IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v238y2019icp1074-1083.html
   My bibliography  Save this article

Heat transfer of composite phase change material modules containing a eutectic carbonate salt for medium and high temperature thermal energy storage applications

Author

Listed:
  • Li, Chuan
  • Li, Qi
  • Li, Yongliang
  • She, Xiaohui
  • Cao, Hui
  • Zhang, Peikun
  • Wang, Li
  • Ding, Yulong

Abstract

This paper concerns the heat transfer behaviour of Composite Phase Change Material (CPCM) modules made of a eutectic carbonate salt of NaLiCO3 (phase change material, PCM), MgO (ceramic skeleton material, CSM) and graphite flakes (thermal conductivity enhancement material, TCEM). The CPCM has a melting point around 500 °C and is suitable for medium and high temperature thermal energy storage applications including peak shaving of power grids, effective use of curtailed wind energy, and concentrated solar power generation. Disk-like CPCM modules were fabricated for the work. The effects of TCEM loading and surface cooling conditions on the heat transfer were experimentally investigated and analysed. The results showed that the use of TCEM not only significantly enhanced heat transfer of the CPCM modules, but also reduced the temperature difference and hence the thermal resistance between heater surface and CPCM module surface, leading to a significant extent of enhancement of overall heat transfer. Temperature measurements of a flat surface of the CPCM modules as well as that within the modules showed a non-uniform temperature distribution perpendicular to heat transfer direction, suggesting the effect of CPCM microstructure on heat transfer. This microstructural effect was further investigated using a scanning electron microscope with energy dispersive spectrometry. The results indicated salt migration, particle breakage and particle redistribution in the interior of the CPCM modules during thermal cycling, leading to a more homogenous distribution of ingredients and more uniform heat transfer within CPCM modules.

Suggested Citation

  • Li, Chuan & Li, Qi & Li, Yongliang & She, Xiaohui & Cao, Hui & Zhang, Peikun & Wang, Li & Ding, Yulong, 2019. "Heat transfer of composite phase change material modules containing a eutectic carbonate salt for medium and high temperature thermal energy storage applications," Applied Energy, Elsevier, vol. 238(C), pages 1074-1083.
    • Handle: RePEc:eee:appene:v:238:y:2019:i:c:p:1074-1083
    DOI: 10.1016/j.apenergy.2019.01.184
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261919301710
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.apenergy.2019.01.184?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Fernandes, D. & Pitié, F. & Cáceres, G. & Baeyens, J., 2012. "Thermal energy storage: “How previous findings determine current research priorities”," Energy, Elsevier, vol. 39(1), pages 246-257.
    2. Mahdi, Jasim M. & Nsofor, Emmanuel C., 2018. "Solidification enhancement of PCM in a triplex-tube thermal energy storage system with nanoparticles and fins," Applied Energy, Elsevier, vol. 211(C), pages 975-986.
    3. Joseph P. Heremans, 2014. "The ugly duckling," Nature, Nature, vol. 508(7496), pages 327-328, April.
    4. Lin, Yaxue & Zhu, Chuqiao & Alva, Guruprasad & Fang, Guiyin, 2018. "Palmitic acid/polyvinyl butyral/expanded graphite composites as form-stable phase change materials for solar thermal energy storage," Applied Energy, Elsevier, vol. 228(C), pages 1801-1809.
    5. Zhang, Zhishan & Alva, Guruprasad & Gu, Min & Fang, Guiyin, 2018. "Experimental investigation on n–octadecane/polystyrene/expanded graphite composites as form–stable thermal energy storage materials," Energy, Elsevier, vol. 157(C), pages 625-632.
    6. Zhang, Long & Zhou, Kechao & Wei, Quiping & Ma, Li & Ye, Wentao & Li, Haichao & Zhou, Bo & Yu, Zhiming & Lin, Cheng-Te & Luo, Jingting & Gan, Xueping, 2019. "Thermal conductivity enhancement of phase change materials with 3D porous diamond foam for thermal energy storage," Applied Energy, Elsevier, vol. 233, pages 208-219.
    7. Wang, Peilun & Wang, Xiang & Huang, Yun & Li, Chuan & Peng, Zhijian & Ding, Yulong, 2015. "Thermal energy charging behaviour of a heat exchange device with a zigzag plate configuration containing multi-phase-change-materials (m-PCMs)," Applied Energy, Elsevier, vol. 142(C), pages 328-336.
    8. Peng, Hao & Li, Rui & Ling, Xiang & Dong, Huihua, 2015. "Modeling on heat storage performance of compressed air in a packed bed system," Applied Energy, Elsevier, vol. 160(C), pages 1-9.
    9. Leng, Guanghui & Qiao, Geng & Jiang, Zhu & Xu, Guizhi & Qin, Yue & Chang, Chun & Ding, Yulong, 2018. "Micro encapsulated & form-stable phase change materials for high temperature thermal energy storage," Applied Energy, Elsevier, vol. 217(C), pages 212-220.
    10. Tian, Y. & Zhao, C.Y., 2011. "A numerical investigation of heat transfer in phase change materials (PCMs) embedded in porous metals," Energy, Elsevier, vol. 36(9), pages 5539-5546.
    11. Tian, Heqing & Du, Lichan & Wei, Xiaolan & Deng, Suyan & Wang, Weilong & Ding, Jing, 2017. "Enhanced thermal conductivity of ternary carbonate salt phase change material with Mg particles for solar thermal energy storage," Applied Energy, Elsevier, vol. 204(C), pages 525-530.
    12. Wickramaratne, Chatura & Dhau, Jaspreet S. & Kamal, Rajeev & Myers, Philip & Goswami, D.Y. & Stefanakos, E., 2018. "Macro-encapsulation and characterization of chloride based inorganic Phase change materials for high temperature thermal energy storage systems," Applied Energy, Elsevier, vol. 221(C), pages 587-596.
    13. Wang, Weilong & Yang, Xiaoxi & Fang, Yutang & Ding, Jing & Yan, Jinyue, 2009. "Enhanced thermal conductivity and thermal performance of form-stable composite phase change materials by using [beta]-Aluminum nitride," Applied Energy, Elsevier, vol. 86(7-8), pages 1196-1200, July.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Zhao, Xiaohuan & E, Jiaqiang & Zhang, Zhiqing & Chen, Jingwei & Liao, Gaoliang & Zhang, Feng & Leng, Erwei & Han, Dandan & Hu, Wenyu, 2020. "A review on heat enhancement in thermal energy conversion and management using Field Synergy Principle," Applied Energy, Elsevier, vol. 257(C).
    2. Li, Chuan & Li, Qi & Ding, Yulong, 2019. "Investigation on the effective thermal conductivity of carbonate salt based composite phase change materials for medium and high temperature thermal energy storage," Energy, Elsevier, vol. 176(C), pages 728-741.
    3. Li, Chuan & Li, Qi & Ding, Yulong, 2019. "Investigation on the thermal performance of a high temperature packed bed thermal energy storage system containing carbonate salt based composite phase change materials," Applied Energy, Elsevier, vol. 247(C), pages 374-388.
    4. Jiang, Feng & Zhang, Lingling & She, Xiaohui & Li, Chuan & Cang, Daqiang & Liu, Xianglei & Xuan, Yimin & Ding, Yulong, 2020. "Skeleton materials for shape-stabilization of high temperature salts based phase change materials: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 119(C).
    5. Sakai, Hiroki & Sheng, Nan & Kurniawan, Ade & Akiyama, Tomohiro & Nomura, Takahiro, 2020. "Fabrication of heat storage pellets composed of microencapsulated phase change material for high-temperature applications," Applied Energy, Elsevier, vol. 265(C).
    6. Li, Chuan & Li, Qi & Ding, Yulong, 2019. "Carbonate salt based composite phase change materials for medium and high temperature thermal energy storage: From component to device level performance through modelling," Renewable Energy, Elsevier, vol. 140(C), pages 140-151.
    7. Li, Chuan & Li, Qi & Cong, Lin & jiang, Feng & Zhao, Yanqi & Liu, Chuanping & Xiong, Yaxuan & Chang, Chun & Ding, Yulong, 2019. "MgO based composite phase change materials for thermal energy storage: The effects of MgO particle density and size on microstructural characteristics as well as thermophysical and mechanical properti," Applied Energy, Elsevier, vol. 250(C), pages 81-91.
    8. Jiang, Feng & Ge, Zhiwei & Ling, Xiang & Cang, Daqiang & Zhang, Lingling & Ding, Yulong, 2021. "Improved thermophysical properties of shape-stabilized NaNO3 using a modified diatomite-based porous ceramic for solar thermal energy storage," Renewable Energy, Elsevier, vol. 179(C), pages 327-338.
    9. Li, Xinyi & Cui, Wei & Simon, Terrence & Ma, Ting & Cui, Tianhong & Wang, Qiuwang, 2021. "Pore-scale analysis on selection of composite phase change materials for photovoltaic thermal management," Applied Energy, Elsevier, vol. 302(C).
    10. Rostami, Sara & Afrand, Masoud & Shahsavar, Amin & Sheikholeslami, M. & Kalbasi, Rasool & Aghakhani, Saeed & Shadloo, Mostafa Safdari & Oztop, Hakan F., 2020. "A review of melting and freezing processes of PCM/nano-PCM and their application in energy storage," Energy, Elsevier, vol. 211(C).
    11. Wang, Wei & Shuai, Yong & He, Xibo & Hou, Yicheng & Qiu, Jun & Huang, Yudong, 2023. "Influence of tank-to-particle diameter ratio on thermal storage performance of random packed-bed with spherical macro-encapsulated phase change materials," Energy, Elsevier, vol. 282(C).
    12. Zhao, Y. & Zhao, C.Y. & Markides, C.N. & Wang, H. & Li, W., 2020. "Medium- and high-temperature latent and thermochemical heat storage using metals and metallic compounds as heat storage media: A technical review," Applied Energy, Elsevier, vol. 280(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Li, Chuan & Li, Qi & Ding, Yulong, 2019. "Investigation on the thermal performance of a high temperature packed bed thermal energy storage system containing carbonate salt based composite phase change materials," Applied Energy, Elsevier, vol. 247(C), pages 374-388.
    2. Li, Chuan & Li, Qi & Ding, Yulong, 2019. "Carbonate salt based composite phase change materials for medium and high temperature thermal energy storage: From component to device level performance through modelling," Renewable Energy, Elsevier, vol. 140(C), pages 140-151.
    3. Sardari, Pouyan Talebizadeh & Mohammed, Hayder I. & Giddings, Donald & walker, Gavin S. & Gillott, Mark & Grant, David, 2019. "Numerical study of a multiple-segment metal foam-PCM latent heat storage unit: Effect of porosity, pore density and location of heat source," Energy, Elsevier, vol. 189(C).
    4. Ibrahim, Nasiru I. & Al-Sulaiman, Fahad A. & Rahman, Saidur & Yilbas, Bekir S. & Sahin, Ahmet Z., 2017. "Heat transfer enhancement of phase change materials for thermal energy storage applications: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 74(C), pages 26-50.
    5. Wu, Weixiong & Wu, Wei & Wang, Shuangfeng, 2019. "Form-stable and thermally induced flexible composite phase change material for thermal energy storage and thermal management applications," Applied Energy, Elsevier, vol. 236(C), pages 10-21.
    6. Li, Chuan & Li, Qi & Cong, Lin & jiang, Feng & Zhao, Yanqi & Liu, Chuanping & Xiong, Yaxuan & Chang, Chun & Ding, Yulong, 2019. "MgO based composite phase change materials for thermal energy storage: The effects of MgO particle density and size on microstructural characteristics as well as thermophysical and mechanical properti," Applied Energy, Elsevier, vol. 250(C), pages 81-91.
    7. Mahdi, Jasim M. & Mohammed, Hayder I. & Hashim, Emad T. & Talebizadehsardari, Pouyan & Nsofor, Emmanuel C., 2020. "Solidification enhancement with multiple PCMs, cascaded metal foam and nanoparticles in the shell-and-tube energy storage system," Applied Energy, Elsevier, vol. 257(C).
    8. Jiang, Liang & Lei, Yuan & Liu, Qinfeng & Lei, Jingxin, 2020. "Polyethylene glycol based self-luminous phase change materials for both thermal and light energy storage," Energy, Elsevier, vol. 193(C).
    9. Kawaguchi, Takahiro & Sakai, Hiroki & Sheng, Nan & Kurniawan, Ade & Nomura, Takahiro, 2020. "Microencapsulation of Zn-Al alloy as a new phase change material for middle-high-temperature thermal energy storage applications," Applied Energy, Elsevier, vol. 276(C).
    10. Rostami, Sara & Afrand, Masoud & Shahsavar, Amin & Sheikholeslami, M. & Kalbasi, Rasool & Aghakhani, Saeed & Shadloo, Mostafa Safdari & Oztop, Hakan F., 2020. "A review of melting and freezing processes of PCM/nano-PCM and their application in energy storage," Energy, Elsevier, vol. 211(C).
    11. Yu, De-Hai & He, Zhi-Zhu, 2019. "Shape-remodeled macrocapsule of phase change materials for thermal energy storage and thermal management," Applied Energy, Elsevier, vol. 247(C), pages 503-516.
    12. Shahsavar, Amin & Goodarzi, Abbas & Mohammed, Hayder I. & Shirneshan, Alireza & Talebizadehsardari, Pouyan, 2020. "Thermal performance evaluation of non-uniform fin array in a finned double-pipe latent heat storage system," Energy, Elsevier, vol. 193(C).
    13. Chen, C.Q. & Diao, Y.H. & Zhao, Y.H. & Ji, W.H. & Wang, Z.Y. & Liang, L., 2019. "Thermal performance of a thermal-storage unit by using a multichannel flat tube and rectangular fins," Applied Energy, Elsevier, vol. 250(C), pages 1280-1291.
    14. Ewelina Radomska & Lukasz Mika & Karol Sztekler & Lukasz Lis, 2020. "The Impact of Heat Exchangers’ Constructions on the Melting and Solidification Time of Phase Change Materials," Energies, MDPI, vol. 13(18), pages 1-44, September.
    15. Sardari, Pouyan Talebizadeh & Giddings, Donald & Grant, David & Gillott, Mark & Walker, Gavin S., 2020. "Discharge of a composite metal foam/phase change material to air heat exchanger for a domestic thermal storage unit," Renewable Energy, Elsevier, vol. 148(C), pages 987-1001.
    16. Mahdi, Jasim M. & Nsofor, Emmanuel C., 2017. "Melting enhancement in triplex-tube latent heat energy storage system using nanoparticles-metal foam combination," Applied Energy, Elsevier, vol. 191(C), pages 22-34.
    17. Zhao, Liang & Xing, Yuming & Liu, Xin, 2020. "Experimental investigation on the thermal management performance of heat sink using low melting point alloy as phase change material," Renewable Energy, Elsevier, vol. 146(C), pages 1578-1587.
    18. Mohammad Javad Zarei & Hassan Bazai & Mohsen Sharifpur & Omid Mahian & Bahman Shabani, 2020. "The Effects of Fin Parameters on the Solidification of PCMs in a Fin-Enhanced Thermal Energy Storage System," Energies, MDPI, vol. 13(1), pages 1-20, January.
    19. Liu, Yang & Zheng, Ruowei & Li, Ji, 2022. "High latent heat phase change materials (PCMs) with low melting temperature for thermal management and storage of electronic devices and power batteries: Critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 168(C).
    20. Gustavo Cáceres & Macarena Montané & Shahriyar Nasirov & Raúl O’Ryan, 2016. "Review of Thermal Materials for CSP Plants and LCOE Evaluation for Performance Improvement using Chilean Strategic Minerals: Lithium Salts and Copper Foams," Sustainability, MDPI, vol. 8(2), pages 1-20, January.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:238:y:2019:i:c:p:1074-1083. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.