IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v160y2018icp44-53.html
   My bibliography  Save this article

13X Ex-Cu zeolite performance characterization towards H2S removal for biogas use in molten carbonate fuel cells

Author

Listed:
  • Barelli, Linda
  • Bidini, Gianni
  • Micoli, Luca
  • Sisani, Elena
  • Turco, Maria

Abstract

A 13X zeolite modified with Cu ions (13X Ex-Cu) by means of an innovative technique was employed as adsorbent for H2S removal from biogas, to obtain a desulfurized fuel suitable for molten carbonate fuel cell systems. Sorbent performance was characterized over a wide range of operating conditions typical of biogas mixtures (high H2S content - 200 and 1000 ppmv; CH4 (60%)/CO2 (40%) matrices) and compared to several conventional sorbents. A sensitivity performance analysis was conducted, varying parameters as space velocity, reactor temperature, gas matrix composition and particles size, finalized to identify the optimal conditions for the studied application.

Suggested Citation

  • Barelli, Linda & Bidini, Gianni & Micoli, Luca & Sisani, Elena & Turco, Maria, 2018. "13X Ex-Cu zeolite performance characterization towards H2S removal for biogas use in molten carbonate fuel cells," Energy, Elsevier, vol. 160(C), pages 44-53.
    • Handle: RePEc:eee:energy:v:160:y:2018:i:c:p:44-53
    DOI: 10.1016/j.energy.2018.05.057
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544218308776
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2018.05.057?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Sharaf, Omar Z. & Orhan, Mehmet F., 2014. "An overview of fuel cell technology: Fundamentals and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 32(C), pages 810-853.
    2. Cozzolino, Raffaello & Lombardi, Lidia & Tribioli, Laura, 2017. "Use of biogas from biowaste in a solid oxide fuel cell stack: Application to an off-grid power plant," Renewable Energy, Elsevier, vol. 111(C), pages 781-791.
    3. Divya, D. & Gopinath, L.R. & Merlin Christy, P., 2015. "A review on current aspects and diverse prospects for enhancing biogas production in sustainable means," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 690-699.
    4. Papadias, Dionissios D. & Ahmed, Shabbir & Kumar, Romesh, 2012. "Fuel quality issues with biogas energy – An economic analysis for a stationary fuel cell system," Energy, Elsevier, vol. 44(1), pages 257-277.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Mirzokhid Abdirakhimov & Mohsen H. Al-Rashed & Janusz Wójcik, 2022. "Recent Attempts on the Removal of H 2 S from Various Gas Mixtures Using Zeolites and Waste-Based Adsorbents," Energies, MDPI, vol. 15(15), pages 1-20, July.
    2. Becker, C.M. & Marder, M. & Junges, E. & Konrad, O., 2022. "Technologies for biogas desulfurization - An overview of recent studies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 159(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Das, Himadry Shekhar & Tan, Chee Wei & Yatim, A.H.M., 2017. "Fuel cell hybrid electric vehicles: A review on power conditioning units and topologies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 76(C), pages 268-291.
    2. Jae Yun Jeong & Inje Kang & Ki Seok Choi & Byeong-Hee Lee, 2018. "Network Analysis on Green Technology in National Research and Development Projects in Korea," Sustainability, MDPI, vol. 10(4), pages 1-12, April.
    3. Lv, Xiuqing & Chen, Huili & Zhou, Wei & Li, Si-Dian & Cheng, Fangqin & Shao, Zongping, 2022. "SrCo0.4Fe0.4Zr0.1Y0.1O3-δ, A new CO2 tolerant cathode for proton-conducting solid oxide fuel cells," Renewable Energy, Elsevier, vol. 185(C), pages 8-16.
    4. Zhilong Wei & Lei Wang & Hu Liu & Zihao Liu & Haisheng Zhen, 2021. "Numerical Investigation on the Flame Structure and CO/NO Formations of the Laminar Premixed Biogas–Hydrogen Impinging Flame in the Wall Vicinity," Energies, MDPI, vol. 14(21), pages 1-16, November.
    5. Mehrpooya, Mehdi & Ansarinasab, Hojat & Mousavi, Seyed Ali, 2021. "Life cycle assessment and exergoeconomic analysis of the multi-generation system based on fuel cell for methanol, power, and heat production," Renewable Energy, Elsevier, vol. 172(C), pages 1314-1332.
    6. Lin, Jui-Yen & Shih, Yu-Jen & Chen, Po-Yen & Huang, Yao-Hui, 2016. "Precipitation recovery of boron from aqueous solution by chemical oxo-precipitation at room temperature," Applied Energy, Elsevier, vol. 164(C), pages 1052-1058.
    7. Wang, Junye, 2015. "Theory and practice of flow field designs for fuel cell scaling-up: A critical review," Applied Energy, Elsevier, vol. 157(C), pages 640-663.
    8. Xuexia Zhang & Zixuan Yu & Weirong Chen, 2019. "Life Prediction Based on D-S ELM for PEMFC," Energies, MDPI, vol. 12(19), pages 1-15, September.
    9. Bao, Zhiming & Niu, Zhiqiang & Jiao, Kui, 2020. "Gas distribution and droplet removal of metal foam flow field for proton exchange membrane fuel cells," Applied Energy, Elsevier, vol. 280(C).
    10. Jiang, Hongliang & Xu, Liangfei & Li, Jianqiu & Hu, Zunyan & Ouyang, Minggao, 2019. "Energy management and component sizing for a fuel cell/battery/supercapacitor hybrid powertrain based on two-dimensional optimization algorithms," Energy, Elsevier, vol. 177(C), pages 386-396.
    11. Saka, Kenan & Orhan, Mehmet Fatih, 2022. "Analysis of stack operating conditions for a polymer electrolyte membrane fuel cell," Energy, Elsevier, vol. 258(C).
    12. Faydi, Younes & Djdiaa, AbdelAli & Laabassi, Hichame & Ait Omar, Aissam & Bouzekri, Hicham, 2024. "Contribution of green hydrogen vector to guarantee electricity feeding in remote areas- Case study," Renewable Energy, Elsevier, vol. 222(C).
    13. Zhu, Li & Chen, Junghui, 2018. "Prognostics of PEM fuel cells based on Gaussian process state space models," Energy, Elsevier, vol. 149(C), pages 63-73.
    14. Shi, Yi & Xu, Jiuping, 2023. "A multi-objective approach to kitchen waste and excess sludge co-digestion for biomethane production with anaerobic digestion," Energy, Elsevier, vol. 262(PA).
    15. Roberto Paglini & Marta Gandiglio & Andrea Lanzini, 2022. "Technologies for Deep Biogas Purification and Use in Zero-Emission Fuel Cells Systems," Energies, MDPI, vol. 15(10), pages 1-30, May.
    16. Mohammadi, Mohammad & Noorollahi, Younes & Mohammadi-ivatloo, Behnam & Yousefi, Hossein, 2017. "Energy hub: From a model to a concept – A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 80(C), pages 1512-1527.
    17. Lorenzi, Guido & Lanzini, Andrea & Santarelli, Massimo & Martin, Andrew, 2017. "Exergo-economic analysis of a direct biogas upgrading process to synthetic natural gas via integrated high-temperature electrolysis and methanation," Energy, Elsevier, vol. 141(C), pages 1524-1537.
    18. Hagos, Kiros & Zong, Jianpeng & Li, Dongxue & Liu, Chang & Lu, Xiaohua, 2017. "Anaerobic co-digestion process for biogas production: Progress, challenges and perspectives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 76(C), pages 1485-1496.
    19. Isa, Normazlina Mat & Das, Himadry Shekhar & Tan, Chee Wei & Yatim, A.H.M. & Lau, Kwan Yiew, 2016. "A techno-economic assessment of a combined heat and power photovoltaic/fuel cell/battery energy system in Malaysia hospital," Energy, Elsevier, vol. 112(C), pages 75-90.
    20. Pu, Zonghua & Zhang, Gaixia & Hassanpour, Amir & Zheng, Dewen & Wang, Shanyu & Liao, Shijun & Chen, Zhangxin & Sun, Shuhui, 2021. "Regenerative fuel cells: Recent progress, challenges, perspectives and their applications for space energy system," Applied Energy, Elsevier, vol. 283(C).

    More about this item

    Keywords

    13X zeolite; Biogas; MCFC; H2S adsorption; XRD analysis;
    All these keywords.

    JEL classification:

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:160:y:2018:i:c:p:44-53. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.