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Living poly(α-methylstyrene) near the polymerization line 6. Chemical kinetics

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  • Zhuang, Juewen
  • Sarkar Das, S.
  • Nowakowski, M.D.
  • Greer, S.C.

Abstract

We present new measurements of the kinetics of polymerization near the polymerization line of poly(α-methylstyrene) in the solvent tetrahydrofuran, initiated by sodium naphthalide or cesium naphthalide. We develop a computer model of the kinetics of the reversible polymerization of this system. We fit the model to the experimental data to obtain rate constants for propagation and depropagation.

Suggested Citation

  • Zhuang, Juewen & Sarkar Das, S. & Nowakowski, M.D. & Greer, S.C., 1997. "Living poly(α-methylstyrene) near the polymerization line 6. Chemical kinetics," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 244(1), pages 522-535.
    • Handle: RePEc:eee:phsmap:v:244:y:1997:i:1:p:522-535
    DOI: 10.1016/S0378-4371(97)00242-2
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    References listed on IDEAS

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    1. Mark R. Greer, 1995. "Aggressive Greenhouse Gas Policies: How They Could Spur Economic Growth," Journal of Economic Issues, Taylor & Francis Journals, vol. 29(4), pages 1045-1062, December.
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    4. Descôtes, L. & Bellissent, R. & Pfeuty, P. & Dianoux, A.J., 1993. "Dynamics of liquid sulphur around the equilibrium polymerization transition," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 201(1), pages 381-385.
    5. Livingstone, Jl, 1967. "Accelerated Depreciation, Cyclical Asset Expenditures And Deferred Taxes," Journal of Accounting Research, Wiley Blackwell, vol. 5(1), pages 77-94.
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