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Releasing behavior of chlorine and fluorine during agricultural waste pyrolysis

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  • Du, Shenglei
  • Wang, Xianhua
  • Shao, Jingai
  • Yang, Haiping
  • Xu, Guangfu
  • Chen, Hanping

Abstract

The releasing behavior of chlorine (Cl) and fluorine (F) during agricultural waste pyrolysis was investigated using a fixed-bed pyrolysis system with pyrohydrolytic-ion chromatography and thermodynamic equilibrium calculation. Agricultural waste contains a large amount of Cl-bearing species, among which approximately 30% is easily released with biomass drying. During biomass pyrolysis, Cl-bearing species evolve out rapidly to the gas phase, and higher temperature is favorable for the releasing. The releasing process can be divided into two ranges: the fast evaporating range (200–600 °C) and slow evaporating range (600–1000 °C). F shows similar transforming behavior. However, higher temperature is preferred for the release. Thermodynamic simulation shows that Cl mainly exists as KCl(g) at higher temperatures (>600 °C) with some HCl(g) and K2Cl2(g) as intermediate species at lower temperatures (<600 °C), whereas F mainly releases as SiF4 at higher temperatures (>500 °C) with SF5Cl being the dominant F-bearing species at lower temperatures (<500 °C).

Suggested Citation

  • Du, Shenglei & Wang, Xianhua & Shao, Jingai & Yang, Haiping & Xu, Guangfu & Chen, Hanping, 2014. "Releasing behavior of chlorine and fluorine during agricultural waste pyrolysis," Energy, Elsevier, vol. 74(C), pages 295-300.
    • Handle: RePEc:eee:energy:v:74:y:2014:i:c:p:295-300
    DOI: 10.1016/j.energy.2014.01.012
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    2. Zhao, Jing & Li, Bo & Wei, Xiaolin & Zhang, Yufeng & Li, Teng, 2020. "Slagging characteristics caused by alkali and alkaline earth metals during municipal solid waste and sewage sludge co-incineration," Energy, Elsevier, vol. 202(C).
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    4. Ling, Jester Lih Jie & Yang, Won & Park, Han Saem & Lee, Ha Eun & Lee, See Hoon, 2023. "A comparative review on advanced biomass oxygen fuel combustion technologies for carbon capture and storage," Energy, Elsevier, vol. 284(C).
    5. Branca, Carmen & Galgano, Antonio & Di Blasi, Colomba, 2023. "Dynamics and products of potato crop residue conversion under a pyrolytic runaway regime - Influences of feedstock variability," Energy, Elsevier, vol. 276(C).
    6. Kajina, Wanida & Rousset, Patrick & Chen, Wei-Hsin & Sornpitak, Thitima & Commandré, Jean Michel, 2018. "Coupled effect of torrefaction and blending on chemical and energy properties for combustion of major open burned agriculture residues in Thailand," Renewable Energy, Elsevier, vol. 118(C), pages 113-121.

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