Regular quantum plasmons in segments of graphene nanoribbons

Graphene plasmons have advantages over noble metal plasmons such as high tunability and low loss. However, for graphene nanostructures smaller than 10 nm, little is known about their plasmons or whether regular plasmonic behavior exists, despite their potential applications. Here, we present first-principles calculations of plasmon excitations in zigzag graphene nanoribbon segments. Very regular plasmonic behavior is found: Only one plasmon mode exists in the low-energy regime (<1.5 eV). The classical electrostatic scaling law still approximately holds when the width (W) is larger than ∼1.5 nm but totally fails when W<1.5 nm due to quantum effects. The scaling with different doping densities shows that the plasmon is nearly free-electron plasmon instead of Dirac plasmon.