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Reciprocal relations based on the non-stationary Boltzmann equation

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  • Sharipov, Felix

Abstract

The reciprocal relations for open gaseous systems are obtained on the basis of main properties of the non-stationary Boltzmann equation and gas–surface interaction law. It is shown that the main principles to derive the kinetic coefficients satisfying the reciprocal relations remain the same as those used for time-independent gaseous systems [F. Sharipov, Onsager–Casimir reciprocal relations based on the Boltzmann equation and gas–surface interaction law single gas, Phys. Rev. 73 (2006) 026110]. First, the kinetic coefficients are obtained from the entropy production expression; then it is proved that the coefficient matrix calculated for time reversed source functions is symmetric. The proof is based on the reversibility of the gas–gas and gas–surface interactions. Three examples of applications of the present theory are given. None of these examples can be treated in the frame of the classical Onsager–Casimir reciprocal relations, which are valid only in a particular case, when the kinetic coefficients are odd or even with respect to the time reversion. The approach is generalized for gaseous mixtures.

Suggested Citation

  • Sharipov, Felix, 2012. "Reciprocal relations based on the non-stationary Boltzmann equation," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 391(5), pages 1972-1983.
    • Handle: RePEc:eee:phsmap:v:391:y:2012:i:5:p:1972-1983
    DOI: 10.1016/j.physa.2011.11.033
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    References listed on IDEAS

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    1. Naris, S & Valougeorgis, D & Kalempa, D & Sharipov, F, 2004. "Gaseous mixture flow between two parallel plates in the whole range of the gas rarefaction," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 336(3), pages 294-318.
    2. Napier, Duncan G. & Shizgal, Bernie D., 2008. "Sound dispersion in single-component systems," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 387(16), pages 4099-4118.
    3. Sharipov, Felix, 1994. "Onsager-Casimir reciprocity relations for open gaseous systems at arbitrary rarefaction," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 203(3), pages 437-456.
    4. Sharipov, Felix, 2010. "The reciprocal relations between cross phenomena in boundless gaseous systems," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 389(18), pages 3743-3760.
    5. Sharipov, Felix, 1994. "Onsager-Casimir reciprocity relations for open gaseous systems at arbitrary rarefaction III. Theory and its application for gaseous mixtures," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 209(3), pages 457-476.
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