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Synergistic effects in the copyrolysis of municipal sewage sludge digestate and salix: Reaction mechanism, product characterization and char stability

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  • Wang, Shule
  • Mandfloen, Per
  • Jönsson, Pär
  • Yang, Weihong

Abstract

Anaerobic digestion is a practical process for recovering energy and materials from sewage sludge. However, land disposal of the derived digestate results in environmental problems, such as eutrophication and salinization. Copyrolysis of sewage sludge digestate and lignocellulosic biomass produces a high-quality oil, a diluted hazardous component of biochar. This study investigates the copyrolysis behavior of lignocellulosic biomass and sludge digestate with different blending ratios using bench-scale experiments. Compared to individual feedstock pyrolysis, copyrolysis shows a higher energy distribution in the liquid product and a lower energy distribution in the char and gas product. The highest energy yield with respect to the organic fraction of liquid product is observed in the copyrolysis case, corresponding to 36.4% of the total energy in the feedstock. The interaction between the sludge digestate and lignocellulosic biomass is studied through product characterizations, mechanistic investigations and char stability assessments. The liquid products in the copyrolysis cases show a relatively high abundance of esters, aliphatic hydrocarbons, pyridines and pyrroles. The reaction pathways of proteins, lipids and carbohydrates are investigated. Two synergistic reaction pathways are proposed. The char stability and nitrogen distribution are investigated. According to the results, the synergistic interaction between feedstocks enhances the quality and energy yield of the liquid biofuel. The char product from copyrolysis has higher potential for use as a carbon sink and fertilizer.

Suggested Citation

  • Wang, Shule & Mandfloen, Per & Jönsson, Pär & Yang, Weihong, 2021. "Synergistic effects in the copyrolysis of municipal sewage sludge digestate and salix: Reaction mechanism, product characterization and char stability," Applied Energy, Elsevier, vol. 289(C).
    • Handle: RePEc:eee:appene:v:289:y:2021:i:c:s0306261921002154
    DOI: 10.1016/j.apenergy.2021.116687
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    Citations

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    Cited by:

    1. Li, Chunxing & Wang, Yu & Xie, Shengyu & Wang, Ruming & Sheng, Hu & Yang, Hongmin & Yuan, Zengwei, 2024. "Synergistic treatment of sewage sludge and food waste digestate residues for efficient energy recovery and biochar preparation by hydrothermal pretreatment, anaerobic digestion, and pyrolysis," Applied Energy, Elsevier, vol. 364(C).
    2. Vishwajeet & Halina Pawlak-Kruczek & Marcin Baranowski & Michał Czerep & Artur Chorążyczewski & Krystian Krochmalny & Michał Ostrycharczyk & Paweł Ziółkowski & Paweł Madejski & Tadeusz Mączka & Amit A, 2022. "Entrained Flow Plasma Gasification of Sewage Sludge–Proof-of-Concept and Fate of Inorganics," Energies, MDPI, vol. 15(5), pages 1-14, March.
    3. Wang, Shule & Yang, Hanmin & Shi, Ziyi & Zaini, Ilman Nuran & Wen, Yuming & Jiang, Jianchun & Jönsson, Pär Göran & Yang, Weihong, 2022. "Renewable hydrogen production from the organic fraction of municipal solid waste through a novel carbon-negative process concept," Energy, Elsevier, vol. 252(C).
    4. Wang, Biao & Chen, Yasen & Chen, Wei & Hu, Junhao & Chang, Chun & Pang, Shusheng & Li, Pan, 2024. "Enhancement of aromatics and syngas production by co-pyrolysis of biomass and plastic waste using biochar-based catalysts in microwave field," Energy, Elsevier, vol. 293(C).

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