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Transport properties of dense fluids via spherical models of the interaction potential

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  • Nebelenchuk, V.F.
  • Mazur, V.A.

Abstract

The method for evaluation of the dense fluid viscosity and thermal conductivity (translational part) from intermolecular interaction information is derived on the basis of the local similarity principle. The non-equilibrium criteria of mapping a real-system interaction function Ur(R) to the reference Van der Waals potential Ub(R, A) are formulated first. Then the density dependence for the kinetic effective hard-sphere diameter is studied. The test of the proposed approach has been carried out for a number of spherical potential models (Ne-Ne, Ar-Ar, Kr-Kr, Xe-Xe, CO2-CO2, N2-N2, O2-O2) in the range of the reduced densities 0.4

Suggested Citation

  • Nebelenchuk, V.F. & Mazur, V.A., 1991. "Transport properties of dense fluids via spherical models of the interaction potential," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 178(1), pages 123-148.
    • Handle: RePEc:eee:phsmap:v:178:y:1991:i:1:p:123-148
    DOI: 10.1016/0378-4371(91)90077-P
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    1. Alfred Meier & Walter Moser, 1979. "Investitionsverhalten ausgewählter Kantone und Gemeinden in der Rezession," Swiss Journal of Economics and Statistics (SJES), Swiss Society of Economics and Statistics (SSES), vol. 115(IV), pages 689-711, December.
    2. Le Neindre, B. & Garrabos, Y. & Tufeu, R., 1989. "Thermal conductivity of dense noble gases," Physica A: Statistical Mechanics and its Applications, Elsevier, vol. 156(1), pages 512-521.
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