IDEAS home Printed from https://ideas.repec.org/a/eee/phsmap/v205y1994i1p122-139.html
   My bibliography  Save this article

Is there a second critical point in liquid water?

Author

Listed:
  • Stanley, H.E.
  • Angell, C.A.
  • Essmann, U.
  • Hemmati, M.
  • Poole, P.H.
  • Sciortino, F.

Abstract

The supercooled and stretched regions of the phase diagram of simulated liquid water are investigated by calculating the equation of state of the ST2 and TIP4P pair-potentials. We find that simulated water does not display a re-entrant spinodal and that the projection of the density maximum line in the plane of pressure and temperature becomes positively sloped on stretching. The well-known anomalous behavior of supercooled water is tentatively associated with the existence of an inaccessible critical point. Evidence is presented that suggests the association of this new critical point with the transition between low density and high density amorphous solid water. We show how the observed transformation behavior of the two forms of amorphous solid water can be explained in terms of a first order phase transition, via a consideration of the limits of metastability associated with this kind of transition, and support this interpretation with simulations of the amorphous solid. We therefore propose a phase diagram which accounts for the behavior of both liquid and amorphous solid water.

Suggested Citation

  • Stanley, H.E. & Angell, C.A. & Essmann, U. & Hemmati, M. & Poole, P.H. & Sciortino, F., 1994. "Is there a second critical point in liquid water?," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 205(1), pages 122-139.
  • Handle: RePEc:eee:phsmap:v:205:y:1994:i:1:p:122-139
    DOI: 10.1016/0378-4371(94)90495-2
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/0378437194904952
    Download Restriction: Full text for ScienceDirect subscribers only. Journal offers the option of making the article available online on Science direct for a fee of $3,000

    File URL: https://libkey.io/10.1016/0378-4371(94)90495-2?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Buijs, R. & Sluijs, E. M. & Verhaak, P. F. M., 1984. "Byrne and Long: A classification for rating the interview style of doctors," Social Science & Medicine, Elsevier, vol. 19(7), pages 683-690, January.
    2. Debenedetti, Franco, 1987. "Managing the change to advanced manufacturing: Top management's role," European Management Journal, Elsevier, vol. 5(2), pages 68-71, June.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Kiselev, S.B. & Ely, J.F., 2001. "Curvature effect on the physical boundary of metastable states in liquids," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 299(3), pages 357-370.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Galliero, Guillaume & Medvedev, Oleg O. & Shapiro, Alexander A., 2005. "Molecular dynamics simulations of the penetration lengths: application within the fluctuation theory for diffusion coefficients," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 350(2), pages 315-337.

    More about this item

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:phsmap:v:205:y:1994:i:1:p:122-139. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/physica-a-statistical-mechpplications/ .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.