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Generating carbyne equivalents with photoredox catalysis

Author

Listed:
  • Zhaofeng Wang

    (Institute of Chemical Research of Catalonia (ICIQ), The Barcelona Institute of Science and Technology)

  • Ana G. Herraiz

    (Institute of Chemical Research of Catalonia (ICIQ), The Barcelona Institute of Science and Technology)

  • Ana M. del Hoyo

    (Institute of Chemical Research of Catalonia (ICIQ), The Barcelona Institute of Science and Technology)

  • Marcos G. Suero

    (Institute of Chemical Research of Catalonia (ICIQ), The Barcelona Institute of Science and Technology)

Abstract

A photocatalytic strategy is described that generates diazomethyl radicals as direct equivalents of carbynes, which are often too reactive to use, enabling the functionalization of a range of medically useful compounds.

Suggested Citation

  • Zhaofeng Wang & Ana G. Herraiz & Ana M. del Hoyo & Marcos G. Suero, 2018. "Generating carbyne equivalents with photoredox catalysis," Nature, Nature, vol. 554(7690), pages 86-91, February.
    • Handle: RePEc:nat:nature:v:554:y:2018:i:7690:d:10.1038_nature25185
    DOI: 10.1038/nature25185
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    Cited by:

    1. Chichu Qin & Dong Wang & Yumin Liu & Pengkun Yang & Tian Xie & Lu Huang & Haiyan Zou & Guanwu Li & Yingpeng Wu, 2021. "Tribo-electrochemistry induced artificial solid electrolyte interface by self-catalysis," Nature Communications, Nature, vol. 12(1), pages 1-11, December.

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