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Regenerable sodium-based lithium silicate sorbents with a new mechanism for CO2 capture at high temperature

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  • Kwon, Yong Mok
  • Lee, Soo Chool
  • Chae, Ho Jin
  • Cho, Min Sun
  • Park, Yong Ki
  • Seo, Hwi Min
  • Chang Kim, Jae

Abstract

Recently, lithium-ion batteries have become widespread as a source of power or energy for everything from portable electronics to electric vehicles. As a result, the consumption of lithium is rapidly increasing, accompanied by an increase in its price. This study reports the synthesis of a regenerable sodium-based lithium silicate solid sorbent that uses less lithium than Li4SiO4 solid sorbents. The regenerable sodium-based lithium silicate solid sorbent was prepared by mixing LiOH with a sodium silicate solution in a 2:1 M ratio, which steadily maintained its CO2 capture capacity during multiple cycles. In addition to Li4SiO4 present in the developed solid sorbent, we attribute CO2 sorption and regeneration to a new structure, namely Li3NaSiO4. Notably, the LONS2 solid sorbent exhibits a faster CO2 sorption rate than that of the Li4SiO4 sorbent. Moreover, the LONS2 solid sorbent containing both Li3NaSiO4 and Li4SiO4 phases has potential for CO2 capture at high temperature.

Suggested Citation

  • Kwon, Yong Mok & Lee, Soo Chool & Chae, Ho Jin & Cho, Min Sun & Park, Yong Ki & Seo, Hwi Min & Chang Kim, Jae, 2019. "Regenerable sodium-based lithium silicate sorbents with a new mechanism for CO2 capture at high temperature," Renewable Energy, Elsevier, vol. 144(C), pages 180-187.
  • Handle: RePEc:eee:renene:v:144:y:2019:i:c:p:180-187
    DOI: 10.1016/j.renene.2018.08.039
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    References listed on IDEAS

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    1. Wang, Ke & Zhou, Zhongyun & Zhao, Pengfei & Yin, Zeguang & Su, Zhen & Sun, Ji, 2016. "Synthesis of a highly efficient Li4SiO4 ceramic modified with a gluconic acid-based carbon coating for high-temperature CO2 capture," Applied Energy, Elsevier, vol. 183(C), pages 1418-1427.
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    More about this item

    Keywords

    CO2 capture; Li3NaSiO4; Li4SiO4; Li2SiO3; Solid sorbent;
    All these keywords.

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