IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v203y2023icp779-787.html
   My bibliography  Save this article

Bulk and surface modified polycrystalline CuWO4 films for photoelectrochemical water oxidation

Author

Listed:
  • Lee, Jin Uk
  • Kim, Jeong Hun
  • Kang, Kyungwoong
  • Shin, Yun Seop
  • Kim, Jin Young
  • Kim, Jin Hyun
  • Lee, Jae Sung

Abstract

Polycrystalline CuWO4 film is an emerging photoanode material for photoelectrochemical (PEC) water splitting with a small bandgap to absorb visible light and excellent stability in a neutral electrolyte. However, its PEC performance is quite low mainly due to its poor charge transfer characteristics. To enhance the performance of the CuWO4 photoanode, two modification strategies are employed; SnO2 as an electron transfer layer to improve the bulk charge separation efficiency of CuWO4 and cobalt phosphate as a co-catalyst to augment the surface charge separation efficiency at the interface of CuWO4||electrolyte. The two modifications enhance the PEC activity two times to 0.13 mA/cm2 @ 1.23 VRHE for water oxidation and 0.24 mA/cm2 @ 1.23 VRHE for hole scavenger oxidation, and exhibit an excellent stability in a neutral electrolyte. Although the performance is still very low compared to well-developed metal oxide photoanodes, this work shows possibility of further improvement with further developments of synthesis method as well as applying other elaborate modification strategies.

Suggested Citation

  • Lee, Jin Uk & Kim, Jeong Hun & Kang, Kyungwoong & Shin, Yun Seop & Kim, Jin Young & Kim, Jin Hyun & Lee, Jae Sung, 2023. "Bulk and surface modified polycrystalline CuWO4 films for photoelectrochemical water oxidation," Renewable Energy, Elsevier, vol. 203(C), pages 779-787.
    • Handle: RePEc:eee:renene:v:203:y:2023:i:c:p:779-787
    DOI: 10.1016/j.renene.2022.12.129
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148122019255
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2022.12.129?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Hyosung Choi & Cheng-Kang Mai & Hak-Beom Kim & Jaeki Jeong & Seyeong Song & Guillermo C. Bazan & Jin Young Kim & Alan J. Heeger, 2015. "Conjugated polyelectrolyte hole transport layer for inverted-type perovskite solar cells," Nature Communications, Nature, vol. 6(1), pages 1-6, November.
    2. Ji-Wook Jang & Chun Du & Yifan Ye & Yongjing Lin & Xiahui Yao & James Thorne & Erik Liu & Gregory McMahon & Junfa Zhu & Ali Javey & Jinghua Guo & Dunwei Wang, 2015. "Enabling unassisted solar water splitting by iron oxide and silicon," Nature Communications, Nature, vol. 6(1), pages 1-5, November.
    3. Jin Hyun Kim & Ji-Wook Jang & Yim Hyun Jo & Fatwa F. Abdi & Young Hye Lee & Roel van de Krol & Jae Sung Lee, 2016. "Hetero-type dual photoanodes for unbiased solar water splitting with extended light harvesting," Nature Communications, Nature, vol. 7(1), pages 1-9, December.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Hamdani, I.R. & Bhaskarwar, A.N., 2021. "Recent progress in material selection and device designs for photoelectrochemical water-splitting," Renewable and Sustainable Energy Reviews, Elsevier, vol. 138(C).
    2. Stephanie J. Boyd & Run Long & Niall J. English, 2022. "Electric Field Effects on Photoelectrochemical Water Splitting: Perspectives and Outlook," Energies, MDPI, vol. 15(4), pages 1-16, February.
    3. Rashmi Mehrotra & Dongrak Oh & Ji-Wook Jang, 2021. "Unassisted selective solar hydrogen peroxide production by an oxidised buckypaper-integrated perovskite photocathode," Nature Communications, Nature, vol. 12(1), pages 1-9, December.
    4. Camilo A. Mesa & Michael Sachs & Ernest Pastor & Nicolas Gauriot & Alice J. Merryweather & Miguel A. Gomez-Gonzalez & Konstantin Ignatyev & Sixto Giménez & Akshay Rao & James R. Durrant & Raj Pandya, 2024. "Correlating activities and defects in (photo)electrocatalysts using in-situ multi-modal microscopic imaging," Nature Communications, Nature, vol. 15(1), pages 1-12, December.
    5. Dhandole, Love Kumar & Anushkkaran, Periyasamy & Hwang, Jun Beom & Chae, Weon-Sik & Kumar, Manish & Lee, Hyun-Hwi & Choi, Sun Hee & Jang, Jum Suk & Lee, Jae Sung, 2022. "Microwave-assisted metal-ion attachment for ex-situ zirconium doping into hematite for enhanced photoelectrochemical water splitting," Renewable Energy, Elsevier, vol. 189(C), pages 694-703.
    6. Maheswari Arunachalam & Rohini Subhash Kanase & Kai Zhu & Soon Hyung Kang, 2023. "Reliable bi-functional nickel-phosphate /TiO2 integration enables stable n-GaAs photoanode for water oxidation under alkaline condition," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    7. Liang, Mengjun & Karthick, Ramalingam & Wei, Qiang & Dai, Jinhong & Jiang, Zhuosheng & Chen, Xuncai & Oo, Than Zaw & Aung, Su Htike & Chen, Fuming, 2022. "The progress and prospect of the solar-driven photoelectrochemical desalination," Renewable and Sustainable Energy Reviews, Elsevier, vol. 155(C).
    8. Mehmood, Umer & Al-Ahmed, Amir & Afzaal, Mohammad & Al-Sulaiman, Fahad A. & Daud, Muhammad, 2017. "Recent progress and remaining challenges in organometallic halides based perovskite solar cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 78(C), pages 1-14.
    9. Tayebi, Meysam & Lee, Byeong-Kyu, 2019. "Recent advances in BiVO4 semiconductor materials for hydrogen production using photoelectrochemical water splitting," Renewable and Sustainable Energy Reviews, Elsevier, vol. 111(C), pages 332-343.
    10. Zeng, Qingyi & Bai, Jing & Li, Jinhua & Li, Linsen & Xia, Ligang & Zhou, Baoxue & Sun, Yugang, 2018. "Highly-stable and efficient photocatalytic fuel cell based on an epitaxial TiO2/WO3/W nanothorn photoanode and enhanced radical reactions for simultaneous electricity production and wastewater treatme," Applied Energy, Elsevier, vol. 220(C), pages 127-137.
    11. Yuyang Pan & Huiyan Zhang & Bowen Zhang & Feng Gong & Jianyong Feng & Huiting Huang & Srinivas Vanka & Ronglei Fan & Qi Cao & Mingrong Shen & Zhaosheng Li & Zhigang Zou & Rui Xiao & Sheng Chu, 2023. "Renewable formate from sunlight, biomass and carbon dioxide in a photoelectrochemical cell," Nature Communications, Nature, vol. 14(1), pages 1-10, December.
    12. Saraswat, Sushil Kumar & Rodene, Dylan D. & Gupta, Ram B., 2018. "Recent advancements in semiconductor materials for photoelectrochemical water splitting for hydrogen production using visible light," Renewable and Sustainable Energy Reviews, Elsevier, vol. 89(C), pages 228-248.
    13. Chao Zhen & Xiangtao Chen & Ruotian Chen & Fengtao Fan & Xiaoxiang Xu & Yuyang Kang & Jingdong Guo & Lianzhou Wang & Gao Qing (Max) Lu & Kazunari Domen & Hui-Ming Cheng & Gang Liu, 2024. "Liquid metal-embraced photoactive films for artificial photosynthesis," Nature Communications, Nature, vol. 15(1), pages 1-13, December.
    14. Sang Eon Jun & Youn-Hye Kim & Jaehyun Kim & Woo Seok Cheon & Sungkyun Choi & Jinwook Yang & Hoonkee Park & Hyungsoo Lee & Sun Hwa Park & Ki Chang Kwon & Jooho Moon & Soo-Hyun Kim & Ho Won Jang, 2023. "Atomically dispersed iridium catalysts on silicon photoanode for efficient photoelectrochemical water splitting," Nature Communications, Nature, vol. 14(1), pages 1-11, December.
    15. Yuri Choi & Rashmi Mehrotra & Sang-Hak Lee & Trang Vu Thien Nguyen & Inhui Lee & Jiyeong Kim & Hwa-Young Yang & Hyeonmyeong Oh & Hyunwoo Kim & Jae-Won Lee & Yong Hwan Kim & Sung-Yeon Jang & Ji-Wook Ja, 2022. "Bias-free solar hydrogen production at 19.8 mA cm−2 using perovskite photocathode and lignocellulosic biomass," Nature Communications, Nature, vol. 13(1), pages 1-9, December.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:203:y:2023:i:c:p:779-787. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.