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Comparison of acid and alkaline pre-treatment of lignocellulosic materials for biogas production

Author

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  • Barbora Jankovičová
  • Miroslav Hutňan

    (Slovak University of Technology, Faculty of Chemical and Food Technology, Department of Environmental Engineering, Bratislava, Slovak Republic)

  • Marianna Nagy Czölderová

    (Slovak University of Technology, Faculty of Chemical and Food Technology, Department of Environmental Engineering, Bratislava, Slovak Republic)

  • Kristína Hencelová

    (Slovak University of Technology, Faculty of Chemical and Food Technology, Department of Environmental Engineering, Bratislava, Slovak Republic)

  • Zuzana Imreová

    (Slovak University of Technology, Faculty of Chemical and Food Technology, Department of Environmental Engineering, Bratislava, Slovak Republic)

Abstract

This work deals with the study of a pre-treatment method promoting degradability of lignocellulosic biomass and hence biogas yield therefrom, as this material is challenging to decompose due to its structure. The investigated pre-treatment methods are hydrolysis of the material in NaOH (0.5% and 5%) and H2SO4 (0.5% and 5%) at temperatures of 90-100 °C for 2 h. This work aimed to compare the effects of these pre-treatment methods on the lignocellulosic composition of maize waste (maize stalks, leaves and cobs), rapeseed straw and wheat straw and the biogas yields from its subsequent anaerobic digestion. Pre-treatment by 0.5% NaOH increased the biogas production the most (by 159% for rapeseed straw, 240% for wheat straw and 59% for maize waste) also the degrees of solubilisation was higher, at the same time the proportions of total organic carbon (TOC) in the solid component appear to be sufficiently high, it could be assumed that there has been sufficient disturbance of the material structure. Alkaline methods have proven to be more suitable compared to acid pre-treatment methods, also the use of alkali with a lower concentration has shown to be more efficient, which is more advantageous for use in practice from an environmental and economic point of view.

Suggested Citation

  • Barbora Jankovičová & Miroslav Hutňan & Marianna Nagy Czölderová & Kristína Hencelová & Zuzana Imreová, 2022. "Comparison of acid and alkaline pre-treatment of lignocellulosic materials for biogas production," Plant, Soil and Environment, Czech Academy of Agricultural Sciences, vol. 68(4), pages 195-204.
  • Handle: RePEc:caa:jnlpse:v:68:y:2022:i:4:id:421-2021-pse
    DOI: 10.17221/421/2021-PSE
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    References listed on IDEAS

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    1. Kaur, Karamjeet & Phutela, Urmila Gupta, 2016. "Enhancement of paddy straw digestibility and biogas production by sodium hydroxide-microwave pretreatment," Renewable Energy, Elsevier, vol. 92(C), pages 178-184.
    2. Mustafa, Ahmed M. & Poulsen, Tjalfe G. & Sheng, Kuichuan, 2016. "Fungal pretreatment of rice straw with Pleurotus ostreatus and Trichoderma reesei to enhance methane production under solid-state anaerobic digestion," Applied Energy, Elsevier, vol. 180(C), pages 661-671.
    3. Tan, Minghui & Ma, Liang & Rehman, Muhamamd Saif Ur & Ahmed, Muhammad Ajaz & Sajid, Muhammad & Xu, Xia & Sun, Yong & Cui, Ping & Xu, Jian, 2019. "Screening of acidic and alkaline pretreatments for walnut shell and corn stover biorefining using two way heterogeneity evaluation," Renewable Energy, Elsevier, vol. 132(C), pages 950-958.
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