garnica, Efrén, 2018. "Biodiesel production in a continuous packed bed reactor with recycle: A modeling approach for an esterification system," Renewable Energy, Elsevier, vol. 116(PA), pages 857-865.
    3. Patel, Anjali & Brahmkhatri, Varsha & Singh, Namita, 2013. "Biodiesel production by esterification of free fatty acid over sulfated zirconia," Renewable Energy, Elsevier, vol. 51(C), pages 227-233.
    4. Borges, M.E. & Díaz, L., 2012. "Recent developments on heterogeneous catalysts for biodiesel production by oil esterification and transesterification reactions: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(5), pages 2839-2849.
    5. Talebian-Kiakalaieh, Amin & Amin, Nor Aishah Saidina & Mazaheri, Hossein, 2013. "A review on novel processes of biodiesel production from waste cooking oil," Applied Energy, Elsevier, vol. 104(C), pages 683-710.
    6. Mauro Banchero & Giuseppe Gozzelino, 2018. "A Simple Pseudo-Homogeneous Reversible Kinetic Model for the Esterification of Different Fatty Acids with Methanol in the Presence of Amberlyst-15," Energies, MDPI, vol. 11(7), pages 1-12, July.

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